The reaction of bromoalkane A to D in the presence of NaN 3 , DMF needs to be discussed. Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry . In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene .

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Answer 1

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Chapter 7, Problem 65P

(a)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of NaN₃, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(b)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of LDA, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(c)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of NaOH, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(d)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of sodium acetate and acetic acid needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(e)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence methanol needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

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4. Draw and label all possible isomers for [M(py)3(DMSO)2(CI)] (py = pyridine, DMSO dimethylsulfoxide).

Answer 2

Question

Chapter 7, Problem 65P

(a)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of NaN₃, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(b)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of LDA, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(c)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of NaOH, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(d)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of sodium acetate and acetic acid needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(e)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence methanol needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

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Answer 3

Question

Chapter 7, Problem 65P

(a)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of NaN₃, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(b)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of LDA, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(c)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of NaOH, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(d)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of sodium acetate and acetic acid needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(e)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence methanol needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

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Answer 4

Question

Chapter 7, Problem 65P

(a)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of NaN₃, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(b)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of LDA, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(c)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of NaOH, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(d)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of sodium acetate and acetic acid needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(e)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence methanol needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

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Answer 5

Chapter 7, Problem 65P

(a)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of NaN₃, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(b)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of LDA, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(c)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of NaOH, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(d)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of sodium acetate and acetic acid needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

(e)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence methanol needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 6

Chapter 7, Problem 65P

(a)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of NaN₃, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 7

Chapter 7, Problem 65P

(a)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of NaN₃, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 8

(b)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of LDA, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 9

(b)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of LDA, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 10

(c)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of NaOH, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 11

(c)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of NaOH, DMF needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 12

(d)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of sodium acetate and acetic acid needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 13

(d)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence of sodium acetate and acetic acid needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 14

(e)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence methanol needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 15

(e)

Interpretation Introduction

Interpretation: The reaction of bromoalkane A to D in the presence methanol needs to be discussed.

Concept Introduction: Nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry. In the nucleophillic substitution reaction, a leaving group is replaced with a nucleophile and in the elimination reaction rearrangement takes place resulting formation of an alkene.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 7.1 - Prob. 7.1E Ch. 7.2 - Prob. 7.2E Ch. 7.3 - Prob. 7.3E Ch. 7.3 - Prob. 7.5TIY Ch. 7.4 - Prob. 7.7TIY Ch. 7.5 - Prob. 7.9TIY Ch. 7.6 - Prob. 7.10E Ch. 7.7 - Prob. 7.11E Ch. 7.7 - Prob. 7.12E Ch. 7.7 - Prob. 7.13E

Solution Summary: The author explains that nucleophillic substitution and elimination reactions are two types of the reactions, playing important role in organic chemistry.

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