ORGANIC CHEMISTRY (LL)-PACKAGE
ORGANIC CHEMISTRY (LL)-PACKAGE
8th Edition
ISBN: 9781319316389
Author: VOLLHARDT
Publisher: MAC HIGHER
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Chapter 7, Problem 27P

(a)

Interpretation Introduction

Interpretation:

The two major substitution products of the following reaction should be drawn along with the mechanism for the formation.

  ORGANIC CHEMISTRY (LL)-PACKAGE, Chapter 7, Problem 27P

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as SN1 and SN2 reaction.

Cis-Trans isomers are known as geometric isomers. In Cis isomers, functional groups are present on same side of the carbon chain whereas in Tans isomers, functional groups are present on different or opposite side of the chain.

(b)

Interpretation Introduction

Interpretation:

The reaction mixture should be monitored which reveals an isomer of the starting material is generated as an intermediate along with its structure and its preparation.

Concept Introduction:

The chemical reaction in which one functional group is substituted by another functional group is known as substitution reaction.

The chemical reaction in which displacement of leaving group occurs by a nucleophile is known as nucleophilic substitution reaction.

The reaction between nucleophile (electron pair donor) and electrophile (electron pair acceptor) is known as nucleophilic substitution reaction. It is classified as SN1 and SN2 reaction.

Cis-Trans isomers are known as geometric isomers. In Cis isomers, functional groups are present on same side of the carbon chain whereas in Tans isomers, functional groups are present on different or opposite side of the chain.

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1) Calculate the longest and shortest wavelengths in the Lyman and Paschen series. 2) Calculate the ionization energy of He* and L2+ ions in their ground states. 3) Calculate the kinetic energy of the electron emitted upon irradiation of a H-atom in ground state by a 50-nm radiation.
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