ORGANIC CHEMISTRY (LL)-PACKAGE
ORGANIC CHEMISTRY (LL)-PACKAGE
8th Edition
ISBN: 9781319316389
Author: VOLLHARDT
Publisher: MAC HIGHER
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Chapter 7, Problem 67P
Interpretation Introduction

Interpretation: The mechanism for the given reaction of tertiary alkyl halide with methoxide base to form alkene needs to be identified.

Concept introduction: Haloalkanes react with water and formed alkene via nucleophilic elimination reaction. In this reaction, halogen leaves the molecule and carbocation is formed. The nucleophile a nucleophile acts as a base and extracts a proton from carbocation resulting in the formation of the alkene.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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