Concept explainers
(a)
Interpretation:
The given compound is a constitutional isomer of 1-hexanol or not has to be indicated.
Concept Introduction:
Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.
Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.
If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same
In case of alcohols, constitutional isomerism is possible for the compounds that contain three or more carbon atoms.
(b)
Interpretation:
The given compound is a constitutional isomer of 1-hexanol or not has to be indicated.
Concept Introduction:
Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.
Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.
If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.
In case of alcohols, constitutional isomerism is possible for the compounds that contain three or more carbon atoms.
(c)
Interpretation:
The given compound is a constitutional isomer of 1-hexanol or not has to be indicated.
Concept Introduction:
Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.
Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.
If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.
In case of alcohols, constitutional isomerism is possible for the compounds that contain three or more carbon atoms.
(d)
Interpretation:
The given compound is a constitutional isomer of 1-hexanol or not has to be indicated.
Concept Introduction:
Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.
Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.
If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.
In case of alcohols, constitutional isomerism is possible for the compounds that contain three or more carbon atoms.
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Chapter 3 Solutions
Organic And Biological Chemistry
- Draw a curved arrow mechanism for the reaction, adding steps as necessary. Be sure to include all electrons that are necessary to the mechanism and all nonzero formal charges. C Ö-H H + -S-OH .0. Add/Remove step X टे Click and drag to start drawing a structure.arrow_forwardDraw a curved arrow mechanism for its formation. You may need to re-draw structures to show certain bonds. Ensure that HSO is used as the base to deprotonate the ẞ carbon when necessary. C HO : OH HO: OH =s = + 1 Add/Remove step X Click and drag to start drawing a structure.arrow_forwardWhich of the following could 1,2-ethanediol be directly synthesized from? OH HO О 0 0. O ?arrow_forward
- Design a synthesis of 1,2-diethoxyethane from an alkene. Select the single best answer for each part. Part: 0/3 Part 1 of 3 Which of the following could 1,2-diethoxyethane be directly synthesized from? O HO 0 HO.... OH HO HO × 5 > ?arrow_forwardDraw the skeletal structure of the major organic product of each step of the reaction sequence. Part: 0/2 Part 1 of 2 Part: 1/2 Part 2 of 2 Continue OH NaH Na Na Br + Click and drag to start drawing a structure. X : X G : Garrow_forwardpleasearrow_forward
- please help me please pleasearrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: N2 (g) + 3H2 (g) = 2NH3 (g) AG⁰ = -34. KJ Now suppose a reaction vessel is filled with 8.06 atm of nitrogen (N2) and 2.58 atm of ammonia (NH3) at 106. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of N2 tend to rise or fall? ☐ x10 fall Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of N2 will tend to rise, can that be changed to a tendency to fall by adding H₂? Similarly, if you said the pressure of N2 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. yes no ☐ atm ☑ 5 00. 18 Ararrow_forwardi need help with the followingarrow_forward
- Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NO(g) +Cl₂ (g) = 2NOC1 (g) AGº = -41. kJ Now suppose a reaction vessel is filled with 8.90 atm of chlorine (C12) and 5.71 atm of nitrosyl chloride (NOC1) at 1075. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. atm ☑ 18 Ararrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HCN is a weak acid. acids: 0.29 mol of NaOH is added to 1.0 L of a 1.2M HCN solution. bases: ☑ other: 0.09 mol of HCl is added to acids: 1.0 L of a solution that is bases: 0.3M in both HCN and KCN. other: 0,0,... ? 00. 18 Ar 日arrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: 0.2 mol of KOH is added to 1.0 L of a 0.5 M HF solution. bases: Х other: ☐ acids: 0.10 mol of HI is added to 1.0 L of a solution that is 1.4M in both HF and NaF. bases: other: ☐ 0,0,... ด ? 18 Ararrow_forward
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