(a) Interpretation: When increasing the length of the box to 2 L for fixed total energy, the change in the number of accessible microstates and the entropy of the system should be explained. Concept introduction: Microstates is a specific microscopic configuration describing how the particles of a system are distributed among the available energy levels. In a system, the entropy of a system depends on the total number of possible microscopic states by the Boltzmann relation as shown below: S = K B × ln W Here, K B is Boltzmann constant, S is entropy and W is number of microstates.

Question

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Answer 1

Question

Chapter 13, Problem 1E

Interpretation Introduction

(a)

Interpretation:

When increasing the length of the box to 2 L for fixed total energy, the change in the number of accessible microstates and the entropy of the system should be explained.

Concept introduction:

Microstates is a specific microscopic configuration describing how the particles of a system are distributed among the available energy levels.

In a system, the entropy of a system depends on the total number of possible microscopic states by the Boltzmann relation as shown below:

S = KB× ln W

Here, KB is Boltzmann constant, S is entropy and W is number of microstates.

Expert Solution

Answer to Problem 1E

Number of microstates and the entropy increases.

Explanation of Solution

Given information:

Number of particles = 5

1D box length = L

When the length of the box is increased to 2 L, the number of the microstates increases for fixed total energy. the energy levels are shifted to lower values and are more closely spaced. Therefore,

more energy levels are accessible

According to the S = KB× ln W equation, when number of microstates increase, entropy also gets increased.

Interpretation Introduction

(b)

Interpretation:

Whenthe total energy for constant box length is increased, the change in the number of accessible microstates and the entropy of the system should be explained.

Concept introduction:

Microstates is a specific microscopic configuration describing how the particles of a system are distributed among the available energy levels.

In a system, the entropy of a system depends on the total number of possible microscopic states by the Boltzmann relation as shown below:

S = KB× ln W

Here, KB is Boltzmann constant, S is entropy and W is number of microstates.

Expert Solution

Answer to Problem 1E

Number of microstates and the entropy increases.

Explanation of Solution

Given information:

Number of particles = 5

1D box length = L

With the increase of total energy, the number of microstates increases because more energy levels are accessible.

According to the S = KB× ln W equation, when number of microstates increase, entropy also gets increased.

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For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3) → Give the expression for the acceptable rate. → → (A). d[N205] dt == 2k,k₂[N₂O₂] k₁+k₁₂ (B). d[N2O5] =-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³ dt (C). d[N2O5] =-k₁[N₂O] + k [NO] - k₂[NO] [NO] d[N2O5] (D). = dt = -k₁[N2O5] - k¸[NO][N₂05] dt Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.

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Answer 2

Question

Chapter 13, Problem 1E

Interpretation Introduction

(a)

Interpretation:

When increasing the length of the box to 2 L for fixed total energy, the change in the number of accessible microstates and the entropy of the system should be explained.

Concept introduction:

Microstates is a specific microscopic configuration describing how the particles of a system are distributed among the available energy levels.

In a system, the entropy of a system depends on the total number of possible microscopic states by the Boltzmann relation as shown below:

S = KB× ln W

Here, KB is Boltzmann constant, S is entropy and W is number of microstates.

Expert Solution

Answer to Problem 1E

Number of microstates and the entropy increases.

Explanation of Solution

Given information:

Number of particles = 5

1D box length = L

When the length of the box is increased to 2 L, the number of the microstates increases for fixed total energy. the energy levels are shifted to lower values and are more closely spaced. Therefore,

more energy levels are accessible

According to the S = KB× ln W equation, when number of microstates increase, entropy also gets increased.

Interpretation Introduction

(b)

Interpretation:

Whenthe total energy for constant box length is increased, the change in the number of accessible microstates and the entropy of the system should be explained.

Concept introduction:

Microstates is a specific microscopic configuration describing how the particles of a system are distributed among the available energy levels.

In a system, the entropy of a system depends on the total number of possible microscopic states by the Boltzmann relation as shown below:

S = KB× ln W

Here, KB is Boltzmann constant, S is entropy and W is number of microstates.

Expert Solution

Answer to Problem 1E

Number of microstates and the entropy increases.

Explanation of Solution

Given information:

Number of particles = 5

1D box length = L

With the increase of total energy, the number of microstates increases because more energy levels are accessible.

According to the S = KB× ln W equation, when number of microstates increase, entropy also gets increased.

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Answer 3

Question

Chapter 13, Problem 1E

Interpretation Introduction

(a)

Interpretation:

When increasing the length of the box to 2 L for fixed total energy, the change in the number of accessible microstates and the entropy of the system should be explained.

Concept introduction:

Microstates is a specific microscopic configuration describing how the particles of a system are distributed among the available energy levels.

In a system, the entropy of a system depends on the total number of possible microscopic states by the Boltzmann relation as shown below:

S = KB× ln W

Here, KB is Boltzmann constant, S is entropy and W is number of microstates.

Expert Solution

Answer to Problem 1E

Number of microstates and the entropy increases.

Explanation of Solution

Given information:

Number of particles = 5

1D box length = L

When the length of the box is increased to 2 L, the number of the microstates increases for fixed total energy. the energy levels are shifted to lower values and are more closely spaced. Therefore,

more energy levels are accessible

According to the S = KB× ln W equation, when number of microstates increase, entropy also gets increased.

Interpretation Introduction

(b)

Interpretation:

Whenthe total energy for constant box length is increased, the change in the number of accessible microstates and the entropy of the system should be explained.

Concept introduction:

Microstates is a specific microscopic configuration describing how the particles of a system are distributed among the available energy levels.

In a system, the entropy of a system depends on the total number of possible microscopic states by the Boltzmann relation as shown below:

S = KB× ln W

Here, KB is Boltzmann constant, S is entropy and W is number of microstates.

Expert Solution

Answer to Problem 1E

Number of microstates and the entropy increases.

Explanation of Solution

Given information:

Number of particles = 5

1D box length = L

With the increase of total energy, the number of microstates increases because more energy levels are accessible.

According to the S = KB× ln W equation, when number of microstates increase, entropy also gets increased.

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Answer 4

Question

Chapter 13, Problem 1E

Interpretation Introduction

(a)

Interpretation:

When increasing the length of the box to 2 L for fixed total energy, the change in the number of accessible microstates and the entropy of the system should be explained.

Concept introduction:

Microstates is a specific microscopic configuration describing how the particles of a system are distributed among the available energy levels.

In a system, the entropy of a system depends on the total number of possible microscopic states by the Boltzmann relation as shown below:

S = KB× ln W

Here, KB is Boltzmann constant, S is entropy and W is number of microstates.

Expert Solution

Answer to Problem 1E

Number of microstates and the entropy increases.

Explanation of Solution

Given information:

Number of particles = 5

1D box length = L

When the length of the box is increased to 2 L, the number of the microstates increases for fixed total energy. the energy levels are shifted to lower values and are more closely spaced. Therefore,

more energy levels are accessible

According to the S = KB× ln W equation, when number of microstates increase, entropy also gets increased.

Interpretation Introduction

(b)

Interpretation:

Whenthe total energy for constant box length is increased, the change in the number of accessible microstates and the entropy of the system should be explained.

Concept introduction:

Microstates is a specific microscopic configuration describing how the particles of a system are distributed among the available energy levels.

In a system, the entropy of a system depends on the total number of possible microscopic states by the Boltzmann relation as shown below:

S = KB× ln W

Here, KB is Boltzmann constant, S is entropy and W is number of microstates.

Expert Solution

Answer to Problem 1E

Number of microstates and the entropy increases.

Explanation of Solution

Given information:

Number of particles = 5

1D box length = L

With the increase of total energy, the number of microstates increases because more energy levels are accessible.

According to the S = KB× ln W equation, when number of microstates increase, entropy also gets increased.

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Answer 5

Chapter 13, Problem 1E

Interpretation Introduction

(a)

Interpretation:

When increasing the length of the box to 2 L for fixed total energy, the change in the number of accessible microstates and the entropy of the system should be explained.

Concept introduction:

Microstates is a specific microscopic configuration describing how the particles of a system are distributed among the available energy levels.

In a system, the entropy of a system depends on the total number of possible microscopic states by the Boltzmann relation as shown below:

S = KB× ln W

Here, KB is Boltzmann constant, S is entropy and W is number of microstates.

Expert Solution

Answer to Problem 1E

Number of microstates and the entropy increases.

Explanation of Solution

Given information:

Number of particles = 5

1D box length = L

When the length of the box is increased to 2 L, the number of the microstates increases for fixed total energy. the energy levels are shifted to lower values and are more closely spaced. Therefore,

more energy levels are accessible

According to the S = KB× ln W equation, when number of microstates increase, entropy also gets increased.

Interpretation Introduction

(b)

Interpretation:

Whenthe total energy for constant box length is increased, the change in the number of accessible microstates and the entropy of the system should be explained.

Concept introduction:

Microstates is a specific microscopic configuration describing how the particles of a system are distributed among the available energy levels.

In a system, the entropy of a system depends on the total number of possible microscopic states by the Boltzmann relation as shown below:

S = KB× ln W

Here, KB is Boltzmann constant, S is entropy and W is number of microstates.

Expert Solution

Answer to Problem 1E

Number of microstates and the entropy increases.

Explanation of Solution

Given information:

Number of particles = 5

1D box length = L

With the increase of total energy, the number of microstates increases because more energy levels are accessible.

According to the S = KB× ln W equation, when number of microstates increase, entropy also gets increased.

Answer 6

Chapter 13, Problem 1E

Interpretation Introduction

(a)

Interpretation:

When increasing the length of the box to 2 L for fixed total energy, the change in the number of accessible microstates and the entropy of the system should be explained.

Concept introduction:

Microstates is a specific microscopic configuration describing how the particles of a system are distributed among the available energy levels.

In a system, the entropy of a system depends on the total number of possible microscopic states by the Boltzmann relation as shown below:

S = KB× ln W

Here, KB is Boltzmann constant, S is entropy and W is number of microstates.

Expert Solution

Answer to Problem 1E

Number of microstates and the entropy increases.

Explanation of Solution

Given information:

Number of particles = 5

1D box length = L

When the length of the box is increased to 2 L, the number of the microstates increases for fixed total energy. the energy levels are shifted to lower values and are more closely spaced. Therefore,

more energy levels are accessible

According to the S = KB× ln W equation, when number of microstates increase, entropy also gets increased.

Answer 7

Chapter 13, Problem 1E

Interpretation Introduction

(a)

Interpretation:

When increasing the length of the box to 2 L for fixed total energy, the change in the number of accessible microstates and the entropy of the system should be explained.

Concept introduction:

Microstates is a specific microscopic configuration describing how the particles of a system are distributed among the available energy levels.

In a system, the entropy of a system depends on the total number of possible microscopic states by the Boltzmann relation as shown below:

S = KB× ln W

Here, KB is Boltzmann constant, S is entropy and W is number of microstates.

Answer 8

Expert Solution

Answer to Problem 1E

Number of microstates and the entropy increases.

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

Given information:

Number of particles = 5

1D box length = L

When the length of the box is increased to 2 L, the number of the microstates increases for fixed total energy. the energy levels are shifted to lower values and are more closely spaced. Therefore,

more energy levels are accessible

According to the S = KB× ln W equation, when number of microstates increase, entropy also gets increased.

Answer 13

Interpretation Introduction

(b)

Interpretation:

Whenthe total energy for constant box length is increased, the change in the number of accessible microstates and the entropy of the system should be explained.

Concept introduction:

Microstates is a specific microscopic configuration describing how the particles of a system are distributed among the available energy levels.

In a system, the entropy of a system depends on the total number of possible microscopic states by the Boltzmann relation as shown below:

S = KB× ln W

Here, KB is Boltzmann constant, S is entropy and W is number of microstates.

Expert Solution

Answer to Problem 1E

Number of microstates and the entropy increases.

Explanation of Solution

Given information:

Number of particles = 5

1D box length = L

With the increase of total energy, the number of microstates increases because more energy levels are accessible.

According to the S = KB× ln W equation, when number of microstates increase, entropy also gets increased.

Answer 14

Interpretation Introduction

(b)

Interpretation:

Whenthe total energy for constant box length is increased, the change in the number of accessible microstates and the entropy of the system should be explained.

Concept introduction:

Microstates is a specific microscopic configuration describing how the particles of a system are distributed among the available energy levels.

In a system, the entropy of a system depends on the total number of possible microscopic states by the Boltzmann relation as shown below:

S = KB× ln W

Here, KB is Boltzmann constant, S is entropy and W is number of microstates.

Answer 15

Expert Solution

Answer to Problem 1E

Number of microstates and the entropy increases.

Answer 16

Expert Solution

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Explanation of Solution

Given information:

Number of particles = 5

1D box length = L

With the increase of total energy, the number of microstates increases because more energy levels are accessible.

According to the S = KB× ln W equation, when number of microstates increase, entropy also gets increased.

Answer 20

Ch. 13 - Prob. 1E Ch. 13 - Consider a sample of ideal gas initially in a...Ch. 13 - Prob. 3E Ch. 13 - Prob. 4E Ch. 13 - Indicate whether each of the following changes...Ch. 13 - Arrange the entropy changes of the following...Ch. 13 - Prob. 7E Ch. 13 - Prob. 8E Ch. 13 - Indicate whether entropy increases or decreases in...Ch. 13 - Which substance in each of the following pairs...

Answer to Problem 1E

Explanation of Solution

Answer to Problem 1E

Explanation of Solution

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