
Concept explainers
Interpretation:A reasonable rate expression corresponding to chlorination of methane reaction should be proposed.
Concept introduction:The mechanism for monochlorination comprises of three stages illustrated as follows:
Step 1- Initiation via homolytic cleavage of
Step 2: Propagation: In the first of the propagation steps
radical generated from step 1 abstracts hydrogen radical from methane as follows:
In subsequent propagation step chloromethyl radical abstracts
Step3: Termination: Radicals generated in propagation steps get quenched upon the combination with one another. Thus termination steps are essentially the radical− radical combination illustrated as follows:

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Chapter 7 Solutions
ORGANIC CHEMISTRY (LL)-PACKAGE
- Draw the mechanism using the arrows on conventions, including all formal charges and correct arrows. If stereochemical distinction can be made they should be included in the structure of the products.arrow_forwardDraw the epoxide formed when the following alkene is treated with mCPBA. Click the "draw structure" button to launch the drawing utility. draw structure ...arrow_forwardRank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. Explanation Check CF3 (Choose one) OH (Choose one) H (Choose one) (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacyarrow_forward
- Identifying electron-donating and electron-withdrawing effects For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects Resonance Effects Overall Electron-Density CF3 O donating O donating O electron-rich O withdrawing withdrawing O no inductive effects O no resonance effects O electron-deficient O similar to benzene OCH3 Explanation Check O donating O donating ○ withdrawing withdrawing O no inductive effects no resonance effects electron-rich electron-deficient O similar to benzene Х © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centerarrow_forwardThe acid-base chemistry of both EDTA and EBT are important to ensuring that the reactions proceed as desired, thus the pH is controlled using a buffer. What percent of the EBT indicator will be in the desired HIn2- state at pH = 10.5. pKa1 = 6.2 and pKa2 = 11.6 of EBTarrow_forwardCUE COLUMN NOTES (A. Determine Stereoisomers it has ⑤ Identify any meso B compounds cl Br cl -c-c-c-c-¿- 1 CI C- | 2,4-Dichloro-3-bromopentanearrow_forward
- The acid-base chemistry of both EDTA and EBT are important to ensuring that the reactions proceed as desired, thus the pH is controlled using a buffer. What percent of the EBT indicator will be in the desired HIn2- state at pH = 10.5. pKa1 = 6.2 and pKa2 = 11.6 of EBTarrow_forwardWhat does the phrase 'fit for purpose' mean in relation to analytical chemistry? Please provide examples too.arrow_forwardFor each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects Resonance Effects Overall Electron-Density × NO2 ○ donating O donating O withdrawing O withdrawing O electron-rich electron-deficient no inductive effects O no resonance effects O similar to benzene E [ CI O donating withdrawing O no inductive effects Explanation Check ○ donating withdrawing no resonance effects electron-rich electron-deficient O similar to benzene © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center Accesarrow_forward
