Question 18 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. HBr ROOR (peroxide) Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O₂ 19 18 17 16 15 CH.COSH (peroxyacid) 14 MCPBA 13 Pd or F 20 1 2 12 11 10 Pd or Ni (catalyst) D₂ (deuterium) FIOH H₂O H₂SO4 HCI 1. BH, THF 2. H₂O2, NaOH Br2 Br2 H₂O BH3⚫THF A mig ОН ABCD OH с B D

Question 18 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. HBr ROOR (peroxide) Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O₂ 19 18 17 16 15 CH.COSH (peroxyacid) 14 MCPBA 13 Pd or F 20 1 2 12 11 10 Pd or Ni (catalyst) D₂ (deuterium) FIOH H₂O H₂SO4 HCI 1. BH, THF 2. H₂O2, NaOH Br2 Br2 H₂O BH3⚫THF A mig ОН ABCD OH с B D

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Question 14 Pd or Pt (catalyst) 19 18 17 16 20 2 HBr ROOR (peroxide) H₂O H2SO4 HCI 5 1. BH3.THF 2. H₂O2, NaOH 13 12 11 10 Br2 Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 15 14 D₂ (deuterium) Pd or l A B Br₂ H₂O BH3⚫THF с D ď ď ď d OH OH OH OH œ œœ "OH OH "OH OH OH ď ď 'OH OH OH de de OH OH А В ABCD
Question 9 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. HBr ROOR (peroxide) H₂O Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI ТСРВА 1. OsO4 2. H₂O₂ sl+H3 19 18 17 16 15 CH3CO₂H (peroxyacid) 14 MCPBA 13