
Concept explainers
(a)
Interpretation:
The structure of alcohol that could be used to prepare the given compound by oxidation reaction has to be drawn.
Concept Introduction:
In
In organic chemistry, reduction reaction is referred to the number
Alcohols do undergo
Primary alcohol:
Secondary alcohol:
(a)

Answer to Problem 3.68EP
The structure of alcohol is,
Explanation of Solution
In organic chemistry, oxidation reaction is said to be decrease in
The given compound is a aldehyde. The aldehyde must have formed from primary alcohol by oxidation. The structure of the primary alcohol can be drawn considering the general scheme. Therefore, the structure can be given as shown below,
Structure of alcohol is drawn from which the given product is obtained by oxidation.
(b)
Interpretation:
The structure of alcohol that could be used to prepare the given compound by oxidation reaction has to be drawn.
Concept Introduction:
In organic chemistry, oxidation reaction is referred to the number
In organic chemistry, reduction reaction is referred to the number
Alcohols do undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and this id further oxidized to give carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.
Primary alcohol:
Secondary alcohol:
(b)

Answer to Problem 3.68EP
The structure of alcohol is,
Explanation of Solution
In organic chemistry, oxidation reaction is said to be decrease in
The given compound is a ketone. This has to be formed from a secondary alcohol only on oxidation. The structure of the secondary alcohol can be drawn considering the general scheme. Therefore, the structure can be given as shown below,
Structure of alcohol is drawn from which the given product is obtained by oxidation.
(c)
Interpretation:
The structure of alcohol that could be used to prepare the given compound by oxidation reaction has to be drawn.
Concept Introduction:
In organic chemistry, oxidation reaction is referred to the number
In organic chemistry, reduction reaction is referred to the number
Alcohols do undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and this id further oxidized to give carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.
Primary alcohol:
Secondary alcohol:
(c)

Answer to Problem 3.68EP
The structure of alcohol is,
Explanation of Solution
In organic chemistry, oxidation reaction is said to be decrease in
The given compound is a carboxylic acid. This has to be formed from aldehyde by oxidation. The aldehyde must have formed from primary alcohol by oxidation. The structure of the primary alcohol can be drawn considering the general scheme. Therefore, the structure can be given as shown below,
Structure of alcohol is drawn from which the given product is obtained by oxidation.
(d)
Interpretation:
The structure of alcohol that could be used to prepare the given compound by oxidation reaction has to be drawn.
Concept Introduction:
In organic chemistry, oxidation reaction is referred to the number
In organic chemistry, reduction reaction is referred to the number
Alcohols do undergo oxidation reaction and reduction reaction. This depends upon the number of hydrogen atoms that is bonded to the alpha carbon atom. Primary and secondary alcohol undergoes oxidation reaction while tertiary alcohol does not undergo oxidation reaction. Primary alcohols undergo oxidation to give aldehyde and this id further oxidized to give carboxylic acid as product. Secondary alcohol undergoes oxidation to give ketone as the product.
Primary alcohol:
Secondary alcohol:
(d)

Answer to Problem 3.68EP
The structure of alcohol is,
Explanation of Solution
In organic chemistry, oxidation reaction is said to be decrease in
The given compound is a aldehyde. The aldehyde must have formed from primary alcohol by oxidation. The structure of the primary alcohol can be drawn considering the general scheme. Therefore, the structure can be given as shown below,
Structure of alcohol is drawn from which the given product is obtained by oxidation.
Want to see more full solutions like this?
Chapter 3 Solutions
Organic And Biological Chemistry
- Steps and explanation please. Add how to solve or target similar problems.arrow_forwardWould the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.arrow_forwardThis organic molecule is dissolved in an acidic aqueous solution: OH OH A short time later sensitive infrared spectroscopy reveals the presence of a new C = O stretch absorption. That is, there must now be a new molecule present with at least one C = O bond. In the drawing area below, show the detailed mechanism that could convert the molecule above into the new molecule. Videos 849 Explanation Check C Click and drag to start dwing a structure. # 3 MAR 23 Add/Remove steparrow_forward||| 7:47 ull 57% ← Problem 19 of 48 Submit Curved arrows are used to illustrate the flow of electrons. Use the reaction conditions provided and follow the curved arrows to draw the product of this carbocation rearrangement. Include all lone pairs and charges as appropriate. H 1,2-alkyl shift +arrow_forwardWould the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.arrow_forwardBelow is the SN1 reaction of (S)-3-chlorocyclohexene and hydroxide (OH). Draw the missing curved arrows, lone pairs of electrons, and nonzero formal charges. In the third box, draw the two enantiomeric products that will be produced. 5th attempt Please draw all four bonds at chiral centers. Draw the two enantiomeric products that will be produced. Draw in any hydrogen at chiral centers. 1000 4th attempt Feedback Please draw all four bonds at chiral centers. 8. R5 HO: See Periodic Table See Hint H Cl Br Jid See Periodic Table See Hintarrow_forwardShow that a molecule with configuration π4 has a cylindrically symmetric electron distribution. Hint: Let the π orbitals be equal to xf and yf, where f is a function that depends only on the distance from the internuclear axis.arrow_forward(a) Verify that the lattice energies of the alkali metal iodides are inversely proportional to the distances between the ions in MI (M = alkali metal) by plotting the lattice energies given below against the internuclear distances dMI. Is the correlation good? Would a better fit be obtained by plotting the lattice energies as a function of (1 — d*/d)/d, as theoretically suggested, with d* = 34.5 pm? You must use a standard graphing program to plot the graph. It generates an equation for the line and calculates a correlation coefficient. (b) From the graph obtained in (a), estimate the lattice energy of silver iodide. (c) Compare the results of (b) with the experimental value of 886 kJ/mol. If they do not agree, explain the deviation.arrow_forwardCan I please get help with #3 & 4? Thanks you so much!arrow_forwardarrow_back_iosSEE MORE QUESTIONSarrow_forward_ios
- Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
- World of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage LearningIntroductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning





