15. Ignoring stereochemistry, what is the overall enthalpy difference of the reaction of 1,2,4,5-tetramethylcyclohexane, chlorine, and light going to the major mono-chlorinated product? Bond Disassociation Energies kcal/mole Selectivity Ratios C-H С-F С-CI C-Br C-I X-X H-X 1° 2° 3° 1° 98 107 81 68 53 F 38 136 F 1 1.2 1.4 2° 95 106 80 68 53 CI 58 103 CI 1 4 3° 91 106 79 65 50 Br 46 88 Br 1 80 1700 а. -25 b. -28 C. -30 d. -33 e. not a.-d.
15. Ignoring stereochemistry, what is the overall enthalpy difference of the reaction of 1,2,4,5-tetramethylcyclohexane, chlorine, and light going to the major mono-chlorinated product? Bond Disassociation Energies kcal/mole Selectivity Ratios C-H С-F С-CI C-Br C-I X-X H-X 1° 2° 3° 1° 98 107 81 68 53 F 38 136 F 1 1.2 1.4 2° 95 106 80 68 53 CI 58 103 CI 1 4 3° 91 106 79 65 50 Br 46 88 Br 1 80 1700 а. -25 b. -28 C. -30 d. -33 e. not a.-d.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Problem 15:**
Ignoring stereochemistry, what is the overall enthalpy difference of the reaction of 1,2,4,5-tetramethylcyclohexane, chlorine, and light going to the major mono-chlorinated product?
**Bond Dissociation Energies (kcal/mole):**
- **1° (Primary) Bonds:**
- C-H: 98
- C-F: 107
- C-Cl: 81
- C-Br: 68
- C-I: 53
- **2° (Secondary) Bonds:**
- C-H: 95
- C-F: 106
- C-Cl: 80
- C-Br: 68
- C-I: 53
- **3° (Tertiary) Bonds:**
- C-H: 91
- C-F: 106
- C-Cl: 79
- C-Br: 65
- C-I: 50
**Bond Dissociation Energies for X-X and H-X:**
- F-F: 38
- Cl-Cl: 58
- Br-Br: 46
- H-F: 136
- H-Cl: 103
- H-Br: 88
**Selectivity Ratios:**
- **Fluorine (F):**
- 1°: 1
- 2°: 1.2
- 3°: 1.4
- **Chlorine (Cl):**
- 1°: 1
- 2°: 4
- 3°: 5
- **Bromine (Br):**
- 1°: 1
- 2°: 80
- 3°: 1700
**Answer Choices:**
- a. -25
- b. -28
- c. -30
- d. -33
- e. not a.-d.
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