Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 3, Problem 15CTQ

(a)

Interpretation Introduction

Interpretation: Dotted lines to show π bond can form between the two white p orbitals should be added.

  Organic Chemistry: A Guided Inquiry, Chapter 3, Problem 15CTQ , additional homework tip  1

Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

A single bond has one σ bond; double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond. For instance, pi bond formation that involves lateral overlap of dumble bell lobes of p orbital as in case of a triple bond are illustrated as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 3, Problem 15CTQ , additional homework tip  2

(b)

Interpretation Introduction

Interpretation: Dotted lines to show σ bond that can form between the two white p orbitals should be labeled.

  Organic Chemistry: A Guided Inquiry, Chapter 3, Problem 15CTQ , additional homework tip  3

Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

A single bond has one σ bond; double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond. There are two possible overlaps by s orbital that results in head to head overlap and sigma bond formation. These are illustrated as follows:

  Organic Chemistry: A Guided Inquiry, Chapter 3, Problem 15CTQ , additional homework tip  4

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b) Now draw those atomic orbitals you obtained in part (a), and then overlap them to (1 form the C-F bonds (you only have to draw ONE C-F bond) and bonds of the C=O. Feel free to draw as many drawings as you need. Make them clear. Label the atomic orbitals of all atoms and also label the resulting bonds as σ or TT. NO EXPLANATIONS ON THIS PAGE - JUST THE ORBITALS (LOBES)
help with 2a and 2b if possible please. image attached of question. thank you
1. a) Sketch the Lewis structure and name the molecular VSEPR shape for CCl4 b) What is the hybridization for the C atoms in C2H2? Show your work. (Start with a Lewis structure.  This molecule has a skeleton of HCCH.) c) Sketch an s orbital.  (This is meant to be a simple question.  Don't sweat it!) d) Sketch a p orbital of your choice. Indicate the phase and the cartesian directions (x, y, z axes).
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