The concentration cell is given as follows: Ag | Ag + ( 0.10 M [ Ag(CN) 2 ] − , 0.10 MCN ) | | A g + ( 0.10 M ) | | A g | The value of Ecell is to be determined when the value of K f [Ag(CN) 2 ] - is 5.6×10 18 . Concept introduction: The Nernst equation is represented as follows: E = E ° − K T n e ln [ R e d ] [ O x ] Here, K is Boltzmann constant, T is temperature, ne is number of electrons transferred and [ R e d ] [ O x ] is the ratio of concentration of species that reduce and oxidize.

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Chapter 24, Problem 54IAE

Interpretation Introduction

Interpretation:

The concentration cell is given as follows:

Ag|Ag+(0.10M[Ag(CN)2]−,0.10MCN)||Ag+(0.10M)||Ag|

The value of Ecell is to be determined when the value of K_f [Ag(CN)₂]^- is 5.6×10¹⁸.

Concept introduction:

The Nernst equation is represented as follows:

E=E°−KTneln[Red][Ox]

Here, K is Boltzmann constant, T is temperature, ne is number of electrons transferred and [Red][Ox] is the ratio of concentration of species that reduce and oxidize.

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