EBK ESSENTIAL ORGANIC CHEMISTRY
EBK ESSENTIAL ORGANIC CHEMISTRY
3rd Edition
ISBN: 8220100659461
Author: Bruice
Publisher: PEARSON
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Chapter 6, Problem 54P

(a)

Interpretation Introduction

Interpretation:

The rate of hydration of given alkenes should be determined.

Concept Introduction:

Stereoisomers: Two compounds with same molecular formula but different in their orientation are considered as isomers.

The presence of atom with non-super impossible mirror image is defined as enantiomers which are given R and S configuration based on the atoms bonded with them.

Erythro product: It is the representation of carbohydrates in Fischer projection when two same substituents are placed on the same side.

Threo product: It is the representation of carbohydrates in Fischer projection when two same substituents are placed on opposite side.

(b)

Interpretation Introduction

Interpretation:

The reason for the reactivity of (Z)-2-butene than (E)-2-butene should be determined.

Concept Introduction:

Stereoisomers: Two compounds with same molecular formula but different in their orientation are considered as isomers.

The presence of atom with non-super impossible mirror image is defined as enantiomers which are given R and S configuration based on the atoms bonded with them.

Erythro product: It is the representation of carbohydrates in Fischer projection when two same substituents are placed on the same side.

Threo product: It is the representation of carbohydrates in Fischer projection when two same substituents are placed on opposite side.

(c)

Interpretation Introduction

Interpretation:

The reason for the reactivity of 2-methyl-2-butene than (Z)-2-butene should be determined.

Concept Introduction:

Stereoisomers: Two compounds with same molecular formula but different in their orientation are considered as isomers.

The presence of atom with non-super impossible mirror image is defined as enantiomers which are given R and S configuration based on the atoms bonded with them.

Erythro product: It is the representation of carbohydrates in Fischer projection when two same substituents are placed on the same side.

Threo product: It is the representation of carbohydrates in Fischer projection when two same substituents are placed on opposite side.

(d)

Interpretation Introduction

Interpretation:

The reason for the reactivity of 2,3-dimethyl-2-butene than 2-methyl-2-butene should be determined.

Concept Introduction:

Stereoisomers: Two compounds with same molecular formula but different in their orientation are considered as isomers.

The presence of atom with non-super impossible mirror image is defined as enantiomers which are given R and S configuration based on the atoms bonded with them.

Erythro product: It is the representation of carbohydrates in Fischer projection when two same substituents are placed on the same side.

Threo product: It is the representation of carbohydrates in Fischer projection when two same substituents are placed on opposite side.

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3) Catalytic hydrogenation of the compound below produced the expected product. However, a byproduct with molecular formula C10H12O is also formed in small quantities. What is the by product?
What is the ΔHorxn of the reaction?  NaOH(aq) + HCl(aq) → H2O(l) + NaCl(aq)   ΔHorxn 1= ________ kJ/mol
= +92kJ ΔΗ = +170kJ Use the following reactions: 2NH3(9) N2(g) + 3H2(g) → 11/N2(g) + 2H2O (1) → NO2(g) + 2H2(g) Determine the DH° of this reaction: NO2(g) + H2(g) → 2(g) → 2H2O(l) + NH3(9) ΔΗ

Chapter 6 Solutions

EBK ESSENTIAL ORGANIC CHEMISTRY

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