Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Chapter 3, Problem 3.79P
Interpretation Introduction
Interpretation:The value of
Concept introduction:Masspercent indicates concentration with respect to fraction in parts per hundred parts. For example,
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Indicate the processes in the dismutation of Cu2O.
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
2600
2400
2200
2000
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1600
1400
1200
1000
800
Potential Energy (kJ)
600
400
200
0
-200-
-400
-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
d. What is the overall amount of activation energy for the above chemical reaction?
e. Which reaction intermediate would be considered a catalyst (if any) and why?
f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would
you be able to make the reaction reverse itself (i.e. have…
draw the enolate anion and the carbonyl that would be needed to make this product through an aldol addition reaction.
Chapter 3 Solutions
Principles of General Chemistry
Ch. 3 - The atomic mass of Cl is 35.45 amu, and the atomic...Ch. 3 - (a) How many moles of C atoms are in 1 mol of...Ch. 3 - Prob. 3.3PCh. 3 - How is the molecular mass of a compound the same...Ch. 3 - What advantage is there to using a counting unit...Ch. 3 - Prob. 3.6PCh. 3 - Prob. 3.7PCh. 3 - Calculate the molar mass of each of the following:...Ch. 3 - Prob. 3.9PCh. 3 - Calculate the molar mass of each of the following:...
Ch. 3 - Prob. 3.11PCh. 3 - Calculate each of the following quantities: (a)...Ch. 3 - Prob. 3.13PCh. 3 - Prob. 3.14PCh. 3 - Prob. 3.15PCh. 3 - Calculate each of the following quantities: (a)...Ch. 3 - Calculate each of the following: Mass % of H in...Ch. 3 - Prob. 3.18PCh. 3 - Prob. 3.19PCh. 3 - Prob. 3.20PCh. 3 - Prob. 3.21PCh. 3 - Prob. 3.22PCh. 3 - Prob. 3.23PCh. 3 - Which of the following sets of information allows...Ch. 3 - What is the empirical formula and empirical...Ch. 3 - Prob. 3.26PCh. 3 - Prob. 3.27PCh. 3 - Prob. 3.28PCh. 3 - Prob. 3.29PCh. 3 - Prob. 3.30PCh. 3 - Prob. 3.31PCh. 3 - Prob. 3.32PCh. 3 - Cortisol (m=362.47g/mol) is a steroid hormone...Ch. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Prob. 3.36PCh. 3 - Write balanced equations for each of the following...Ch. 3 - Write balanced equations for each of the following...Ch. 3 - Prob. 3.39PCh. 3 - Prob. 3.40PCh. 3 - Prob. 3.41PCh. 3 - Potassium nitrate decomposes on heating, producing...Ch. 3 - Prob. 3.43PCh. 3 - Calculate the mass of each product formed when...Ch. 3 - Prob. 3.45PCh. 3 - Prob. 3.46PCh. 3 - Prob. 3.47PCh. 3 - Many metals react with oxygen gas to form the...Ch. 3 - Prob. 3.49PCh. 3 - Calculate the maximum numbers of moles and grams...Ch. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - Prob. 3.53PCh. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - Prob. 3.56PCh. 3 - Prob. 3.57PCh. 3 - Prob. 3.58PCh. 3 - Prob. 3.59PCh. 3 - Prob. 3.60PCh. 3 - Prob. 3.61PCh. 3 - Prob. 3.62PCh. 3 - Prob. 3.63PCh. 3 - Prob. 3.64PCh. 3 - Prob. 3.65PCh. 3 - Six different aqueous solutions (with solvent...Ch. 3 - Prob. 3.67PCh. 3 - Prob. 3.68PCh. 3 - Prob. 3.69PCh. 3 - Calculate each of the following quantities: (a)...Ch. 3 - Prob. 3.71PCh. 3 - Prob. 3.72PCh. 3 - Prob. 3.73PCh. 3 - Prob. 3.74PCh. 3 - Prob. 3.75PCh. 3 - Prob. 3.76PCh. 3 - Prob. 3.77PCh. 3 - Prob. 3.78PCh. 3 - Prob. 3.79PCh. 3 - Prob. 3.80PCh. 3 - Prob. 3.81PCh. 3 - Prob. 3.82PCh. 3 - Prob. 3.83PCh. 3 - Prob. 3.84PCh. 3 - Prob. 3.85PCh. 3 - Seawater is approximately 4.0% by mass dissolved...Ch. 3 - Is each of the following statements true or false?...Ch. 3 - Prob. 3.88PCh. 3 - In each pair, choose the larger of the indicated...Ch. 3 - Prob. 3.90PCh. 3 - Prob. 3.91PCh. 3 - Assuming that the volumes are additive, what is...Ch. 3 - Prob. 3.93PCh. 3 - Prob. 3.94PCh. 3 - Hydrocarbon mixtures are used as fuels, (a) How...Ch. 3 - Prob. 3.96PCh. 3 - Prob. 3.97PCh. 3 - Prob. 3.98PCh. 3 - Prob. 3.99PCh. 3 - Write a balanced equation for the reaction...Ch. 3 - Prob. 3.101PCh. 3 - Citric acid (right) is concentrated in citrus...Ch. 3 - Prob. 3.103PCh. 3 - Prob. 3.104PCh. 3 - Prob. 3.105PCh. 3 - Prob. 3.106PCh. 3 - Aspirin (acetylsalicylic acid, C9H8O4 ) is made by...Ch. 3 - Prob. 3.108PCh. 3 - Prob. 3.109PCh. 3 - Prob. 3.110PCh. 3 - High-temperature superconducting oxides hold great...
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