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(a)
Interpretation:
The atom has larger atomic radius has to be selected.
Concept Introduction:
Atomic radius: The concept explain chemical element is a measured of the size of its atoms, in other words to measure the distance from the center of the nucleus to the boundary of the surrounding cloud of number of electrons.
Increase and decrease electronegativity: The less vacancy electrons an atoms has the least it will gain of electrons. Moreover the
Electronegativity: It is measure of the tendency of an atom to attract a bonding pair of electrons. For example the (F) fluorine is more electronegative element is assigned a value f (4.0) and values range down to cesium (CS) and francium (Fr) which are the largest electronegative at (0.7) range, generally the Pauling scale is used to analyze the electronegative range (or) properties.
(b)
Interpretation:
The ion that has larger atomic radius has to be selected.
Concept Introduction:
Atomic radius: The concept explain chemical element is a measured of the size of its atoms, in other words to measure the distance from the center of the nucleus to the boundary of the surrounding cloud of number of electrons.
Increase and decrease electronegativity: The less vacancy electrons an atoms has the least it will gain of electrons. Moreover the electron affinity decrease down the groups and from right to left across the periods on the periodic table, the reason is electrons are placed in a higher energy level far from the nucleus thus a decrease from its pull.
Electronegativity: It is measure of the tendency of an atom to attract a bonding pair of electrons. For example the (F) fluorine is more electronegative element is assigned a value f (4.0) and values range down to cesium (CS) and francium (Fr) which are the largest electronegative at (0.7) range, generally the Pauling scale is used to analyze the electronegative range (or) properties.
(c)
Interpretation:
The atom has larger atomic radius has to be selected.
Concept Introduction:
Atomic radius: The concept explain chemical element is a measured of the size of its atoms, in other words to measure the distance from the center of the nucleus to the boundary of the surrounding cloud of number of electrons.
Increase and decrease electronegativity: The less vacancy electrons an atoms has the least it will gain of electrons. Moreover the electron affinity decrease down the groups and from right to left across the periods on the periodic table, the reason is electrons are placed in a higher energy level far from the nucleus thus a decrease from its pull.
Electronegativity: It is measure of the tendency of an atom to attract a bonding pair of electrons. For example the (F) fluorine is more electronegative element is assigned a value f (4.0) and values range down to cesium (CS) and francium (Fr) which are the largest electronegative at (0.7) range, generally the Pauling scale is used to analyze the electronegative range (or) properties.
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Chapter 7 Solutions
Chemistry & Chemical Reactivity
- Diels Alder Cycloaddition: Focus on regiochemistry (problems E-F) –> match + of thedienophile and - of the diene while also considering stereochemistry (endo).arrow_forwardHELP! URGENT! PLEASE RESOND ASAP!arrow_forwardQuestion 4 Determine the rate order and rate constant for sucrose hydrolysis. Time (hours) [C6H12O6] 0 0.501 0.500 0.451 1.00 0.404 1.50 0.363 3.00 0.267 First-order, k = 0.210 hour 1 First-order, k = 0.0912 hour 1 O Second-order, k = 0.590 M1 hour 1 O Zero-order, k = 0.0770 M/hour O Zero-order, k = 0.4896 M/hour O Second-order, k = 1.93 M-1-hour 1 10 ptsarrow_forward
- Determine the rate order and rate constant for sucrose hydrolysis. Time (hours) [C6H12O6] 0 0.501 0.500 0.451 1.00 0.404 1.50 0.363 3.00 0.267arrow_forwardDraw the products of the reaction shown below. Use wedge and dash bonds to indicate stereochemistry. Ignore inorganic byproducts. OSO4 (cat) (CH3)3COOH Select to Draw ઘarrow_forwardCalculate the reaction rate for selenious acid, H2SeO3, if 0.1150 M I-1 decreases to 0.0770 M in 12.0 minutes. H2SeO3(aq) + 6I-1(aq) + 4H+1(aq) ⟶ Se(s) + 2I3-1(aq) + 3H2O(l)arrow_forward
- Problem 5-31 Which of the following objects are chiral? (a) A basketball (d) A golf club (b) A fork (c) A wine glass (e) A spiral staircase (f) A snowflake Problem 5-32 Which of the following compounds are chiral? Draw them, and label the chirality centers. (a) 2,4-Dimethylheptane (b) 5-Ethyl-3,3-dimethylheptane (c) cis-1,4-Dichlorocyclohexane Problem 5-33 Draw chiral molecules that meet the following descriptions: (a) A chloroalkane, C5H11Cl (c) An alkene, C6H12 (b) An alcohol, C6H140 (d) An alkane, C8H18 Problem 5-36 Erythronolide B is the biological precursor of erythromycin, a broad-spectrum antibiotic. How H3C CH3 many chirality centers does erythronolide B have? OH Identify them. H3C -CH3 OH Erythronolide B H3C. H3C. OH OH CH3arrow_forwardPLEASE HELP! URGENT! PLEASE RESPOND!arrow_forward2. Propose a mechanism for this reaction. ہلی سے ملی N H (excess)arrow_forward
- Steps and explanationn please.arrow_forwardProblem 5-48 Assign R or S configurations to the chirality centers in ascorbic acid (vitamin C). OH H OH HO CH2OH Ascorbic acid O H Problem 5-49 Assign R or S stereochemistry to the chirality centers in the following Newman projections: H Cl H CH3 H3C. OH H3C (a) H H H3C (b) CH3 H Problem 5-52 Draw the meso form of each of the following molecules, and indicate the plane of symmetry in each: OH OH (a) CH3CHCH2CH2CHCH3 CH3 H3C. -OH (c) H3C CH3 (b) Problem 5-66 Assign R or S configurations to the chiral centers in cephalexin, trade-named Keflex, the most widely prescribed antibiotic in the United States. H2N H IHH S Cephalexin N. CH3 CO₂Harrow_forwardSteps and explanationn please.arrow_forward
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