Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 3, Problem 12CTQ
Interpretation Introduction

Interpretation: Lewis structure that corresponds to orbital description shown below should be drawn.

  Organic Chemistry: A Guided Inquiry, Chapter 3, Problem 12CTQ

Concept introduction: Lewis structures depict covalent bonds and describe valence electrons are present in the molecule.

The sequence that leads to Lewis structure of the molecule is as follows:

  • Identify central atom and arrange various other atoms around it. This atom so chosen is the least electronegative one.
  • Estimate the total valence electrons.
  • Firstly place single bond between each pair.
  • The remaining electrons can be allocated lone pairs to satisfy the octet rule for each atom.

Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

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Give typed full explanation  Look at figure 3-22 that shows the electron density that occurs abound the Si-O bond. This electron density map gives the "shape" of the O and Si atoms when they are bonded together. Think about the answer in Q9 and choose the best response below: (Select answer choice) a. This figure shows that the Si and O atoms, when they bond together, do not form spheres, which is due to the fact that the Si-O bond is strongly covalent and these shared electrons affect atomic shape. This change in shape limits the applicability of Pauling's Coordination principle since that principle is based on the geometry of perfect spheres. b. This figure shows that the Si and O atoms, when they bond together are close to perfect spheres, which is due to the fact that the Si-O bond is strongly covalent. This figure shows that Pauling's Coordination principle should apply very precisely to any substance that contains Si-O bonds c. This figure shows that the Si and O atoms, form in a…
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