The optically active complex ion is to be determined. Concept introduction: The optically active complexes are capable of rotating the plane of polarized light to the left or right. The optically active coordinate compound or complex compound has optically active isomers.

Question

Want to see the full answer?

Answer 1

Question

Chapter 24, Problem 73SAE

Interpretation Introduction

Interpretation:

The optically active complex ion is to be determined.

Concept introduction:

The optically active complexes are capable of rotating the plane of polarized light to the left or right. The optically active coordinate compound or complex compound has optically active isomers.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

The complex ion [Co(CO3)3]3-, an octahedral complex with bidentate carbonate ions as ligands, has one absorption in the visible region of the spectrum at 640 nm. From this information, (a) Predict the color of this complex and explain your reasoning. (b) Is the carbonate ion a weak- or strong-field ligand? (c) Predict whether [Co(CO3)3]3- will be paramagnetic or diamagnetic.

The complex ion [Co(H2O)6]3+ exhibits absorbance with max = 600 nm (orange region) , while [Co(NH3)6]3+ exhibits absorbance with max = 475 nm (blue region). (a) Determine the color of each complex ion. (b) Calculate the crystal-field splitting in each complex ion; expressed the splitting energy in kJ/mol. (No = 6.022 x 1023/mol; h = 6.626 x 10–34 J.s.; c = 3.00 x 108 m/s) Here are the answers for part (b), I am having a hard time trying to get these answers. Can you please show your work for part (b)? [Answers: (b) [Co(H2O)6]3+ : max = 600. nm; octahedral splitting energy, O = 200. kJ/mol; [Co(NH3)6]3+ : max = 475 nm; octahedral splitting energy, O = 252 kJ/mol]

Solutions of [Co(NH3)6]2+, [Co(H2O)6]2+ (both octahedral), and [CoCl4]2- (tetrahedral) are colored. One is pink, one is blue, and one is yellow. Based on the spectrochemical series and remembering that the energy splitting in tetrahedral complexes is normally much less than that in octahedral ones, assign a color to each complex.

Answer 2

Question

Chapter 24, Problem 73SAE

Interpretation Introduction

Interpretation:

The optically active complex ion is to be determined.

Concept introduction:

The optically active complexes are capable of rotating the plane of polarized light to the left or right. The optically active coordinate compound or complex compound has optically active isomers.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 24, Problem 73SAE

Interpretation Introduction

Interpretation:

The optically active complex ion is to be determined.

Concept introduction:

The optically active complexes are capable of rotating the plane of polarized light to the left or right. The optically active coordinate compound or complex compound has optically active isomers.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 24, Problem 73SAE

Interpretation Introduction

Interpretation:

The optically active complex ion is to be determined.

Concept introduction:

The optically active complexes are capable of rotating the plane of polarized light to the left or right. The optically active coordinate compound or complex compound has optically active isomers.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 24, Problem 73SAE

Interpretation Introduction

Interpretation:

The optically active complex ion is to be determined.

Concept introduction:

The optically active complexes are capable of rotating the plane of polarized light to the left or right. The optically active coordinate compound or complex compound has optically active isomers.

Answer 6

Chapter 24, Problem 73SAE

Interpretation Introduction

Interpretation:

The optically active complex ion is to be determined.

Concept introduction:

The optically active complexes are capable of rotating the plane of polarized light to the left or right. The optically active coordinate compound or complex compound has optically active isomers.

Answer 7

Chapter 24, Problem 73SAE

Interpretation Introduction

Interpretation:

The optically active complex ion is to be determined.

Concept introduction:

The optically active complexes are capable of rotating the plane of polarized light to the left or right. The optically active coordinate compound or complex compound has optically active isomers.

Answer 8

Expert Solution & Answer

Answer 9

Expert Solution & Answer

Answer 10

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 11

Ch. 24 - Prob. 1E Ch. 24 - Prob. 2E Ch. 24 - Prob. 3E Ch. 24 - Write appropriate formulas for the following. a....Ch. 24 - Prob. 5E Ch. 24 - Prob. 6E Ch. 24 - Prob. 7E Ch. 24 - Prob. 8E Ch. 24 - Prob. 9E Ch. 24 - Prob. 10E

The optically active complex ion is to be determined. Concept introduction: The optically active complexes are capable of rotating the plane of polarized light to the left or right. The optically active coordinate compound or complex compound has optically active isomers.

Solution Summary: The author explains that the optically active complex ion is to be determined. The correct option is cis-[CoCl 2 (en) 2 ] + because it has non-superimposable mirror image

Concept explainers

Videos

Interpretation:

The optically active complex ion is to be determined.

Concept introduction:

The optically active complexes are capable of rotating the plane of polarized light to the left or right. The optically active coordinate compound or complex compound has optically active isomers.

Want to see the full answer?

Chapter 24 Solutions

The optically active complex ion is to be determined. Concept introduction: The optically active complexes are capable of rotating the plane of polarized light to the left or right. The optically active coordinate compound or complex compound has optically active isomers.

Solution Summary: The author explains that the optically active complex ion is to be determined. The correct option is cis-[CoCl 2 (en) 2 ] + because it has non-superimposable mirror image

Concept explainers

Videos

Interpretation: The optically active complex ion is to be determined. Concept introduction: The optically active complexes are capable of rotating the plane of polarized light to the left or right. The optically active coordinate compound or complex compound has optically active isomers.

Want to see the full answer?

Chapter 24 Solutions

Interpretation:

The optically active complex ion is to be determined.

Concept introduction:

The optically active complexes are capable of rotating the plane of polarized light to the left or right. The optically active coordinate compound or complex compound has optically active isomers.