FUND.OF GEN CHEM CHAP 1-13 W/ACCESS
16th Edition
ISBN: 9781323406038
Author: McMurry
Publisher: PEARSON C
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Textbook Question
Chapter 24.5, Problem 24.7P
How much energy is released as ATP from the complete oxidation of stearic acid
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How many ATP’s are formed in the process phosphoglyceraldehyde also known as PGAL?
Ethanol is oxidized in the liver to form acetate, which is then converted to acetyl-CoA. Determine how many molecules of ATP are produced from 1 mol of ethanol. (Note that 2 mol of NADH are produced when ethanol is oxidized to form acetate.)
Glyceraldehyde-3-phosphate (GAP) is converted to 1,3-bisphosphoglycerate (1,3-BPG)
as shown.
GAP + P + NAD+ 1,3-BPG + NADH
Is this reaction spontaneous? How do you know?
AG = 6.7 kJ mol-¹
The reaction shown above is coupled to the following reaction in which 1,3-BPG is
converted to 3-phosphoglycerate (3-PG):
GAP + P + NAD+ + ADP3-PG + NADH + ATP
AG = -18.8 kJ mol-¹
1,3-BPG+ADP3-PG+ATP
Write the equation for the overall conversion of GAP to 3PG. Is the coupled reaction
favorable? How do you know?
Chapter 24 Solutions
FUND.OF GEN CHEM CHAP 1-13 W/ACCESS
Ch. 24.1 - Prob. 24.1KCPCh. 24.3 - Prob. 24.2PCh. 24.3 - Prob. 24.3PCh. 24.5 - Prob. 24.4KCPCh. 24.5 - Prob. 24.5PCh. 24.5 - Prob. 24.6PCh. 24.5 - How much energy is released as ATP from the...Ch. 24.6 - Prob. 24.1CIAPCh. 24.6 - Prob. 24.2CIAPCh. 24.6 - Prob. 24.3CIAP
Ch. 24.6 - Prob. 24.8PCh. 24.6 - Prob. 24.9PCh. 24.7 - Prob. 24.4CIAPCh. 24.7 - Prob. 24.5CIAPCh. 24.7 - Prob. 24.6CIAPCh. 24.7 - What is atherosclerosis?Ch. 24.7 - Prob. 24.8CIAPCh. 24 - Oxygen is not a reactant in the oxidation of...Ch. 24 - Prob. 24.12UKCCh. 24 - Prob. 24.13UKCCh. 24 - Prob. 24.14UKCCh. 24 - Prob. 24.15UKCCh. 24 - Prob. 24.16UKCCh. 24 - Prob. 24.17UKCCh. 24 - Prob. 24.18UKCCh. 24 - Prob. 24.19APCh. 24 - Prob. 24.20APCh. 24 - Prob. 24.21APCh. 24 - Prob. 24.22APCh. 24 - Prob. 24.23APCh. 24 - Prob. 24.24APCh. 24 - Prob. 24.25APCh. 24 - Prob. 24.26APCh. 24 - Prob. 24.27APCh. 24 - Prob. 24.28APCh. 24 - Prob. 24.29APCh. 24 - Prob. 24.30APCh. 24 - Prob. 24.33APCh. 24 - Prob. 24.34APCh. 24 - Prob. 24.35APCh. 24 - Prob. 24.36APCh. 24 - Prob. 24.37APCh. 24 - Prob. 24.38APCh. 24 - Prob. 24.39APCh. 24 - Prob. 24.40APCh. 24 - Prob. 24.41APCh. 24 - Prob. 24.42APCh. 24 - Prob. 24.43APCh. 24 - Prob. 24.44APCh. 24 - Prob. 24.45APCh. 24 - Prob. 24.46APCh. 24 - Prob. 24.47APCh. 24 - Prob. 24.48APCh. 24 - Prob. 24.49APCh. 24 - Prob. 24.50APCh. 24 - Prob. 24.51APCh. 24 - Prob. 24.52APCh. 24 - Prob. 24.53APCh. 24 - Individuals suffering from ketoacidosis have...Ch. 24 - Prob. 24.55APCh. 24 - Prob. 24.56APCh. 24 - Prob. 24.57APCh. 24 - Prob. 24.58APCh. 24 - Why are fatty acids generally composed of an even...Ch. 24 - Prob. 24.60APCh. 24 - Prob. 24.62APCh. 24 - Prob. 24.63APCh. 24 - Prob. 24.64CPCh. 24 - Prob. 24.66CPCh. 24 - Prob. 24.67CPCh. 24 - Prob. 24.68CPCh. 24 - Prob. 24.70GPCh. 24 - In the synthesis of cholesterol, acetyl-CoA is...Ch. 24 - Prob. 24.72GP
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- How many ATP molecules can be generated from one mol of 14CH3-COOH? (The conversion of acetate to acetyl-CoA requires the consumption of 2 ATP.)arrow_forwardWith H2 as electron donor, why is reduction of Fe3+ a morefavorable reaction than reduction of fumarate?arrow_forwardwhich staments are falsearrow_forward
- Ethylene glycol (HO−CH2−CH2−OH) is a major component of antifreeze. In the body, it is first converted to HOOC−CHO (oxoethanoic acid) and then to HOOC−COOH (oxalic acid), which is toxic. What class of enzyme catalyzes both of the reactions of ethylene glycol? The treatment for the ingestion of ethylene glycol is an intravenous solution of ethanol. How might this help prevent toxic levels of oxalic acid in the body?arrow_forwardThe phosphorylation of glucose to glucose 1-phosphate requires 5.0 kcal/mol of energy. This unfavorable reaction can be driven by the hydrolysis of ATP to ADP. (a) Write the equation for the coupled reaction. (b) How much energy is released in the coupled reaction? glucose + HPO4---------->2– glucose 1-phosphate + H2Oarrow_forwardIn tricarboxylic acid cycle, what are the reactions that involve the following : (write down complete reactions with enzymes): (a) oxidative decarboxylation (b) hydration and dehydrationarrow_forward
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