ORGANIC CHEMISTRY (LL)-PACKAGE
ORGANIC CHEMISTRY (LL)-PACKAGE
8th Edition
ISBN: 9781319316389
Author: VOLLHARDT
Publisher: MAC HIGHER
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Chapter 7, Problem 47P

(a)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane and KCl in DMF.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(b)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KI in DMF.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(c)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KCl in CH3NO2.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(d)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with NH3 in CH3CH2OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(e)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with NaOCH2CH3 in CH3CH2OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(f)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with CH3CH2OH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(g)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with KOC(CH3)3 in (CH3)3COH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(h)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with (CH3)3P.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(i)

Interpretation Introduction

Interpretation: The major product and mechanism needs to be determined in the reaction between 2-bromo-2methylpropane with CH3COOH.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

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