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(a)
Interpretation:
The rate of hydration of given
Concept Introduction:
Stereoisomers: Two compounds with same molecular formula but different in their orientation are considered as isomers.
The presence of atom with non-super impossible mirror image is defined as enantiomers which are given
Erythro product: It is the representation of carbohydrates in Fischer projection when two same substituents are placed on the same side.
Threo product: It is the representation of carbohydrates in Fischer projection when two same substituents are placed on opposite side.
(b)
Interpretation:
The reason for the reactivity of
Concept Introduction:
Stereoisomers: Two compounds with same molecular formula but different in their orientation are considered as isomers.
The presence of atom with non-super impossible mirror image is defined as enantiomers which are given
Erythro product: It is the representation of carbohydrates in Fischer projection when two same substituents are placed on the same side.
Threo product: It is the representation of carbohydrates in Fischer projection when two same substituents are placed on opposite side.
(c)
Interpretation:
The reason for the reactivity of
Concept Introduction:
Stereoisomers: Two compounds with same molecular formula but different in their orientation are considered as isomers.
The presence of atom with non-super impossible mirror image is defined as enantiomers which are given
Erythro product: It is the representation of carbohydrates in Fischer projection when two same substituents are placed on the same side.
Threo product: It is the representation of carbohydrates in Fischer projection when two same substituents are placed on opposite side.
(d)
Interpretation:
The reason for the reactivity of
Concept Introduction:
Stereoisomers: Two compounds with same molecular formula but different in their orientation are considered as isomers.
The presence of atom with non-super impossible mirror image is defined as enantiomers which are given
Erythro product: It is the representation of carbohydrates in Fischer projection when two same substituents are placed on the same side.
Threo product: It is the representation of carbohydrates in Fischer projection when two same substituents are placed on opposite side.
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Chapter 6 Solutions
EBK ESSENTIAL ORGANIC CHEMISTRY
- 2. What Alkene would be used to synthesize 3-bromohexane? + HBr CH;CH,CHCH,CH,CH3 br 3. Write down the mechanism for the following reaction and predict which of the two possible products will be formed in the greatest yield ( 2nd and 3d carbocation). Write down the structures of the two possible products and explain your answer. CH;CH = CHCH, CH, CH3 + HBrarrow_forwardEthers can be prepared by reaction of an alkoxide or phenoxide ion with a primary alkyl halide. Draw the structure of the expected organic product of the reaction of 1-iodo-2-methylpropane with the following alkoxide ic + O Na You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Do not include counter-ions, e.g., Na", I", in your answer. C opy astearrow_forwardThe rate law for the reaction of HO- with tert-butyl bromide to form an elimination product in 75% ethanol/ 25% water at 30 °C is the sum of the rate laws for the E2 and E1 reactions. What percentage of the reaction takes place by an E2 pathway when [HO-] = 5.0 M? (k2 = 7.1 x 10-5, and k1 = 1.5 x 10-5)arrow_forward
- Ethers can be prepared by reaction of an alkoxide or phenoxide ion with a primary alkyl halide. Draw the structure of the expected organic product of the reaction of iodoethane with the following alkoxide ion: H3C CH3 + Na You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. Do not include lone pairs in your answer. They will not be considered in the grading. • Do not include counter-ions, e.g., Na", I, in your answer. P opy aste [*arrow_forwardChoose from the options A-E and explain briefly by illustrations the chemistry behind each answer. Preamble: A reaction flask contains a 2-bromopentane in an ethanolic solution of sodium ethoxide at room temperature and results in the formation of two olefinic 1.All the following parameters would affect the rate and kinetics of the reaction exceptA.Solvent mediumB.Reaction temperatureC.Reaction timeD.Geometry and structure of the alkyl halideE.pH 2.What would be the major product when 2-iodopentane is involved in a dehydrohalogenation reaction? A.2-iodo-1-penteneB.2-penteneC.(E)-2-penteneD.(Z)-2-penteneE.Cis-2-pentenearrow_forwardWhat would the major organic reaction product be from the reaction of 1-bromo-1-methylcyclopentane withsodium hydroxide? Would the elimination reaction outcome be affected if a student accidentally adds sodium tertbutoxide instead of sodium hydroxide?arrow_forward
- The rate law for the reaction of HO- with tert-butyl bromide to form an elimination product in 75% ethanol/25% water at 30 °C is the sum of the rate laws for the E2 and E1 reactions. What percentage of the reaction takes place by an E2 pathway when [HO-] = 5.0 M? (k2 = 7.1 * 10 - 5, and k1 = 1.5 * 10 - 5) rate = rate law for the E2 reaction + rate law for the E1 reation rate = k2 3tert@butyl bromide43HO-4 + k1 3tert@butyl bromide4arrow_forwardDraw the major organic product formed by reaction of 2-hexyne with the following reagent: BH3 followed by CH3COOH. . Consider E/Z stereochemistry of alkenes. In cases where there is more than one answer, just draw one. • If no reaction occurs, draw the organic starting material.arrow_forwardEthers can be prepared by reaction of an alkoxide or phenoxide ion with a primary alkyl halide. Draw the structure of the expected organic product of the reaction of iodomethane with the following alkoxide ion: CH3 H3C O Na You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Do not include counter-ions, e.g., Na", I, in your answer. орy вste ChemDoodlearrow_forward
- Following is a balanced equation for the allylic bromination of propene. CH2==CHCH3 + Br2 h CH2==CHCH2Br + HBr (a) Calculate the heat of reaction, H 0, for this conversion. (b) Propose a pair of chain propagation steps and show that they add up to the observed stoichiometry. (c) Calculate the H 0 for each chain propagation step and show that they add up to the observed H 0 for the overall reaction.arrow_forwardUsing your reaction roadmap as a guide, show how to convert ethylene into 1-butene. All of the carbon atoms of the target molecule must be derived from ethylene. Show all intermediate molecules synthesized along the way.arrow_forward3A. During the workup portion of the reaction of alkenes with HBr as described in the experiment provided, a student transferred the reaction mixture to a separatory funnel, rinsed the reaction flask with diethyl ether, and added the ether rinses to the separatory funnel. The student then added sodium bicarbonate to the separatory funnel. Extremely vigorous bubbling occurred. What did the student do wrong? Can they still isolate the product? If so describe the next steps the student should take to isolate the product.arrow_forward
Macroscale and Microscale Organic ExperimentsChemistryISBN:9781305577190Author:Kenneth L. Williamson, Katherine M. MastersPublisher:Brooks Cole
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
