ORGANIC CHEMISTRY (LL)-PACKAGE
ORGANIC CHEMISTRY (LL)-PACKAGE
8th Edition
ISBN: 9781319316389
Author: VOLLHARDT
Publisher: MAC HIGHER
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Chapter 7.1, Problem 7.1E
Interpretation Introduction

Interpretation: The reason behind compound A completely stable in ethanol while B converted into another compound rapidly should be explained.

Concept introduction: The haloalkanes react with various solvents such as water, ethanol to give substituted products that have halide replaced by nucleophilic part of solvent. Such reactions are termed solvolysis. The experimental order of reactive for three types of halides towards solvolysis is as follows:

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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