Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 3, Problem 8CTQ
Interpretation Introduction

Interpretation: The blank that is related to overlap of orbitals in sp2 hybrid orbital should be filled.

Concept introduction: Two or more of orbitals undergo redistributions of their different energies so as to form mathematically averaged orbitals in terms of energy although they may differ in shape and orientation. This phenomenon is referred as hybridization.

The energy and orientation of the new hybrid orbital depends upon by the kind and number of orbitals used in the hybridization. The new hybrid orbitals are always equal in number to number of atomic orbitals that combine.

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" is The structure of the bicarbonate (hydrogen carbonate) ion, HCO3-, HCO3 best described as a hybrid of several contributing resonance forms, two of which are shown here. HO :0: :Ö: HO + Bicarbonate is crucial for the control of body pH (for example, blood pH: 7.4). A more self-indulgent use is in baking soda, where it serves as a source of CO2 CO₂ 2 gas, which gives bread and pastry their fluffy constituency. (i) Draw at least one additional resonance form. = (ii) Using curved "electron-pushing" arrows, show how these Lewis structures may be interconverted by movement of electron pairs. (iii) Determine which form or forms will be the major contributor(s) to the real structure of bicarbonate, explaining your answer on the basis of the criteria in Section 1-5.
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