The more stable compound from the given set of compounds should be determined. Concept introduction: Carbocation: It is carbon ion that bears a positive charge on it. Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via h e t e r o l y t i c bond cleavage. Carbocation stability order: Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable. Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation. Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom. Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

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Answer 1

Question

Chapter 6, Problem 38P

(a)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

(b)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

(c)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

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3. a. Use the MS to propose at least two possible molecular formulas. For an unknown compound: 101. 27.0 29.0 41.0 50.0 52.0 55.0 57.0 100 57.5 58.0 58.5 62.0 63.0 64.0 65.0 74.0 40 75.0 76.0 20 20 40 60 80 100 120 140 160 180 200 220 m/z 99.5 68564810898409581251883040 115.0 116.0 77404799 17417M 117.0 12.9 118.0 33.5 119.0 36 133 0 1.2 157.0 2.1 159.0 16 169.0 219 170.0 17 171.0 21.6 172.0 17 181.0 1.3 183.0 197.0 100.0 198.0 200. 784 Relative Intensity 2 2 8 ō (ppm) 6 2

Solve the structure and assign each of the following spectra (IR and C-NMR)

1. For an unknown compound with a molecular formula of C8H100: a. What is the DU? (show your work) b. Solve the structure and assign each of the following spectra. 8 6 2 ō (ppm) 4 2 0 200 150 100 50 ō (ppm) LOD D 4000 3000 2000 1500 1000 500 HAVENUMBERI -11

Answer 2

Question

Chapter 6, Problem 38P

(a)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

(b)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

(c)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

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Answer 3

Question

Chapter 6, Problem 38P

(a)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

(b)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

(c)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

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Answer 4

Question

Chapter 6, Problem 38P

(a)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

(b)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

(c)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

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Answer 5

Chapter 6, Problem 38P

(a)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

(b)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

(c)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Answer 6

Chapter 6, Problem 38P

(a)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Answer 7

Chapter 6, Problem 38P

(a)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The more stable compound from the given set of compounds should be determined.

Concept introduction:

Carbocation: It is carbon ion that bears a positive charge on it.

Leaving group: It is a fragment that leaves from a substrate with a pair of electrons via heterolytic bond cleavage.

Carbocation stability order:

Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes that molecule more stable.

Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.

Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.

Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.

Answer 12

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Answer 13

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Answer 15

Ch. 6.1 - Draw the mechanism for the reaction of cyclohexene...Ch. 6.2 - a. How many bond orbitals are available for...Ch. 6.2 - Prob. 3P Ch. 6.2 - Prob. 4P Ch. 6.3 - Prob. 5P Ch. 6.3 - Prob. 6P Ch. 6.3 - Prob. 7P Ch. 6.5 - Prob. 9P Ch. 6.5 - Prob. 10P Ch. 6.5 - a. What is the major product of each of the...

Solution Summary: The author explains that the more stable compound from the given set of compounds should be determined. Carbocation is carbon ion that bears a positive charge.

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