Question 7 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI A O A B C 20 1 2 19 18 17 16 15 HBr ROOR (peroxide) H₂O 9 12 11 10 mCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) 14 13 Br D EtOH D₂ (deuterium) Pd or l B с Br Br Br Br Br Br 3.8 H₂SO4 HCI 1. BH3.THF 2. H₂O2, NaOH Br2 Br2 H₂O BH3⚫THF D Br Br 'Br Br Br Br Br Br
Question 7 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI A O A B C 20 1 2 19 18 17 16 15 HBr ROOR (peroxide) H₂O 9 12 11 10 mCPBA 1. OsO4 2. H₂O₂ CH3CO₂H (peroxyacid) 14 13 Br D EtOH D₂ (deuterium) Pd or l B с Br Br Br Br Br Br 3.8 H₂SO4 HCI 1. BH3.THF 2. H₂O2, NaOH Br2 Br2 H₂O BH3⚫THF D Br Br 'Br Br Br Br Br Br
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![Question 7
Please predict the products for each of the following reactions.
Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).
If a mixture of enantiomers is formed, please draw all the enantiomers.
Br2
CH₂OH
1.03
2. DMS
KMnO4, NaOH
cold
HI
20 1
2
19
18
17
16
HBr
ROOR (peroxide)
9
12 11 10
mCPBA
1. OsO4
2. H₂O₂
CH.COSH
(peroxyacid)
15
14
13
A
B
Br
Br
Br
Br
O A
Br
Br
B
FIQH
D₂ (deuterium)
Pd or l
Br
Br
C
D
0
H₂O
H₂SO4
HCI
1. BH3⚫THF
2. H₂O2, NaOH
Br2
Br2
H₂O
BH3⚫THF
8.8
D
Br
Br
Br
'Br
Br
Br
'Br
Br](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F6fb46d0e-bf36-4ed9-804c-98f856ba3c31%2F67a254e4-5ae3-40ed-8db8-b5d3d57e817c%2Flj4b2gk_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Question 7
Please predict the products for each of the following reactions.
Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).
If a mixture of enantiomers is formed, please draw all the enantiomers.
Br2
CH₂OH
1.03
2. DMS
KMnO4, NaOH
cold
HI
20 1
2
19
18
17
16
HBr
ROOR (peroxide)
9
12 11 10
mCPBA
1. OsO4
2. H₂O₂
CH.COSH
(peroxyacid)
15
14
13
A
B
Br
Br
Br
Br
O A
Br
Br
B
FIQH
D₂ (deuterium)
Pd or l
Br
Br
C
D
0
H₂O
H₂SO4
HCI
1. BH3⚫THF
2. H₂O2, NaOH
Br2
Br2
H₂O
BH3⚫THF
8.8
D
Br
Br
Br
'Br
Br
Br
'Br
Br
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