Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Textbook Question
Chapter 3, Problem 16CTQ
Now consider the fully formed molecule on the right side of Figure 3.7.
a. Draw a Lewis structure of this molecule.
b. Identify orbital representations of the two
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1) For each condensed or skeletal structure below:
A. Draw a complete Lewis structure. Note: show all non-bonding electron pairs.
B. Indicate the hybridization of all C, O, and N atoms in each of the molecules.
C.
Label each of the indicated bonds (marked by an arrow) as either a sigma or pi bond. (Note: Remember,
e.g. that a double bond is made up of both a o and a π bond). Also indicate which orbitals overlap to form
the bond (e.g., Ols-2sp3).
D.
For atoms having lone pairs in the molecules below, indicate in which orbitals the lone pairs are located.
E. Which of the bonds indicated by arrows is shorter?
a)
c) H
CH3
C=CHC=C-CH
g) (CH3)3CCN
CH3
CH₂CH=CHCECH
b)
d)
CH3
Lo
LOH
f) CH₂CH(CH3)SH
h) (CH3)2CH(CH₂)3Br
Answer following questions
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Chapter 3 Solutions
Organic Chemistry: A Guided Inquiry
Ch. 3 - Prob. 1CTQCh. 3 - What neutral atom is represented by the electron...Ch. 3 - Prob. 3CTQCh. 3 - Consider any one of the four identical hybrid...Ch. 3 - Prob. 5CTQCh. 3 - Prob. 6CTQCh. 3 - Prob. 7CTQCh. 3 - Prob. 8CTQCh. 3 - Prob. 9CTQCh. 3 - Prob. 10CTQ
Ch. 3 - On the left side of Figure 3.6, label the areas...Ch. 3 - Prob. 12CTQCh. 3 - Prob. 13CTQCh. 3 - Prob. 14CTQCh. 3 - Prob. 15CTQCh. 3 - Now consider the fully formed molecule on the...Ch. 3 - Prob. 1ECh. 3 - Explain why the two molecules below cannot...Ch. 3 - Prob. 3ECh. 3 - Consider the incomplete orbital representation of...Ch. 3 - Consider the following orbital representation of...Ch. 3 - Summarize how one determines the hybridization...Ch. 3 - Explain what is wrong with each of the following...Ch. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Complete the following tables, and memorize their...Ch. 3 - Draw orbital representations of bonding in water...Ch. 3 - Draw electron configuration diagrams for carbon in...Ch. 3 - Prob. 13E
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- 7. Predict the polarity of 6 real molecules. First, draw the molecules and any bond dipoles. Then draw any molecular dipoles. Explain your reasoning before you check your predictions with the simulation.arrow_forwarda) Draw the Lewis structure for the molecule on the left (labeled as Molecule A above). Draw the Lewis structure which has minimum formal charges. b) Draw the correct Lewis structure for the molecule on the right (labeled as Molecule B above). Draw the Lewis structure which has minimum formal charges. c) Select the three TRUE statements from those provided below. The molecule on the right (Molecule B) is planar (all atoms lie within the same plane). The molecule on the left (Molecule A) is planar (all atoms lie within the same plane). The molecule on the right (Molecule B) has polar bonds. The molecule on the left (Molecule A) has polar bonds. We can distinguish between the two molecules (Molecule A and Molecule B) based upon their dipole moment.arrow_forwardXeO2F2arrow_forward
- Use your knowledge of hybridization to fill in the following table. Rank the sigma bonds labeled A, B, C, and D from strongest to weakest. Explain your answer.arrow_forward3. The following shows all resonance structures for the following molecule. a. Draw in all implied lone pairs. b. Draw in curved arrows that show the flow of electrons, making sure the arrows show the precise starting point and destination of the electrons. Label each arrow as: lp →→→л (p=lone pair) c. d. Rank the resonance structures from most stable to least based on the number of formal charges and atoms that lack an octet of electrons. ol-of-o. B A D d-d-d-o E C F Garrow_forward5. Follow the curve arrows in the image below and draw the correct second resonan structure.arrow_forward
- Please help.arrow_forwardDo 1 and 2 only thank you. I'll upvotearrow_forward2. Draw a Lewis structure for each molecule or ion below. Draw any resonance structures. Determine the form al charges on atoms in each of your resonance structures. Based on this, determine which resonance structure(s) are most im portant. Circle the most important contributor(s) to the resonance hybrid. If they are all equivalent, circle them all. a. NO, b. COFCIarrow_forward
- A student draws the picture of ammonia (NH3) in the box below, left, and predicts it will be a flatmolecule with HNH bond angles of exactly 120°. Unfortunately, the student left something out. a. What did the student omit from his drawing? b. What is the actual HNH bond angle of ammonia (based on the draw g above, right)? c. Explain why water, ammonia, and methane (shown below) all have about the same bondangles (close to 109.5°) even though they have different numbers of bonds.arrow_forwardHow many valence electrons does a neutral a. K atom have? b. C atom? N atom? O atom?arrow_forward6. Good question. A molecule with zero formal charges on all atoms is drawn below. Identify which group of the periodic table each of the elements X, Y, Z, and A, belong to. A A A -X A A :Z-A Ÿ-Aarrow_forward
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