For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and checkthe appropriate box.Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions- just focus on the first stable product you expect to form in solution.?NH2MgBrWill the first product that forms in this reactioncreate a new CC bond?○ Yes○ NoMgBr?Will the first product that forms in this reactioncreate a new CC bond?O YesO NoClick and drag to start drawing astructure.:☐GxcoloArHE

Approach to solving the question: First you need to observe that in each reaction above the arrow…

Answered: For each reaction below, decide if the…

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter24: Carboxylic Acids & Derivatives

Section: Chapter Questions

Problem 24E

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For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions just focus on the first stable product you expect to form in solution. MgBr NH2 MgCl ? Will the first product that forms in this reaction create a new C-C bond? Yes No Will the first product that forms in this reaction create a new C-C bond? Yes No Click and drag to start drawing a structure. Π : X G P 5
For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 MgBr Will the first product that forms in this reaction create a new CC bond? 1。 MgBr 00 Yes ○ No ? Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No. Click and drag to start drawing a structure. ✗ ח' :
For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced st conditions just fo ts: for this problem, don't worry if you think this product will continue to react under the current he first stable product you expect to form in solution. о о + ? Will the first product that forms in this reaction create a new CC bond? ملی MgBr ? Yes O No Will the first product that forms in this reaction create a new C-C bond? O Yes No ? 8民口 X olo : G Undo Q P
Draw both resonance structures of the most stable carbocation intermediate in the reaction shown. + HCI • You do not have to consider stereochemistry. • Do not include anionic counter-ions, e.g., I, in your answer. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate resonance structures using the → symbol from the drop-down menu. H₂ H₁₂ C C HECH H₂ C H2Cl H ? ▾ n CH₂ H₁₂ C HE HC CH H₂ H2 ChemDoodle H₁₂ CH2 HC C Cl H ? ChemDoodle F n [F
Draw both resonance structures of the most stable carbocation intermediate in the reaction shown. + HCI You do not have to consider stereochemistry. • Do not include anionic counter-ions, e.g., I, in your answer. • • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right Separate resonance structures using the symbol from the drop-down menu. ← - CHA ? n ChemDoodle
20
Use the dropdown menu to indicate whether the rate of the reaction shown below will increase, decrease, or remain the same when the reaction conditions are changed to X or to Y or to Z (see below). NaN3 'N3 Br CH3CN X: Change the leaving group from Br to CI Y: Increase the concentration of haloalkane Z: Increase the concentration of NaN3 X: choose your answer.. ^ Y: choose your answer... V Z: choose your answer... choose your answer... Remain the same Nex Decrease Increase
HO Cro3 H2S04 Edit Click on the drawing box above to activate the MarvinSketch drawing tool and then draw your answer to this question. If there is no reaction, then check the "no reaction" box below. no reaction
3. Drawing Reaction Mechanism Arrows For the reactions that have TWO starting materials, indicate and label which species is the nucleophile and which is the electrophile. (HINT: Look at the reactants and look at the products to see where bonds form and where bonds break! Using your pK, table and bond polarity predictions will help!) Draw curved arrows to show the movement of electrons for Bond Forming and Bond Breaking in each of the reaction steps Finally, identify and label what type of elementary step is represented for each mechanism -н Name of Elementary Step н-СI: а. Н -H Name of Elementary Step: нс-о-н b. О-н CHз н Н Name of Elementary Step Н-Сі: с O-H CH3 CНз
Draw both resonance structures of the most stable carbonation intermediate in the reaction shown below
ited Draw both resonance structures of the most stable carbocation intermediate in the reaction shown. od m... • You do not have to consider stereochemistry. . Do not include anionic counter-ions, e.g., I', in your answer. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom Separate resonance structures using the → symbol from the drop-down menu. ● CH4 + ? HBr
You are given the following reactions to complete in lab. However, you recognize an issue with the reaction. 1. Determine why the reactions will not work or why the reactions will give a poor yield? 2. How can you resolve the issues and run the reactions to obtain a better yield? Fix the reactions by redrawing each reaction with the solution (corrected starting materials/reagents/products/etc.).

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