The major product of indicated reaction should be identified. Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below. Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below; Any organic compound must have no plane of symmetry in order to be chiral or optically active. The compounds with any plane of symmetry are achiral and optically inactive.

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Answer 1

Question

Chapter 8, Problem 36P

(a)

Interpretation Introduction

Interpretation:The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

Any organic compound must have no plane of symmetry in order to be chiral or optically active. The compounds with any plane of symmetry are achiral and optically inactive.

(b)

Interpretation Introduction

Interpretation:The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.The work up finally yields alcohol as illustrated below:

(c)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

(d)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.The work up finally yields alcohol as illustrated below:

(e)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

(f)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

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Answer 2

Question

Chapter 8, Problem 36P

(a)

Interpretation Introduction

Interpretation:The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

Any organic compound must have no plane of symmetry in order to be chiral or optically active. The compounds with any plane of symmetry are achiral and optically inactive.

(b)

Interpretation Introduction

Interpretation:The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.The work up finally yields alcohol as illustrated below:

(c)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

(d)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.The work up finally yields alcohol as illustrated below:

(e)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

(f)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

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Answer 3

Question

Chapter 8, Problem 36P

(a)

Interpretation Introduction

Interpretation:The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

Any organic compound must have no plane of symmetry in order to be chiral or optically active. The compounds with any plane of symmetry are achiral and optically inactive.

(b)

Interpretation Introduction

Interpretation:The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.The work up finally yields alcohol as illustrated below:

(c)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

(d)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.The work up finally yields alcohol as illustrated below:

(e)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

(f)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

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Answer 4

Question

Chapter 8, Problem 36P

(a)

Interpretation Introduction

Interpretation:The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

Any organic compound must have no plane of symmetry in order to be chiral or optically active. The compounds with any plane of symmetry are achiral and optically inactive.

(b)

Interpretation Introduction

Interpretation:The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.The work up finally yields alcohol as illustrated below:

(c)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

(d)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.The work up finally yields alcohol as illustrated below:

(e)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

(f)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

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Answer 5

Chapter 8, Problem 36P

(a)

Interpretation Introduction

Interpretation:The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

Any organic compound must have no plane of symmetry in order to be chiral or optically active. The compounds with any plane of symmetry are achiral and optically inactive.

(b)

Interpretation Introduction

Interpretation:The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.The work up finally yields alcohol as illustrated below:

(c)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

(d)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.The work up finally yields alcohol as illustrated below:

(e)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

(f)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

Answer 6

Chapter 8, Problem 36P

(a)

Interpretation Introduction

Interpretation:The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

Any organic compound must have no plane of symmetry in order to be chiral or optically active. The compounds with any plane of symmetry are achiral and optically inactive.

Answer 7

Chapter 8, Problem 36P

(a)

Interpretation Introduction

Interpretation:The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

Any organic compound must have no plane of symmetry in order to be chiral or optically active. The compounds with any plane of symmetry are achiral and optically inactive.

Answer 8

(b)

Interpretation Introduction

Interpretation:The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.The work up finally yields alcohol as illustrated below:

Answer 9

(b)

Interpretation Introduction

Interpretation:The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.The work up finally yields alcohol as illustrated below:

Answer 10

(c)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

Answer 11

(c)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

Answer 12

(d)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.The work up finally yields alcohol as illustrated below:

Answer 13

(d)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

The aluminum and lithium in these reagents such as LiAlH4 tend to push the electron of Al-H bond towards carbonyl carbon.The work up finally yields alcohol as illustrated below:

Answer 14

(e)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

Answer 15

(e)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

Answer 16

(f)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

Answer 17

(f)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of B-H bond towards carbonyl carbon as illustrated below;

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 8.1 - Prob. 8.1E Ch. 8.1 - Prob. 8.2E Ch. 8.3 - Prob. 8.4TIY Ch. 8.3 - Prob. 8.5E Ch. 8.3 - Prob. 8.6E Ch. 8.4 - Prob. 8.7E Ch. 8.5 - Prob. 8.8E Ch. 8.5 - Prob. 8.9E Ch. 8.5 - Prob. 8.10E Ch. 8.5 - Prob. 8.11E

Solution Summary: The author explains that the carbonyl bond is polar and undergoes hydride and proton addition at carbon and oxygen.

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