ORGANIC CHEMISTRY (LL)-PACKAGE
ORGANIC CHEMISTRY (LL)-PACKAGE
8th Edition
ISBN: 9781319316389
Author: VOLLHARDT
Publisher: MAC HIGHER
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Chapter 8.7, Problem 8.16E

(a)

Interpretation Introduction

Interpretation: Synthesis of pentan-1-ol (alcohol) using a starting material containing no more than four carbons needs to be explained.

Concept Introduction: Organometallic reagents of lithium used in the formation of alcohol by reacting with carbonyl compounds. In organometallic reagent, the alkyl part is negatively charged which acts as a nucleophile and attacks the carbonyl carbon to form alcohol.

In this reaction, the number of carbons in the carbonyl chain increases.

(b)

Interpretation Introduction

Interpretation: Synthesis of heptan-7-ol (alcohol) using a starting material containing no more than four carbons needs to be explained.

Concept Introduction: Organometallic reagents of magnesium that is Grignard reagent (RMgX) used in the formation of alcohol by reacting with carbonyl compounds. In organometallic reagent, the alkyl part is negatively charged which acts as a nucleophile and attacks the carbonyl carbon to form alcohol.

(c)

Interpretation Introduction

Interpretation: Synthesis of heptan-7-ol (alcohol) using a starting material containing no more than four carbons needs to be explained.

Concept Introduction: Organometallic reagents of lithium used in the formation of alcohol by reacting with carbonyl compounds. In organometallic reagent, the alkyl part is negatively charged which acts as a nucleophile and attacks the carbonyl carbon to form alcohol.

In this reaction, the number of carbons in the carbonyl chain increases.

(d)

Interpretation Introduction

Interpretation: Synthesis of 2-methylpentan-2-ol (alcohol) using a starting material containing no more than four carbons needs to be explained.

Concept Introduction: Organometallic reagents of magnesium that is Grignard reagent (RMgX) used in the formation of alcohol by reacting with carbonyl compounds. In organometallic reagent, the alkyl part is negatively charged which acts as a nucleophile and attacks the carbonyl carbon to form alcohol.

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1) Calculate the longest and shortest wavelengths in the Lyman and Paschen series. 2) Calculate the ionization energy of He* and L2+ ions in their ground states. 3) Calculate the kinetic energy of the electron emitted upon irradiation of a H-atom in ground state by a 50-nm radiation.
Calculate the ionization energy of He+ and Li²+ ions in their ground states. Thannnxxxxx sirrr Ahehehehehejh27278283-4;*; shebehebbw $+$;$-;$-28283773838 hahhehdva
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