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Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Textbook Question
Chapter 3, Problem 5E
Consider the following orbital representation of HCCH (ethyne).
a. Answer the same three questions (a-c) from the previous exercise.
b. Label each
c. What is the total number of a bonds found in ethyne?….
d. How many p orbitals are there on a single carbon of ethyne?
e. How many hybrid orbitals are there on a single carbon of ethyne?
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Please solve this
1. Is the following orbital sigma or pi? Bonding or antibonding? (circle your answers). The orbital is
between two carbons, the nuclei of which are roughly where the black circles are.
2. What atomic orbitals would be used to make the orbital from question 2?
3. Label the hybridization of each indicated atom in the following molecule as SP, SP³, or SP³,
OH
4. Circle the shortest carbon-carbon single bond in the above molecule (Advanced question).
Explain why it is the shortest in a sentence or two.
5. Draw the major resonance structures of the following molecule
S
H₂N
2. Provide the following answer using the following compound below.
a. Assign the hybridization for each atom, except hydrogen.
b. Determine the number of atomic orbitals and Molecular orbitals (AO, MO).
c. Draw the atomic orbitals for each atom and their MO
d. Draw the energy diagram.
e. Assign the HOMO and LUMO in the energy diagram.
H
H-C-C=C-H
FO:
H
Chapter 3 Solutions
Organic Chemistry: A Guided Inquiry
Ch. 3 - Prob. 1CTQCh. 3 - What neutral atom is represented by the electron...Ch. 3 - Prob. 3CTQCh. 3 - Consider any one of the four identical hybrid...Ch. 3 - Prob. 5CTQCh. 3 - Prob. 6CTQCh. 3 - Prob. 7CTQCh. 3 - Prob. 8CTQCh. 3 - Prob. 9CTQCh. 3 - Prob. 10CTQ
Ch. 3 - On the left side of Figure 3.6, label the areas...Ch. 3 - Prob. 12CTQCh. 3 - Prob. 13CTQCh. 3 - Prob. 14CTQCh. 3 - Prob. 15CTQCh. 3 - Now consider the fully formed molecule on the...Ch. 3 - Prob. 1ECh. 3 - Explain why the two molecules below cannot...Ch. 3 - Prob. 3ECh. 3 - Consider the incomplete orbital representation of...Ch. 3 - Consider the following orbital representation of...Ch. 3 - Summarize how one determines the hybridization...Ch. 3 - Explain what is wrong with each of the following...Ch. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Complete the following tables, and memorize their...Ch. 3 - Draw orbital representations of bonding in water...Ch. 3 - Draw electron configuration diagrams for carbon in...Ch. 3 - Prob. 13E
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- Now consider the fully formed molecule on the right side of Figure 3.7. a. Draw a Lewis structure of this molecule. b. Identify orbital representations of the two bonds and three bonds in Figure 3.7, andmatch these with representations of bonds on the Lewis structure you just drew.arrow_forwardanswer the following questions. Indicate the hybridization of each nitrogen (sp, sp2, sp3) and which orbital the lone pair occupies (s,p,d,f)arrow_forwardanswer the following questions. Indicate the hybridization of each nitrogen (sp, sp2, sp3) AND which orbital the lone pair occupies (s,p,d,f)arrow_forward
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