Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781133949640
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Textbook Question
Chapter 7, Problem 35PS
Explain why the photoelectron spectra of hydrogen and helium each has one peak whereas that for lithium has two peaks. What would be the relative intensity of each of the peaks in these spectra?
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Chapter 7 Solutions
Chemistry & Chemical Reactivity
Ch. 7.1 - How many electrons can be accommodated in the n =...Ch. 7.1 - Prob. 2RCCh. 7.2 - Based on the Aufbau principle and the n + rule,...Ch. 7.3 - (a) What element has the configuration...Ch. 7.3 - Write one possible set of quantum numbers for the...Ch. 7.3 - Using the periodic table and without looking at...Ch. 7.3 - 1. What is the electron configuration of selenium...Ch. 7.3 - 2. Based on electron configurations, which of the...Ch. 7.4 - Prob. 1CYUCh. 7.4 - Prob. 1RC
Ch. 7.4 - Prob. 2RCCh. 7.4 - Which of the following species is most...Ch. 7.5 - Without looking at the figures for the periodic...Ch. 7.5 - What is the trend in sizes of the ions K+, S2, and...Ch. 7.5 - Prob. 2RCCh. 7.6 - Give the electron configurations for iron and the...Ch. 7.6 - Prob. 2QCh. 7.6 - Prob. 3QCh. 7.6 - Prob. 4QCh. 7.6 - Prob. 1RCCh. 7.6 - Prob. 2RCCh. 7.6 - The most common oxidation state of a rare earth...Ch. 7.6 - Prob. 6QCh. 7.6 - Prob. 7QCh. 7.6 - Use the atomic radii of scandium, yttrium,...Ch. 7.6 - Prob. 9QCh. 7.6 - Prob. 10QCh. 7 - Write the electron configurations for P and CI...Ch. 7 - Write the electron configurations for Mg and Ar...Ch. 7 - Using spdf notation, write the electron...Ch. 7 - Using spdf notation, give the electron...Ch. 7 - Prob. 5PSCh. 7 - Prob. 6PSCh. 7 - Use noble gas and spdf notations to depict...Ch. 7 - The lanthanides, once called the rare earth...Ch. 7 - Prob. 9PSCh. 7 - Prob. 10PSCh. 7 - What is the maximum number of electrons that can...Ch. 7 - What is the maximum number of electrons that can...Ch. 7 - Depict the electron configuration for magnesium...Ch. 7 - Depict the electron configuration for phosphorus...Ch. 7 - Using an orbital box diagram and noble gas...Ch. 7 - Using an orbital box diagram and noble gas...Ch. 7 - Using orbital box diagrams, depict an electron...Ch. 7 - Prob. 18PSCh. 7 - Prob. 19PSCh. 7 - Using orbital box diagrams and noble gas notation,...Ch. 7 - Manganese is found as MnO2 in deep ocean deposits....Ch. 7 - One compound found in alkaline batteries is NiOOH,...Ch. 7 - Prob. 23PSCh. 7 - Arrange the following elements in order of...Ch. 7 - Prob. 25PSCh. 7 - Prob. 26PSCh. 7 - Which of the following groups of elements is...Ch. 7 - Arrange the following atoms in order of increasing...Ch. 7 - Compare the elements Na, Mg, O, and P. (a) Which...Ch. 7 - Compare the elements B. Al, C, and Si. (a) Which...Ch. 7 - Explain each answer briefly. (a) Place the...Ch. 7 - Explain each answer briefly. (a) Rank the...Ch. 7 - Identify the element that corresponds to each of...Ch. 7 - Identify the element that corresponds to each of...Ch. 7 - Explain why the photoelectron spectra of hydrogen...Ch. 7 - Sketch the major features (number of peaks and...Ch. 7 - These questions are not designated as to type or...Ch. 7 - The deep blue color of sapphires comes from the...Ch. 7 - Using an orbital box diagram and noble gas...Ch. 7 - Prob. 40GQCh. 7 - Prob. 41GQCh. 7 - Prob. 42GQCh. 7 - Which of the following is not an allowable set of...Ch. 7 - A possible excited state for the H atom has an...Ch. 7 - The magnet in the following photo is made from...Ch. 7 - Name the element corresponding to each...Ch. 7 - Arrange the following atoms in order of increasing...Ch. 7 - Prob. 48GQCh. 7 - Answer the questions below about the elements A...Ch. 7 - Answer (he following questions about the elements...Ch. 7 - Which of the following ions are unlikely to be...Ch. 7 - Prob. 52GQCh. 7 - Answer each of the following questions: (a) Of the...Ch. 7 - Prob. 54GQCh. 7 - Prob. 55GQCh. 7 - Two elements in the second transition series (Y...Ch. 7 - Prob. 57GQCh. 7 - The configuration of an element is given here. (a)...Ch. 7 - Answer the questions below about the elements A...Ch. 7 - Answer the questions below concerning ground state...Ch. 7 - Nickel(II) formate [Ni(HCO2)2] is widely used as a...Ch. 7 - Spinets are solids with the general formula M2+...Ch. 7 - The following questions use concepts from this and...Ch. 7 - Which ions in the following list are not likely to...Ch. 7 - Answer the following questions about first...Ch. 7 - The ionization of the hydrogen atom can be...Ch. 7 - Compare the configurations below with two...Ch. 7 - Prob. 68SCQCh. 7 - Write electron configurations to show the first...Ch. 7 - Prob. 70SCQCh. 7 - (a) Explain why the sizes of atoms change when...Ch. 7 - Which of the following elements has the greatest...Ch. 7 - Prob. 73SCQCh. 7 - Prob. 74SCQCh. 7 - The energies of the orbitals in many elements have...Ch. 7 - The ionization energies for the removal of the...Ch. 7 - Using your knowledge of the trends in element...Ch. 7 - Prob. 78SCQCh. 7 - Prob. 79SCQCh. 7 - Prob. 80SCQCh. 7 - Thionyl chloride. SOCl2, is an important...Ch. 7 - Prob. 82SCQCh. 7 - Slaters rules are a way to estimate the effective...
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- What is the difference between an atom’s ground state and an excited state?arrow_forwarddescribe trace analysis and explain its role in materials testing.arrow_forward6.103 Atomic absorption spectroscopy is based on the atomic spectra of the elements being studied. It can be used to determine the impurities in a metal sample. If an element is present, light at the appropriate wavelength is absorbed. You are working with a metal stamping company and the rolled steel you use to form panels for automobile doors is failing at an alarming rate. There is some chance that the problem is unacceptably high levels of manganese in the steel. Given that the atomic spectrum of manganese has three lines near 403 nm, how could you use a spectrometer to determine the amount of manganese in the steel?arrow_forward
- One bit of evidence that the quantum mechanical model is correct lies in the magnetic properties of matter. Atoms with unpaired electrons are attracted by magnetic fields and thus are said to exhibit pararamagnetism. The degree to which this effect is observed is directly related to the number of unpaired electrons present in the atom. Consider the ground-state electron configurations for Li, N, Ni, Te, Ba, and Hg. Which of these atoms would be expected to be paramagnetic, and how many unpaired electrons are present in each paramagnetic atom?arrow_forwardList the charges on hydrogen-like atoms whose nuclei are of the following elements. a lithium, b carbon, c iron, d samarium, e xenon, f francium, g uranium, h seaborgiumarrow_forwardSuppose that the spin quantum number could have the values 12,0 and 12 . Assuming that the rules governing the values of the other quantum numbers and the order of filling sublevels were unchanged, (a) what would be the electron capacity of an s sublevel? a p sublevel? a d sublevel? (b) how many electrons could fit in the n=3 level? (c) what would be the electron configuration of the element with atomic number 8? 17?arrow_forward
- Suppose that the spin quantum number did not exist, and therefore only one electron could occupy each orbital of a many-electron atom. Give the atomic numbers of the first three noble-gas atoms in this case.arrow_forwardIt requires 799 kJ of energy to break one mole of carbon-oxygen double bonds in carbon dioxide. What wavelength of light does this correspond to per bond? Is there any transition in the hydrogen atom that has at least this quantity of energy to one photon?arrow_forwardThe spectra of hydrogen and of calcium are shown in Figure 6.13. What causes the lines in these spectra? Why are the colors of the lines different? Suggest a reason for the observation that the spectrum of calcium is more complicated than the spectrum of hydrogen.arrow_forward
- Consider the eight most abundant elements in the human body, as outlined in Exercise 156. Excluding hydrogen, which of these elements would have the smallest size? largest size? smallest first ionization energy? largest first ionization energy?arrow_forwardLight Energy, and the Hydrogen Atom a Which has the greater wavelength, blue light or red light? b How do the frequencies of blue light and red light compare? c How does the energy of blue light compare with that of red light? d Does blue light have a greater speed than red light? e How does the energy of three photons from a blue light source compare with the energy of one photon of blue light from the same source? How does the energy of two photons corresponding to a wavelength of 451 nm (blue light) compare with the energy of three photons corresponding to a wavelength of 704 nm (red light)? f A hydrogen atom with an electron in its ground state interacts with a photon of light with a wavelength of 1.22 106 m. Could the electron make a transition from the ground state to a higher energy level? If it does make a transition, indicate which one. If no transition can occur, explain. g If you have one mole of hydrogen atoms with their electrons in the n = 1 level, what is the minimum number of photons you would need to interact with these atoms in order to have all of their electrons promoted to the n = 3 level? What wavelength of light would you need to perform this experiment?arrow_forward
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