EBK GENERAL CHEMISTRY11th EditionBissonnette Publisher: VSTISBN: 9780133400588
EBK GENERAL CHEMISTRY
Solutions for EBK GENERAL CHEMISTRY
Problem 1E:
Calculate the quantity of heat, in kilojoules, (a) required to raise the temperature of 9.25 L of...Problem 2E:
Calculate the final temperature that results when (a)a 12.6 g sample of waterat 22.9C absorbs 875 J...Problem 3E:
Refer to Example 7-2. The experiment is repeated several different metals substituting for the lead....Problem 4E:
A 75.0 g piece of Ag metal is heated to 80.0C and dropped into 50.0 g of water at 23.2 C. The final...Problem 5E:
A 465 g chunk of iron is removed from an oven and plunged into 375 g water in an insulated...Problem 6E:
A piece of stainless steel (C2=0.50Jg-1C-1) is transferred from an oven at 201C into 1500mL of water...Problem 7E:
A 1.00 kg sample of magnesium at 40.0C is added to 1.00 L of water maintained at 20.0C in an...Problem 8E:
Brass has a density of 8.40 g/cm2 and a specific heat capacity of 0.385Jg-1C-1 . A 15.2cm2 piece of...Problem 9E:
A 74.8 g sample of copper at 143.2C is added to an insulated vessel containing 165 mL of glycerol,...Problem 10E:
A 69.0 g sample of gold at 127.1C is added to an insulated vessel containing 543.0 mL of water at...Problem 11E:
In the form of heat, 6052 J of energy is transferred to a 1.0 L sample of air (d=1.204mg/cm2) at...Problem 12E:
What is the final temperature (in C) of 1.24 g of water with an initial temperature of 200C after...Problem 13E:
How much heat, in kilojoules, is associated with one of 283 kg of slaked lime, Ca(OH)2?...Problem 14E:
The standard enthalpy of reaction for the combustion of octane is H0=5.48103kJ/molC5H15(I) . How...Problem 15E:
How much heat, in kilojoules, is evolved the compete combustion of (a) 1.325gC4H10(g) at 25C and 1...Problem 16E:
Upon complete combustion the indicated substances evolve the given quantities of heat. Write a...Problem 17E:
The combustion of methane gas, the principal constituent of natural gas, is represented by the...Problem 18E:
Refer to the Integrative Example. What volume of the synthesis gas, measured at STP and burned an...Problem 19E:
The combustion of hydrogen-oxygen mixtures is used to very high (approximately 2500 C) needed for...Problem 20E:
Thermite mixtures are used for certain types of welding, and the thermite reaction is highly...Problem 21E:
A 0.205 g pellet of potassium hydroxide, KOH, is added to 55.9 g water in a Styrofoam coffee cup....Problem 22E:
The heat of solution of Kl(s) in water is +20.3kJ/molKI. If a Quantity of KI is added to sufficient...Problem 23E:
You are planning lecture demonstration to illustrate an endothermic process. You want to lower the...Problem 24E:
Care must be taken in preparing solutions of solutes that liberate heat on dissolving. The heat of...Problem 25E:
Refer to Example 7-4. The product of the neutralization is 0.500 M NaCl. For this solution, assume a...Problem 29E:
What mass of ice can be meted the same quantity of heat as required to raise the temperature of 3.50...Problem 30E:
What will be the final temperature of the water in an insulated as the result of passing 5.00 g of...Problem 31E:
A 125 g stainless steel ball bearings (C0=0.50Jg1C1) at 525C is dropped into 75.0 mL of water at...Problem 33E:
The enthalpy of sublimation (solid gas) for dry ice (i.e., CO2) is vaH0=5.71kJ/kg at -78.5 C. If...Problem 34E:
The enthalpy of vaporization forN2 (I)is 5.56 kJ/mol. How much heat (in J) is required to produce...Problem 35E:
A sample gives off 5228 cal when burned in a bomb calorimeter The temperature of the calorimeter...Problem 36E:
The following substances undergo complete combustion in a bomb calorimeter. The calorimeter assembly...Problem 37E:
A bomb calorimetry experiment is performed withxylose, C3H10O2(s) as the combustible substance. The...Problem 38E:
A coffee-cup calorimeter contains 100.0 mL of 0.300 M HCIat 20.3 C. When 1.82 g Zn(s) is added, the...Problem 39E:
A 0.75 g sample of KCI is added to 350 g H2O in a Styrofoam cup and stirred it dissolves. The...Problem 40E:
The heat of solution of potassium acetate in water is -15.3 kJ/mol KCH2COO. What will be the final...Problem 42E:
Salicylic acid, C7H5O2 , has been suggested as a calorimetric standard. Its heat of combustion is...Problem 43E:
Refer to Example 7-3. Based on the heat of combustion of sucrose established in the example, what...Problem 44E:
A 1.397 g sample of thymol, C10H14O(s) (a preservative and a mold and mildew preventative), is...Problem 45E:
A g of NaCI is added to a Styrofoam cup of water, and the change in water temperature is 5.0 C. The...Problem 46E:
can determine purity of solid materials by using calorimetry. A gold ring (for pure gold, specific...Problem 47E:
Calculate the quantity of work associated with a 3.5 L expansion of a gas (V) against a pressure of...Problem 48E:
Calculate the quantity of work, in joules, associated with the compression of a gas from 5.62 L to...Problem 49E:
A 1.00 g sample of Ne(g) at 1 atm pressure and 27C is allowed to expand into an evacuated vessel of...Problem 50E:
Compressed air in aerosol cans is used to free electronic equipment of dust. Does the air do any...Problem 51E:
In each of the following processes, is any work done when the reaction is carried out at constant...Problem 52E:
In each of the following processes, any work done when the reaction is carried out at constant...Problem 53E:
If 325 J of work is done by a system at a pressure of 1.0 atm and 298 K, what is the change in the...Problem 54E:
A movable piston a cylinder holding 5.0 L N2(g) is used to lift a 2.41 kg object to a height of 26...Problem 55E:
What is the change in internal energy of a system if the system (a) absorbs 58 J of heat and does 58...Problem 56E:
Whet the change in internal energy of e system if the surroundings (a) transfer 235 of heat and 128...Problem 57E:
The internal energy of a fixed quantity of an ideal gas depends only on its temperature. A sample of...Problem 61E:
There are other forms of work besides PV work. For example, electrical work is defined as the...Problem 62E:
Another form of work is extension, defined as the tension x change in length, w=fI. A piece of DNA...Problem 63E:
Only one of the following quantities is equal to the heat of a chemical reaction, regardless of how...Problem 64E:
Determine whether H is equal to, greater than, or less than U for the following processes. Keep in...Problem 65E:
The heat of combustion of propan-2-ol at 298.15 K, determined in a bomb calorimeter, is -33.41 kJ/g....Problem 67E:
The standard enthalpy of formation of NH2(g) is -46.11 kJ/mol. What is rH for the following...Problem 69E:
Use Hess's law to determine rH for the reaction 2 HÅg) given that H2(g)+12O2(g)H2O(I)...Problem 70E:
Given the following information: 12N2(g)+32H2(g)NH3(g)rH1 NH3(g)+54O2(g)NO(g)+32H2O(I)rH2...Problem 73E:
Substitute natural gas (SNG) is a gaseous mature containing CH4(g) that can be used as a fuel. One...Problem 74E:
CCI4 , an important commercial solvent, is prepared by the reaction of CI2(g) with a carbon...Problem 76E:
The standard heats of combustion (rH) of butane-l ,3-diene, C4H5(g) ; butane, C4H10(g) ; and H2(g)...Problem 77E:
One glucose molecule, C6H12O6(s) is converted to two lactic acid molecules, CH2CH(OH)COOH(s) during...Problem 78E:
The standard of fermentation of glucose to ethanol is C6H12O6(s)2CH3CH2OH(I)+2CO2(g)rH=72kJmol1 Use...Problem 79E:
Use standard enthalpies of formation from Table 7.2 and equation (7.22) to the standard enthalpy of...Problem 80E:
Use standard enthalpies of formation from Tables 7.2 and 7.3 and equation (7.22) to determine the...Problem 81E:
Use the information given here. date from Appendix D, and equation (7.22) to calculate the standard...Problem 86E:
Use data from Table 7.2, together with the factthat rH=3509kJmol1 for the complete combustion of...Problem 87E:
Use data from Table 7.2 and rH for re following reaction to determine the standard enthalpy of...Problem 88E:
Use data from Table 7.2 and rH for the following reaction to determine the standard enthalpy of...Problem 91E:
The decomposition of limestone, CaCO2(s) into quicklime, CaO(s) , and CO2(g) is carried out in a...Problem 92E:
Use data from Table 7.2 to calculate the volume of butane, C4H10(g), measured at 24.6C and 756 mmHg,...Problem 93E:
Ants release formic acid (HCOOH) when they bite. use the data in Table 7.2 and tie standard enthalpy...Problem 95IAE:
A British thermal unit (Btu) is defined as the quantity of heat required to change the temperature...Problem 96IAE:
What volume of 18.5C water must be added, together with a1.23 kg piece of iron at 68.5 C, so that...Problem 97IAE:
A 7.26 kg shot (as used the sporting event, the shot put) is dropped from the top of building 168 m...Problem 98IAE:
An alternative approach to bomb calorimetry is to establish the heat capacity of the calorimeter,...Problem 101IAE:
Determine the missing values of rH in the diagram shown below.Problem 102IAE:
A particular natural gas consists, in mole percents, of 830% CH4, 11.2%C2H5 and 5.8% C2H5. A 385 L...Problem 105IAE:
A calorimeter that measures an exothermic heat of reaction by the quantity of ice that can be melted...Problem 106IAE:
For the reaction C2H4(g)+3O2(g)2CO2(g)+2H2O(I) rH=1410.9kJmol1 if the H2O were obtained as a gas...Problem 107IAE:
Some of the butane, C4H10(g) , in a 200.0 L cylinder at 26.0C is withdrawn and burned at a constant...Problem 108IAE:
The metabolism of glucose, C5H12O5 yields CO2(g) and H2O(I) as products. Heat released in the...Problem 110IAE:
Upon complete combustion, a 1.00 L sample (at STP) of a natural gas gives off 43.6 kJ of heat. If...Problem 112IAE:
Refer to the discussion of the gasification of coal (page 283), and show that some of the heat...Problem 113IAE:
A 1.103 g sample of a gaseous carbon-hydrogen-oxygen compound that occupies a volume of 582 mL at...Problem 114IAE:
Several factors are involved in determining the cooking times required for foods in a microwave...Problem 118IAE:
In the Are You Wondering 7-1 box, the temperature variation of enthalpy is discussed, and the...Problem 121IAE:
Cetane, C15H34, is a typical petrodiesel with a standard enthalpy of combustion of 10,699.1kJmol1 ....Problem 122IAE:
Carbon dioxide emissions have been implicated as a major factor in climate change. Which of the...Problem 125FP:
We can use the heat liberated by a neutralization reaction as a means of establishing the...Problem 126FP:
In a student experiment to confirm Hess's law, the reaction NH3(concdaq)+HCI(aq)NH4CI(aq) was...Problem 128FP:
Refer to Example 7-5 dealing with the work done by 0.100 mol He at 298 K in expanding in a single...Problem 129FP:
Look up the specific heat capacity of several elements, and plot the products of the specific heat...Problem 130SAE:
In your own words, define or explain the following terms or symbols: (a)rH;(b)PV;(c)rH; (d) standard...Problem 132SAE:
Explain the important distinctions between each pair of terms: (a) system and surroundings: (b) heat...Problem 133SAE:
The temperature increase of 225 mL of water at 25C contained in a Styrofoam cup is noted when a 125...Problem 134SAE:
A plausible final temperature when 75.0 ml of water at 80.0C is added to 1000 ml of water at 20C is...Problem 135SAE:
U= 100 J for a system that gives off 100 J of heat and (a) does no work; (b) does 200 J of work; (c)...Problem 137SAE:
The standard molar enthalpy of formation of CO2(g) is equal to (a) 0; (b) the standard molar heat of...Problem 139SAE:
Compute rH for the following reactions. The value of rH in kJ mol-1 is given for each substance...Problem 140SAE:
When dissolved in water, 1.00 mol LiCI produces 37.12 kJ of heat. What is the final temperature in...Problem 144SAE:
A 1.22 kg piece of iron at 126.5C is dropped into 981 g water at 22.1 C. The temperature rises to...Browse All Chapters of This Textbook
Chapter 1 - Matter: Its Properties And MeasurementChapter 2 - Atoms And The Atomic TheoryChapter 3 - Chemical CompoundsChapter 4 - Chemical ReactionsChapter 5 - Introduction To Reactions In Aqueous SolutionsChapter 6 - GasesChapter 7 - ThermochemistryChapter 8 - Electrons In AtomsChapter 9 - The Periodic Table And Some Atomic PropertiesChapter 10 - Chemical Bonding I: Basic Concepts
Chapter 11 - Chemical Bonding Ii: Valence Bond And Molecular Orbital TheoriesChapter 12 - Intermolecular Forces: Liquids And SolidsChapter 13 - Spontaneous Change: Entropy And Gibbs EnergyChapter 14 - Solutions And Their Physical PropertiesChapter 15 - Principles Of Chemical EquilibriumChapter 16 - Acids And BasesChapter 17 - Additional Aspects Of Acid–base EquilibriaChapter 18 - Solubility And Complex-ion EquilibriaChapter 19 - ElectrochemistryChapter 20 - Chemical KineticsChapter 21 - Chemistry Of The Main-group Elements I: Groups 1, 2, 13, And 14Chapter 22 - Chemistry Of The Main-group Elements Ii: Groups 18, 17, 16, 15, And HydrogenChapter 23 - The Transition ElementsChapter 24 - Complex Ions And Coordination CompoundsChapter 25 - Nuclear ChemistryChapter 26 - Structures Of Organic CompoundsChapter 27 - Reactions Of Organic Compounds
Sample Solutions for this Textbook
We offer sample solutions for EBK GENERAL CHEMISTRY homework problems. See examples below:
Chapter 1, Problem 1EChapter 2, Problem 1EChapter 3, Problem 1EChapter 4, Problem 1EChapter 5, Problem 1EChapter 6, Problem 1EChapter 7, Problem 1EChapter 8, Problem 1EFrom periodic table and from the given data table, element having atomic number 114 will be in the...
Chapter 10, Problem 1ELewis theory and valence bond theoryexplainabout covalent bonding. But the main difference is that...Chapter 12, Problem 1EGiven information: Number of particles = 5 1D box length = L When the length of the box is increased...Chapter 14, Problem 1EChapter 15, Problem 1EChapter 16, Problem 1EChapter 17, Problem 1EChapter 18, Problem 1EChapter 19, Problem 1EChapter 20, Problem 1ECesium metal is an alkali metal and it has the tendency to form a monovalent cation, namely Cs+...Chapter 22, Problem 1EChapter 23, Problem 1EThe complex has Cr3+ as the central ion and two NH3 molecules and four Cl- ions as ligands...In β− emission, an electron is emitted from the nucleus. The given nucleus is 2655Fe here, atomic...There is a difference between structural formula and condensed formula. The formula which represents...Chapter 27, Problem 1E
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