Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781133949640
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Textbook Question
Chapter 7, Problem 32PS
Explain each answer briefly.
- (a) Rank the following in order of increasing atomic radius: O, S, and F.
- (b) Which has the largest ionization energy: P, Si, S, or Se?
- (c) Place the following in order of increasing radius: O2−, N3−, and F−.
- (d) Place the following in order of increasing ionization energy: Cs, Sr, and Ba.
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יווי
10
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3.5
3
2.5
2
1.5
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[ppm]
3.5
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6 [ppm]
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2H2S(g)+3O2(g)→2SO2(g)+2H2O(g)
A 1.2mol sample of H2S(g) is combined with excess O2(g), and the reaction goes to completion.
Question
Which of the following predicts the theoretical yield of SO2(g) from the reaction?
Responses
1.2 g
Answer A: 1.2 grams
A
41 g
Answer B: 41 grams
B
77 g
Answer C: 77 grams
C
154 g
Answer D: 154 grams
D
Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
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70
-26
60
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46
30
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115
10
1.0 0.9 0.8
0
-10
Chapter 7 Solutions
Chemistry & Chemical Reactivity
Ch. 7.1 - How many electrons can be accommodated in the n =...Ch. 7.1 - Prob. 2RCCh. 7.2 - Based on the Aufbau principle and the n + rule,...Ch. 7.3 - (a) What element has the configuration...Ch. 7.3 - Write one possible set of quantum numbers for the...Ch. 7.3 - Using the periodic table and without looking at...Ch. 7.3 - 1. What is the electron configuration of selenium...Ch. 7.3 - 2. Based on electron configurations, which of the...Ch. 7.4 - Prob. 1CYUCh. 7.4 - Prob. 1RC
Ch. 7.4 - Prob. 2RCCh. 7.4 - Which of the following species is most...Ch. 7.5 - Without looking at the figures for the periodic...Ch. 7.5 - What is the trend in sizes of the ions K+, S2, and...Ch. 7.5 - Prob. 2RCCh. 7.6 - Give the electron configurations for iron and the...Ch. 7.6 - Prob. 2QCh. 7.6 - Prob. 3QCh. 7.6 - Prob. 4QCh. 7.6 - Prob. 1RCCh. 7.6 - Prob. 2RCCh. 7.6 - The most common oxidation state of a rare earth...Ch. 7.6 - Prob. 6QCh. 7.6 - Prob. 7QCh. 7.6 - Use the atomic radii of scandium, yttrium,...Ch. 7.6 - Prob. 9QCh. 7.6 - Prob. 10QCh. 7 - Write the electron configurations for P and CI...Ch. 7 - Write the electron configurations for Mg and Ar...Ch. 7 - Using spdf notation, write the electron...Ch. 7 - Using spdf notation, give the electron...Ch. 7 - Prob. 5PSCh. 7 - Prob. 6PSCh. 7 - Use noble gas and spdf notations to depict...Ch. 7 - The lanthanides, once called the rare earth...Ch. 7 - Prob. 9PSCh. 7 - Prob. 10PSCh. 7 - What is the maximum number of electrons that can...Ch. 7 - What is the maximum number of electrons that can...Ch. 7 - Depict the electron configuration for magnesium...Ch. 7 - Depict the electron configuration for phosphorus...Ch. 7 - Using an orbital box diagram and noble gas...Ch. 7 - Using an orbital box diagram and noble gas...Ch. 7 - Using orbital box diagrams, depict an electron...Ch. 7 - Prob. 18PSCh. 7 - Prob. 19PSCh. 7 - Using orbital box diagrams and noble gas notation,...Ch. 7 - Manganese is found as MnO2 in deep ocean deposits....Ch. 7 - One compound found in alkaline batteries is NiOOH,...Ch. 7 - Prob. 23PSCh. 7 - Arrange the following elements in order of...Ch. 7 - Prob. 25PSCh. 7 - Prob. 26PSCh. 7 - Which of the following groups of elements is...Ch. 7 - Arrange the following atoms in order of increasing...Ch. 7 - Compare the elements Na, Mg, O, and P. (a) Which...Ch. 7 - Compare the elements B. Al, C, and Si. (a) Which...Ch. 7 - Explain each answer briefly. (a) Place the...Ch. 7 - Explain each answer briefly. (a) Rank the...Ch. 7 - Identify the element that corresponds to each of...Ch. 7 - Identify the element that corresponds to each of...Ch. 7 - Explain why the photoelectron spectra of hydrogen...Ch. 7 - Sketch the major features (number of peaks and...Ch. 7 - These questions are not designated as to type or...Ch. 7 - The deep blue color of sapphires comes from the...Ch. 7 - Using an orbital box diagram and noble gas...Ch. 7 - Prob. 40GQCh. 7 - Prob. 41GQCh. 7 - Prob. 42GQCh. 7 - Which of the following is not an allowable set of...Ch. 7 - A possible excited state for the H atom has an...Ch. 7 - The magnet in the following photo is made from...Ch. 7 - Name the element corresponding to each...Ch. 7 - Arrange the following atoms in order of increasing...Ch. 7 - Prob. 48GQCh. 7 - Answer the questions below about the elements A...Ch. 7 - Answer (he following questions about the elements...Ch. 7 - Which of the following ions are unlikely to be...Ch. 7 - Prob. 52GQCh. 7 - Answer each of the following questions: (a) Of the...Ch. 7 - Prob. 54GQCh. 7 - Prob. 55GQCh. 7 - Two elements in the second transition series (Y...Ch. 7 - Prob. 57GQCh. 7 - The configuration of an element is given here. (a)...Ch. 7 - Answer the questions below about the elements A...Ch. 7 - Answer the questions below concerning ground state...Ch. 7 - Nickel(II) formate [Ni(HCO2)2] is widely used as a...Ch. 7 - Spinets are solids with the general formula M2+...Ch. 7 - The following questions use concepts from this and...Ch. 7 - Which ions in the following list are not likely to...Ch. 7 - Answer the following questions about first...Ch. 7 - The ionization of the hydrogen atom can be...Ch. 7 - Compare the configurations below with two...Ch. 7 - Prob. 68SCQCh. 7 - Write electron configurations to show the first...Ch. 7 - Prob. 70SCQCh. 7 - (a) Explain why the sizes of atoms change when...Ch. 7 - Which of the following elements has the greatest...Ch. 7 - Prob. 73SCQCh. 7 - Prob. 74SCQCh. 7 - The energies of the orbitals in many elements have...Ch. 7 - The ionization energies for the removal of the...Ch. 7 - Using your knowledge of the trends in element...Ch. 7 - Prob. 78SCQCh. 7 - Prob. 79SCQCh. 7 - Prob. 80SCQCh. 7 - Thionyl chloride. SOCl2, is an important...Ch. 7 - Prob. 82SCQCh. 7 - Slaters rules are a way to estimate the effective...
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- Nonearrow_forward4. Draw and label all possible isomers for [M(py)3(DMSO)2(CI)] (py = pyridine, DMSO dimethylsulfoxide).arrow_forwardThe emission data in cps displayed in Table 1 is reported to two decimal places by the chemist. However, the instrument output is shown in Table 2. Table 2. Iron emission from ICP-AES Sample Blank Standard Emission, cps 579.503252562 9308340.13122 Unknown Sample 343.232365741 Did the chemist make the correct choice in how they choose to display the data up in Table 1? Choose the best explanation from the choices below. No. Since the instrument calculates 12 digits for all values, they should all be kept and not truncated. Doing so would eliminate significant information. No. Since the instrument calculates 5 decimal places for the standard, all of the values should be limited to the same number. The other decimal places are not significant for the blank and unknown sample. Yes. The way Saman made the standards was limited by the 250-mL volumetric flask. This glassware can report values to 2 decimal places, and this establishes our number of significant figures. Yes. Instrumental data…arrow_forward
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