EP GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
11th Edition
ISBN: 9780133897340
Author: Petrucci
Publisher: PEARSON CO
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 24, Problem 68SAE
Briefly describe each of the following ideas, phenomena, or methods: (a) spectrochemical series; (b) crystal field theory; (c) optical isomer; (d) structural isomerism.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
A complex ion is formed from one Fe*, two CN and four NO, ions.
(a)
What is the structural formula and name of the complex ion?
(b)
Identify the type of isomerism and draw the isomer structures exhibited by the
complex ion.
(c)
Draw the molecular orbital diagram and calculate the CFSE for the complex ion.
According to valence bond theory, what set of orbitals isused by a Period 4 metal ion in forming (a) a square planarcomplex; (b) a tetrahedral complex?
(i) What type of isomerism is shown by the complex [Cr(H2O)6]Cl3?(ii) On the basis of crystal field theory, write the electronic configuration for d4 ion if Δ0 > P.(iii) Write the hybridization and shape of [CoF6]3-.(Atomic number of Co = 27)
Chapter 24 Solutions
EP GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
Ch. 24 - Prob. 1ECh. 24 - Prob. 2ECh. 24 - Prob. 3ECh. 24 - Write appropriate formulas for the following. a....Ch. 24 - Prob. 5ECh. 24 - Prob. 6ECh. 24 - Prob. 7ECh. 24 - Prob. 8ECh. 24 - Prob. 9ECh. 24 - Prob. 10E
Ch. 24 - Prob. 11ECh. 24 - Prob. 12ECh. 24 - If A, B, C, and D are four different ligands, a....Ch. 24 - Prob. 14ECh. 24 - Prob. 15ECh. 24 - The structures of four complex ions are given....Ch. 24 - Prob. 17ECh. 24 - Prob. 18ECh. 24 - Prob. 19ECh. 24 - In contrast to the case of Co2+ considered in...Ch. 24 - Prob. 21ECh. 24 - Prob. 22ECh. 24 - Prob. 23ECh. 24 - Prob. 24ECh. 24 - Prob. 25ECh. 24 - Prob. 26ECh. 24 - Prob. 27ECh. 24 - Prob. 28ECh. 24 - Prob. 29ECh. 24 - Prob. 30ECh. 24 - Prob. 31ECh. 24 - Prob. 32ECh. 24 - Prob. 33ECh. 24 - Prob. 34ECh. 24 - Prob. 35ECh. 24 - Prob. 36ECh. 24 - Prob. 37ECh. 24 - Draw dashed and solid wedge diagrams of...Ch. 24 - Prob. 39IAECh. 24 - Prob. 40IAECh. 24 - Prob. 41IAECh. 24 - Prob. 42IAECh. 24 - Prob. 43IAECh. 24 - Prob. 44IAECh. 24 - Prob. 45IAECh. 24 - Prob. 46IAECh. 24 - Prob. 47IAECh. 24 - Prob. 48IAECh. 24 - Prob. 49IAECh. 24 - Prob. 50IAECh. 24 - Prob. 51IAECh. 24 - Prob. 52IAECh. 24 - Prob. 53IAECh. 24 - Prob. 54IAECh. 24 - The compound CoCl22H2O4NH2 may be one of the...Ch. 24 - Prob. 56IAECh. 24 - Provide a valence bond description of the bonding...Ch. 24 - Prob. 58IAECh. 24 - Prob. 59IAECh. 24 - Prob. 60IAECh. 24 - Prob. 61IAECh. 24 - Prob. 62IAECh. 24 - The graph that follows represents the molar...Ch. 24 - Prob. 64FPCh. 24 - Prob. 65FPCh. 24 - The crystal field stabilization energy (CFSE) can...Ch. 24 - In your own words, describe the following terms or...Ch. 24 - Briefly describe each of the following ideas,...Ch. 24 - Prob. 69SAECh. 24 - The oxidation state of Ni in the complex ion...Ch. 24 - Prob. 71SAECh. 24 - Prob. 72SAECh. 24 - Prob. 73SAECh. 24 - Prob. 74SAECh. 24 - Prob. 75SAECh. 24 - The most soluble of the following solids in...Ch. 24 - Prob. 77SAECh. 24 - Write appropriate formulas for the following...Ch. 24 - Prob. 79SAECh. 24 - Prob. 80SAECh. 24 - Prob. 81SAECh. 24 - Prob. 82SAECh. 24 - Prob. 83SAECh. 24 - Prob. 84SAE
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- (b) Consider the oxalate (ox) ligand and answer the following questions:(i) Draw the structure of the ox ligand.(ii) Identify all the donor atoms of the ligand.(iii) What is the denticity of the ligand?(iv) What is the charge of the ligand?(v) Draw the structure of a homoleptic octahedral complex with ox as the ligand.Clearly show the geometry at the metal centre.(vi) Identify the stereoisomer in the structure drawn.arrow_forward(b) Explain the bonding in coordination compounds in terms of Werner's postulates.arrow_forwardThe octahedral ion complex [CoF6] 3‒ absorbs at 675 nm. (a) What color is the complex? (b) Calculate the separation energy of the crystalline field Δο in kJ. mol ‒ 1 and in cm ‒ 1. (c) Draw the energy levels of the d orbitals and distribute to them the corresponding electrons of the metal center. Justify your answers.arrow_forward
- Chemistry Briefly define, describe or illustrate the following concepts: a) Crystal field theory b) Δο c) Chelating agent d) CFSE Inorganic chemistry, explain as much as possiblearrow_forward. Give the chemical formula that corresponds to each of the following compounds:(a) Sodium tetrahydroxozincate(II)(b) Dichlorobis(ethylenediamine)cobalt(III) nitrate(c) Triaquabromoplatinum(II) chloride(d) Tetra-amminedinitroplatinum(IV) bromidearrow_forwardPyridine (CsHgN), abbreviated py, is the molecule N: (a) Would you expect pyridine to act as a monodentate or bidentate ligand? (b) For the equilibrium reaction [Ru(py),(bipy)]²+ + 2 py = [Ru(py),J* + bipy would you predict the equilibrium constant to be larger or smaller than one?arrow_forward
- A coordination compound has the following composition (by mass %): 23.53% Co; 42.47% Cl, and 34.00% NH3. When 4.91 g of the compound is dissolved in 75.0 mL of deionized water, and the solution is reacted with an excess of AGNO; solution, it yields 5.60 g of AgCl precipitate. (a) Determine the empirical formula of the compound and write in the form of Co(NH;),Cl, (where x and 24. y are simple integers), and calculate its molar mass. (Assume the compound contains only one Co atom). (b) Deduce the number of chloride (Cl) as counter ions and as ligand, respectively. (c) Write the Werner's formula of the compound and give its systematic name. (Answers: (a) Co(NH3);C13; molar mass = 250.43 g/mol; (b) 2 Cl are counter ions and one is ligand; (c) [Co(NH3);CI]Cl2 = pentaammonechlorocobalt(III) chloride)arrow_forward(a) Draw all possible isomers of the octahedral complex [CoCl2(en)(NH3)2]*, where en is the bidentate ethylenediamine ligand. Name the isomers and identify their point group symmetry. (b) With the aid of simplified molecular orbital energy level diagrams, explain why the 18-electron rule applies to metal complexes of all coordination numbers and not just six coordinate complexes.arrow_forwardWrite the general electron configuration of a transition ele-ment (a) in Period 5; (b) in Period 6.arrow_forward
- What type of isomerism is shown by [CO(NH3)5ONO]Cl2? (ii) On the basis of crystal field theory, write the electronic configuration for d4 ion if A0 < P. (iii) Write the hybridization and shape of [Fe(CN)6]3-. (Atomic number of Fe — 26)arrow_forwardDraw the geometrical isomers of complex [Pt(en)2Cl2]2+. (ii) On the basis of crystal field theory, write the electronic configuration for d4 ion, if Δ0> P. (iii) Write the hybridization type and magnetic behaviour of the complexarrow_forward5. Combinations of Co(III), NH3, NO2 and K* can result in the formation of a series of seven coordination compounds (with 6-coordinate complexes), one of which is [Co(NH;)6](NO2)3. (a) Write the formulas for the other six members of the series. (b) Name each of the seven compounds. (c) Which, if any, of the compounds should form cis/trans geometric isomers? (d) Which, if any, of the compounds should form merlfac geometric isomers? Which, if any, of the compounds would be optically active (i.e., form non- superimposable mirror images)?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
The Bohr Model of the atom and Atomic Emission Spectra: Atomic Structure tutorial | Crash Chemistry; Author: Crash Chemistry Academy;https://www.youtube.com/watch?v=apuWi_Fbtys;License: Standard YouTube License, CC-BY