
Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Chapter 3, Problem 3.84P
Interpretation Introduction
Interpretation:Highest percent yield of
Concept introduction: The formula to convert mass in grams to moles is as follows:
For some stoichiometric balanced equation; the reactant that is present in the smallest amount is consumed completely to form the product and thus governs the product formation.This reactant is known as limiting reactant.On the basis of the stoichiometric ratio by which substrates combine, the moles of product formed from each reactants can be calculated.
The formula to percent yield is as follows:
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Given the equilibrium A2 + B2 ⇌ 2 AB where k1 is the rate coefficient of the forward reaction and k-1 is the rate coefficient of the reverse reaction, with the forward reaction being first-order in A2 and B2, and the reverse reaction being second-order in AB. Equilibrium will be reached later if the relative values of the constants are:(A) k1 high and k-1 high(B) k1 high and k-1 low(C) k1 low and k-1 high(D) k1 low and k-1 low
A 2-step reaction has the following mechanism:
|
1. (fast) R2
R+R
2. (slow) R+Q
K₂ P
k_1
What series does it have?
(A). v=
-
= (k + k1 − k-1)[R2][Q]
(B). v=-k₁[R₂] + k₁[R]² - k₂[R][Q]
(C). v=k₂[R]²[Q]²
(D). v = k[R₂]1/2[Q]
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
Chapter 3 Solutions
Principles of General Chemistry
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