a. Draw a complete arrow pushing mechanism for the following. Is this the thermodynamic or the kinetic product? Use your mechanism to explain your choice. Draw all the resonance. HBr Br
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- 3. Draw the major product in the following reaction and reaction mechanism. Remember when drawing a reaction mechanism, you need to show all nonbonding electron pairs, formal charges, electron flow arrows, and all resonance structures. What is the name of this mechanism? Determine and circle whether the substituent is an activator or deactivator. Explain what is meant by being an activator or deactivator and circle the single resonance structure that supports your decision regarding the substituent in the starting material. OH CH₂CH₂CH₂Br FeBrNitesh1. Consider two SN1 reactions: (A) water and tert-butylbromide and, (B) water and 2- bromopropane, both having the same concentration of reactants. a. Draw the reactants (nucleophile and substrate) for both reactions (A & B). b. Draw a curved arrow mechanism for the reaction between water and tert-butylbromide (A). Show all reactants, intermediates, and products do not show transition state structures. c. Draw products of each reaction (A & B). d. Predict which reaction will be faster (A or B). - e. Draw an energy vs. reaction coordinate diagram showing only the rate-determining step for both reactions on the same set of axes (axes available on the next page). Draw the reaction (A) with a dotted line and (B) with a solid line, and assume that the potential energies of the reactants are the same in both reactions (i.e. the only difference is in the energies of the two different transition states and resulting intermediates).
- Draw a curved arrow mechanism for the substitution reaction that will occur with the alkyl halide and nucleophile below, adding steps as necessary. Be sure to include all nonbonding electrons and all nonzero formal charges, and show all species that react or are formed in this reaction.2. Draw the product(s) of the following reaction and a mechanism. Include all resonance structures of the intermediate. AICI3Draw a curved arrow mechanism for the substitution reaction that will occur with the alkyl halide and nucleophile below, adding steps as necessary. Be sure to include all nonbonding electrons and all nonzero formal charges, and show all species that react or are formed in this reaction. ох Br H₂O
- 3. A) Show all the unique mono-halogenated products for the reaction below. Circle the major product. Br₂ light B) Show the formal arrow pushing mechanism for the first and second propagation step which leads to the radical intermediate of the major product. Be sure to draw in the hydrogen which is being abstracted. Draw the products.we will discuss whether a methoxy group is electron donating or electron withdrawing. We will see that there is a competition between two factors. The methoxy group might be considered electron-withdrawing because of induction, or it might be considered electron-donating because of resonance. Below are the resonance structures of compound 1. Draw the missing curved arrow(s) to convert the each resonance structure into the next one...Draw bith the higher molecular weight prlduct and the lowe weight product
- only answer part D. thank you1.Draw both resonance structures of the most stable carbocation intermediate in the reaction shown. + HCI •You do not have to consider stereochemistry. Do not include anionic counter-ions, e.g., I, in your answer. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom Separate resonance structures using the → symbol from the drop-down menu. • Draw both resonance structures of the most stable carbocation intermediate in the reaction shown. + HCI • You do not have to consider stereochemistry. • Do not include anionic counter-ions, e.g., I, in your answer. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom righ Separate resonance structures using the symbol from the drop-down menu. • - Draw both resonance structures of the most stable carbocation intermediate in the reaction shown. + HBr • You do not have to consider stereochemistry. Do not include anionic counter-ions, e.g., I, in your answer. •…