Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Chapter 3, Problem 3.83P
(a)
Interpretation Introduction
Interpretation: Mass of
Concept introduction: The formula to convert mass in grams to moles is as follows:
For some stoichiometric balanced equation; the reactant that is present in the smallest amount is consumed completely to form the product and thus governs the product formation.This reactant is known as limiting reactant.On the basis of the stoichiometric ratio by which substrates combine, the moles of product formed from each reactant can be calculated.
The formula to convert moles to mass in grams is as follows:
(b)
Interpretation Introduction
Interpretation:Total moles of gaseous products formed are to be calculated.
Concept introduction: The formula to convert mass in grams to moles is as follows:
The formula to convert moles to mass in grams is as follows:
(c)
Interpretation Introduction
Interpretation:Molecules of water vapor formed is to be calculated.
Concept introduction: The formula to convert mass in grams to moles is as follows:
The formula to convert moles to mass in grams is as follows:
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2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Interpreting NMR spectra is a skill that often requires some
amount of practice, which, in turn, necessitates access to a
collection of NMR spectra. Beyond Labz Organic Synthesis and
Organic Qualitative Analysis have spectral libraries containing
over 700 1H NMR spectra. In this assignment, you will take
advantage of this by first predicting the NMR spectra for two
closely related compounds and then checking your predictions
by looking up the actual spectra in the spectra library. After
completing this assignment, you may wish to select other
compounds for additional practice.
1. Write the IUPAC names for the following two structures:
Question 2
Question 3
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
11:14
...
worksheets.beyondlabz.com
3. To check your predictions, click this link for Interpreting
NMR Spectra 1. You will see a list of all the
-
compounds in the spectra library in alphabetical order by
IUPAC name. Hovering over a name in the list will show
the structure on the chalkboard. The four buttons on the
top of the Spectra tab in the tray are used to select the
different spectroscopic techniques for the selected
compound. Make sure the NMR button has been selected.
4. Scroll through the list of names to find the names for the
two compounds you have been given and click on the
name to display the NMR spectrum for each. In the NMR
tables below, list the chemical shift, the splitting, and
the number of hydrogens associated with each peak for
each compound. Compare your answers to your
predictions.
**Not all slots must be filled**
Peak
Chemical Shift (d)
Multiplicity
1
2
3
4
5
Chapter 3 Solutions
Principles of General Chemistry
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Ch. 3 - Prob. 3.11PCh. 3 - Calculate each of the following quantities: (a)...Ch. 3 - Prob. 3.13PCh. 3 - Prob. 3.14PCh. 3 - Prob. 3.15PCh. 3 - Calculate each of the following quantities: (a)...Ch. 3 - Calculate each of the following: Mass % of H in...Ch. 3 - Prob. 3.18PCh. 3 - Prob. 3.19PCh. 3 - Prob. 3.20PCh. 3 - Prob. 3.21PCh. 3 - Prob. 3.22PCh. 3 - Prob. 3.23PCh. 3 - Which of the following sets of information allows...Ch. 3 - What is the empirical formula and empirical...Ch. 3 - Prob. 3.26PCh. 3 - Prob. 3.27PCh. 3 - Prob. 3.28PCh. 3 - Prob. 3.29PCh. 3 - Prob. 3.30PCh. 3 - Prob. 3.31PCh. 3 - Prob. 3.32PCh. 3 - Cortisol (m=362.47g/mol) is a steroid hormone...Ch. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Prob. 3.36PCh. 3 - Write balanced equations for each of the following...Ch. 3 - Write balanced equations for each of the following...Ch. 3 - Prob. 3.39PCh. 3 - Prob. 3.40PCh. 3 - Prob. 3.41PCh. 3 - Potassium nitrate decomposes on heating, producing...Ch. 3 - Prob. 3.43PCh. 3 - Calculate the mass of each product formed when...Ch. 3 - Prob. 3.45PCh. 3 - Prob. 3.46PCh. 3 - Prob. 3.47PCh. 3 - Many metals react with oxygen gas to form the...Ch. 3 - Prob. 3.49PCh. 3 - Calculate the maximum numbers of moles and grams...Ch. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - Prob. 3.53PCh. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - Prob. 3.56PCh. 3 - Prob. 3.57PCh. 3 - Prob. 3.58PCh. 3 - Prob. 3.59PCh. 3 - Prob. 3.60PCh. 3 - Prob. 3.61PCh. 3 - Prob. 3.62PCh. 3 - Prob. 3.63PCh. 3 - Prob. 3.64PCh. 3 - Prob. 3.65PCh. 3 - Six different aqueous solutions (with solvent...Ch. 3 - Prob. 3.67PCh. 3 - Prob. 3.68PCh. 3 - Prob. 3.69PCh. 3 - Calculate each of the following quantities: (a)...Ch. 3 - Prob. 3.71PCh. 3 - Prob. 3.72PCh. 3 - Prob. 3.73PCh. 3 - Prob. 3.74PCh. 3 - Prob. 3.75PCh. 3 - Prob. 3.76PCh. 3 - Prob. 3.77PCh. 3 - Prob. 3.78PCh. 3 - Prob. 3.79PCh. 3 - Prob. 3.80PCh. 3 - Prob. 3.81PCh. 3 - Prob. 3.82PCh. 3 - Prob. 3.83PCh. 3 - Prob. 3.84PCh. 3 - Prob. 3.85PCh. 3 - Seawater is approximately 4.0% by mass dissolved...Ch. 3 - Is each of the following statements true or false?...Ch. 3 - Prob. 3.88PCh. 3 - In each pair, choose the larger of the indicated...Ch. 3 - Prob. 3.90PCh. 3 - Prob. 3.91PCh. 3 - Assuming that the volumes are additive, what is...Ch. 3 - Prob. 3.93PCh. 3 - Prob. 3.94PCh. 3 - Hydrocarbon mixtures are used as fuels, (a) How...Ch. 3 - Prob. 3.96PCh. 3 - Prob. 3.97PCh. 3 - Prob. 3.98PCh. 3 - Prob. 3.99PCh. 3 - Write a balanced equation for the reaction...Ch. 3 - Prob. 3.101PCh. 3 - Citric acid (right) is concentrated in citrus...Ch. 3 - Prob. 3.103PCh. 3 - Prob. 3.104PCh. 3 - Prob. 3.105PCh. 3 - Prob. 3.106PCh. 3 - Aspirin (acetylsalicylic acid, C9H8O4 ) is made by...Ch. 3 - Prob. 3.108PCh. 3 - Prob. 3.109PCh. 3 - Prob. 3.110PCh. 3 - High-temperature superconducting oxides hold great...
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