In a gaseous RbF molecule, the bond length is 2 . 274 × 1 0 − 1 0 m . Using data from Appendix F and making the same oversimplified assumption as in the prior problem on the shape of the potential curve from Rb + + F − to an internuclear separation of 2 . 274 × 1 0 − 1 0 m , calculate the energy in kJ mol − 1 required to dissociate RbF to neutral atoms.
In a gaseous RbF molecule, the bond length is 2 . 274 × 1 0 − 1 0 m . Using data from Appendix F and making the same oversimplified assumption as in the prior problem on the shape of the potential curve from Rb + + F − to an internuclear separation of 2 . 274 × 1 0 − 1 0 m , calculate the energy in kJ mol − 1 required to dissociate RbF to neutral atoms.
Solution Summary: The author explains that the energy required to dissociate RbF into neutral atoms is to be determined.
In a gaseous RbF molecule, the bond length is
2
.
274
×
1
0
−
1
0
m
. Using data from Appendix F and making the same oversimplified assumption as in the prior problem on the shape of the potential curve from
Rb
+
+
F
−
to an internuclear separation of
2
.
274
×
1
0
−
1
0
m
, calculate the energy in
kJ mol
−
1
required to dissociate RbF to neutral atoms.
Vibrational contributions to internal energy and heat capacity1) are temperature independent2) are temperature dependent
The approximation of calculating the partition function by integration instead of the summation of all the energy terms can only be done if the separation of the energy levels is much smaller than the product kT. Explain why.
Explain the meaning of: the electron partition function is equal to the degeneracy of the ground state.
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Quantum Molecular Orbital Theory (PChem Lecture: LCAO and gerade ungerade orbitals); Author: Prof Melko;https://www.youtube.com/watch?v=l59CGEstSGU;License: Standard YouTube License, CC-BY