Concept explainers
(a)
Interpretation:
The structure of alcohol that could be used to prepare the given compound by oxidation reaction has to be drawn.
Concept Introduction:
In
In organic chemistry, reduction reaction is referred to the number
Alcohols do undergo
Primary alcohol:
Secondary alcohol:
(a)
Answer to Problem 3.68EP
The structure of alcohol is,
Explanation of Solution
In organic chemistry, oxidation reaction is said to be decrease in
The given compound is a aldehyde. The aldehyde must have formed from primary alcohol by oxidation. The structure of the primary alcohol can be drawn considering the general scheme. Therefore, the structure can be given as shown below,
Structure of alcohol is drawn from which the given product is obtained by oxidation.
(b)
Interpretation:
The structure of alcohol that could be used to prepare the given compound by oxidation reaction has to be drawn.
Concept Introduction:
In organic chemistry, oxidation reaction is referred to the number
In organic chemistry, reduction reaction is referred to the number
Alcohols do undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and this id further oxidized to give carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.
Primary alcohol:
Secondary alcohol:
(b)
Answer to Problem 3.68EP
The structure of alcohol is,
Explanation of Solution
In organic chemistry, oxidation reaction is said to be decrease in
The given compound is a ketone. This has to be formed from a secondary alcohol only on oxidation. The structure of the secondary alcohol can be drawn considering the general scheme. Therefore, the structure can be given as shown below,
Structure of alcohol is drawn from which the given product is obtained by oxidation.
(c)
Interpretation:
The structure of alcohol that could be used to prepare the given compound by oxidation reaction has to be drawn.
Concept Introduction:
In organic chemistry, oxidation reaction is referred to the number
In organic chemistry, reduction reaction is referred to the number
Alcohols do undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and this id further oxidized to give carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.
Primary alcohol:
Secondary alcohol:
(c)
Answer to Problem 3.68EP
The structure of alcohol is,
Explanation of Solution
In organic chemistry, oxidation reaction is said to be decrease in
The given compound is a carboxylic acid. This has to be formed from aldehyde by oxidation. The aldehyde must have formed from primary alcohol by oxidation. The structure of the primary alcohol can be drawn considering the general scheme. Therefore, the structure can be given as shown below,
Structure of alcohol is drawn from which the given product is obtained by oxidation.
(d)
Interpretation:
The structure of alcohol that could be used to prepare the given compound by oxidation reaction has to be drawn.
Concept Introduction:
In organic chemistry, oxidation reaction is referred to the number
In organic chemistry, reduction reaction is referred to the number
Alcohols do undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and this id further oxidized to give carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.
Primary alcohol:
Secondary alcohol:
(d)
Answer to Problem 3.68EP
The structure of alcohol is,
Explanation of Solution
In organic chemistry, oxidation reaction is said to be decrease in
The given compound is a aldehyde. The aldehyde must have formed from primary alcohol by oxidation. The structure of the primary alcohol can be drawn considering the general scheme. Therefore, the structure can be given as shown below,
Structure of alcohol is drawn from which the given product is obtained by oxidation.
Want to see more full solutions like this?
Chapter 3 Solutions
Organic And Biological Chemistry
- Draw product A, indicating what type of reaction occurs. NH2 F3C CF3 NH OMe NH2-NH2, ACOH Aarrow_forwardPhotochemical smog is formed in part by the action of light on nitrogen dioxide. The wavelength of radiation absorbed by NO2 in this reaction is 197 nm.(a) Draw the Lewis structure of NO2 and sketch its π molecular orbitals.(b) When 1.56 mJ of energy is absorbed by 3.0 L of air at 20 °C and 0.91 atm, all the NO2 molecules in this sample dissociate by the reaction shown. Assume that each absorbed photon leads to the dissociation (into NO and O) of one NO2 molecule. What is the proportion, in parts per million, of NO2 molecules in this sample? Assume that the sample behaves ideally.arrow_forwardCorrect each molecule in the drawing area below so that it has the skeletal ("line") structure it would have if it were dissolved in a 0.1 M aqueous solution of HCI. If there are no changes to be made, check the No changes box under the drawing area. No changes. HO Explanation Check NH, 2 W O :□ G ©2025 M unter Accessibilityarrow_forward
- An expression for the root mean square velocity, vrms, of a gas was derived. Using Maxwell’s velocity distribution, one can also calculate the mean velocity and the most probable velocity (mp) of a collection of molecules. The equations used for these two quantities are vmean=(8RT/πM)1/2 and vmp=(2RT/M)1/2 These values have a fixed relationship to each other.(a) Arrange these three quantities in order of increasing magnitude.(b) Show that the relative magnitudes are independent of the molar mass of the gas.(c) Use the smallest velocity as a reference for establishing the order of magnitude and determine the relationship between the larger and smaller values.arrow_forwardThe reaction of solid dimethylhydrazine, (CH3)2N2H2, and liquefied dinitrogen tetroxide, N2O4, has been investigated for use as rocket fuel. The reaction produces the gases carbon dioxide (CO2), nitrogen (N2), and water vapor (H2O), which are ejected in the exhaust gases. In a controlled experiment, solid dimethylhydrazine was reacted with excess dinitrogen tetroxide, and the gases were collected in a closed balloon until a pressure of 2.50 atm and a temperature of 400.0 K were reached.(a) What are the partial pressures of CO2, N2, and H2O?(b) When the CO2 is removed by chemical reaction, what are the partial pressures of the remaining gases?arrow_forwardOne liter of chlorine gas at 1 atm and 298 K reacts completely with 1.00 L of nitrogen gas and 2.00 L of oxygen gas at the same temperature and pressure. A single gaseous product is formed, which fills a 2.00 L flask at 1.00 atm and 298 K. Use this information to determine the following characteristics of the product:(a) its empirical formula;(b) its molecular formula;(c) the most favorable Lewis formula based on formal charge arguments (the central atom is N);(d) the shape of the molecule.arrow_forward
- How does the square root mean square velocity of gas molecules vary with temperature? Illustrate this relationship by plotting the square root mean square velocity of N2 molecules as a function of temperature from T=100 K to T=300 K.arrow_forwardDraw product B, indicating what type of reaction occurs. F3C CF3 NH2 Me O .N. + B OMearrow_forwardBenzimidazole E. State its formula. sState the differences in the formula with other benzimidazoles.arrow_forward
Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,
General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
World of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage Learning
Introductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning