Organic Chemistry: A Guided Inquiry
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 3, Problem 10CTQ
Interpretation Introduction

Interpretation: Total valence electrons found in cation H3C should be determined.

Concept introduction: A carbocation is a planar system and therefore sp2 hybridized with vacant unhybridized p -orbital. There are three sp2 and 1s overlaps; each shows that sp2 hybrid orbital with one electron overlaps with 1s orbital of hydrogen that has electron in antiparallel spin so that a stable sigma bond formation may occur as illustrated below:

  Organic Chemistry: A Guided Inquiry, Chapter 3, Problem 10CTQ

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Figure 4-2 ①:0: ~:0: + 我 我 244 444 A B 子 附 p* $4 + p*4 ¥ 4 C
For each of the statements below, indicate whether it is true or false and explain your reasoning. (1-3 sentences) ( 1/ It takes more energy to ionize an electron from the 2s orbital than an electron from the 2p orbital in the Li2+ ion. 2/ The electron affinity of the Ne atom is larger than the electron affinity of the F atom. 3/ K* has a larger radius than Ar. 4/ For a diatomic molecule, in which the internuclear axis is the z-axis, the 3dz2 orbital cannot mix with the 2px orbital. 5/ The internuclear distance of O2 increases as it takes an additional electron to become O2.
Identify the atom that has each ground-state electron configuration. Q.) 1s 2 2s 2 2p4
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