Videos
(a)
Interpretation: Structure of
Concept introduction: In accordance with
As per IUPAC recommendations, longest chain found in a continuous manner in a branched molecule is chosen as parent chain. The longest chain must contain the alcohol functional group.The chain carbons are numbered so as to provide least numeral position towards the end in vicinity to
In
(b)
Interpretation: Structure of
Concept introduction:In accordance with IUPAC systematic nomenclature of alcohols can be derived from the parent alkane with “e” dropped and replaced by “ol” suffix.
As per IUPAC recommendations, longest chain found in a continuous manner in a branched molecule is chosen as parent chain. The longest chain must contain the alcohol functional group.The chain carbons are numbered so as to provide least numeral position towards the end in vicinity to
In alkanes, the positions of side chains or alkyl substituents are indicated by lowest numeral places before prefix.
(c)
Interpretation: Structure of
Concept introduction:In accordance with IUPAC systematic nomenclature of alcohols can be derived from the parent alkane with “e” dropped and replaced by “ol” suffix.
As per IUPAC recommendations, longest chain found in a continuous manner in a branched molecule is chosen as parent chain. The longest chain must contain the alcohol functional group.The chain carbons are numbered so as to provide least numeral position towards the end in vicinity to
In alkanes, the positions of side chains or alkyl substituents are indicated by lowest numeral places before prefix.
In order to assign absolute configuration of R and S, Cahn−Ingold−Prelog rules are used and the first step is to assign the priority order on the basis of
The Fischer projection is written along with the priorities assigned and groups are interchangedbetween adjacent places so as to obtain lowest priority group at the bottom or lowest priority.
If the groups now are arranged are read from highest towards least in clockwise fashion the R is assigned to the stereocenter, if the rotation is anticlockwise the S is assigned at the configuration.
(d)
Interpretation: Structure of
Concept introduction:In accordance with IUPAC systematic nomenclature of alcohols can be derived from the parent alkane with “e” dropped and replaced by “ol” suffix.
As per IUPAC recommendations, longest chain found in a continuous manner in a branched molecule is chosen as parent chain. The longest chain must contain the alcohol functional group.The chain carbons are numbered so as to provide least numeral position towards the end in vicinity to
In alkanes, the positions of side chains or alkyl substituents are indicated by lowest numeral places before prefix.
(e)
Interpretation: Structure of
Concept introduction:In accordance with IUPAC systematic nomenclature of alcohols can be derived from the parent alkane with “e” dropped and replaced by “ol” suffix.
As per IUPAC recommendations, longest chain found in a continuous manner in a branched molecule is chosen as parent chain. The longest chain must contain the alcohol functional group.The chain carbons are numbered so as to provide least numeral position towards the end in vicinity to
In alkanes, the positions of side chains or alkyl substituents are indicated by lowest numeral places before prefix.
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Chapter 8 Solutions
ORGANIC CHEMISTRY (LL)-PACKAGE
- Q1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label each compound as chiral or achiral. OH HO CI Br H CI CI Br CI CI Xf x f g Br D OH Br Br H₂N R. IN Ill I -N S OMe D II H CO₂H 1/111 DuckDuckGarrow_forwardThese are synthesis questions. You need to show how the starting material can be converted into the product(s) shown. You may use any reactions we have learned. Show all the reagents you need. Show each molecule synthesized along the way and be sure to pay attention to the regiochemistry and stereochemistry preferences for each reaction. If a racemic molecule is made along the way, you need to draw both enantiomers and label the mixture as "racemic". All of the carbon atoms of the products must come from the starting material! ? H Harrow_forwardQ5: Draw every stereoisomer for 1-bromo-2-chloro-1,2-difluorocyclopentane. Clearly show stereochemistry by drawing the wedge-and-dashed bonds. Describe the relationship between each pair of the stereoisomers you have drawn.arrow_forward
- Classify each pair of molecules according to whether or not they can participate in hydrogen bonding with one another. Participate in hydrogen bonding CH3COCH3 and CH3COCH2CH3 H2O and (CH3CH2)2CO CH3COCH3 and CH₂ CHO Answer Bank Do not participate in hydrogen bonding CH3CH2OH and HCHO CH3COCH2CH3 and CH3OHarrow_forwardNonearrow_forwardQ4: Comparing (3S,4S)-3,4-dimethylhexane and (3R,4S)-3,4-dimethylhexane, which one is optically active? Briefly explain.arrow_forward
- Nonearrow_forwardNonearrow_forwardGiven the standard enthalpies of formation for the following substances, determine the reaction enthalpy for the following reaction. 4A (g) + 2B (g) → 2C (g) + 7D (g) AHrxn =?kJ Substance AH in kJ/mol A (g) - 20.42 B (g) + 32.18 C (g) - 72.51 D (g) - 17.87arrow_forward
- Determine ASran for Zn(s) + 2HCl(aq) = ZnCl2(aq) + H2(aq) given the following information: Standard Entropy Values of Various Substance Substance So (J/mol • K) 60.9 Zn(s) HCl(aq) 56.5 130.58 H2(g) Zn2+(aq) -106.5 55.10 CI (aq)arrow_forward3) Catalytic hydrogenation of the compound below produced the expected product. However, a byproduct with molecular formula C10H12O is also formed in small quantities. What is the by product?arrow_forwardWhat is the ΔHorxn of the reaction? NaOH(aq) + HCl(aq) → H2O(l) + NaCl(aq) ΔHorxn 1= ________ kJ/molarrow_forward
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