EP GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
11th Edition
ISBN: 9780133897340
Author: Petrucci
Publisher: PEARSON CO
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 24, Problem 17E
Interpretation Introduction
Interpretation:
The reason for
Concept introduction:
According to the crystal field theory, due to the presence of ligand, the dor f orbital of the metal ion in transition state will break into two energy groups which will emit white light and after absorption of some of the
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
Apply the concept of crystal-field theory to explain some of the interesting spectral and magnetic properties of coordination compounds?
Give two examples of ligands which form coordination compounds useful in analytical chemistry.
<p>Draw a crystal field splitting diagram for a trigonal planar complex ion. Assume the plane of the molecule is perpendicular to the z axis.
Chapter 24 Solutions
EP GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
Ch. 24 - Prob. 1ECh. 24 - Prob. 2ECh. 24 - Prob. 3ECh. 24 - Write appropriate formulas for the following. a....Ch. 24 - Prob. 5ECh. 24 - Prob. 6ECh. 24 - Prob. 7ECh. 24 - Prob. 8ECh. 24 - Prob. 9ECh. 24 - Prob. 10E
Ch. 24 - Prob. 11ECh. 24 - Prob. 12ECh. 24 - If A, B, C, and D are four different ligands, a....Ch. 24 - Prob. 14ECh. 24 - Prob. 15ECh. 24 - The structures of four complex ions are given....Ch. 24 - Prob. 17ECh. 24 - Prob. 18ECh. 24 - Prob. 19ECh. 24 - In contrast to the case of Co2+ considered in...Ch. 24 - Prob. 21ECh. 24 - Prob. 22ECh. 24 - Prob. 23ECh. 24 - Prob. 24ECh. 24 - Prob. 25ECh. 24 - Prob. 26ECh. 24 - Prob. 27ECh. 24 - Prob. 28ECh. 24 - Prob. 29ECh. 24 - Prob. 30ECh. 24 - Prob. 31ECh. 24 - Prob. 32ECh. 24 - Prob. 33ECh. 24 - Prob. 34ECh. 24 - Prob. 35ECh. 24 - Prob. 36ECh. 24 - Prob. 37ECh. 24 - Draw dashed and solid wedge diagrams of...Ch. 24 - Prob. 39IAECh. 24 - Prob. 40IAECh. 24 - Prob. 41IAECh. 24 - Prob. 42IAECh. 24 - Prob. 43IAECh. 24 - Prob. 44IAECh. 24 - Prob. 45IAECh. 24 - Prob. 46IAECh. 24 - Prob. 47IAECh. 24 - Prob. 48IAECh. 24 - Prob. 49IAECh. 24 - Prob. 50IAECh. 24 - Prob. 51IAECh. 24 - Prob. 52IAECh. 24 - Prob. 53IAECh. 24 - Prob. 54IAECh. 24 - The compound CoCl22H2O4NH2 may be one of the...Ch. 24 - Prob. 56IAECh. 24 - Provide a valence bond description of the bonding...Ch. 24 - Prob. 58IAECh. 24 - Prob. 59IAECh. 24 - Prob. 60IAECh. 24 - Prob. 61IAECh. 24 - Prob. 62IAECh. 24 - The graph that follows represents the molar...Ch. 24 - Prob. 64FPCh. 24 - Prob. 65FPCh. 24 - The crystal field stabilization energy (CFSE) can...Ch. 24 - In your own words, describe the following terms or...Ch. 24 - Briefly describe each of the following ideas,...Ch. 24 - Prob. 69SAECh. 24 - The oxidation state of Ni in the complex ion...Ch. 24 - Prob. 71SAECh. 24 - Prob. 72SAECh. 24 - Prob. 73SAECh. 24 - Prob. 74SAECh. 24 - Prob. 75SAECh. 24 - The most soluble of the following solids in...Ch. 24 - Prob. 77SAECh. 24 - Write appropriate formulas for the following...Ch. 24 - Prob. 79SAECh. 24 - Prob. 80SAECh. 24 - Prob. 81SAECh. 24 - Prob. 82SAECh. 24 - Prob. 83SAECh. 24 - Prob. 84SAE
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- What structural feature is used to determine whether a compound can exist as optical isomers?arrow_forwardAn aqueous solution of [Rh(C2O4)3]3− is yellow. Predict the approximate wavelength and predominant color of light absorbed by the complex.arrow_forwardFor each d electron configuration, state the number of unpaired electrons expected in octahedral complexes. Give an example complex for each case. (Two answers are possible for some of these cases.) (a) d2 (b) d4 (c) d6 (d) d8arrow_forward
- Define the terms complex ion, ligand, and coordination number. Use an example to illustrate the use of these terms.arrow_forwardFluoride ion ranks low in the spectrochemical series and produces a weak crystal field in complex ions. Based on this information, predict the number of unpaired electrons in CoF,.arrow_forward<p>Draw a crystal field splitting diagram for a trigonal bipyramidal complex ion. Assume the axial positions are on the z axis.arrow_forward
- The molecule CO is a common ligand in transition metal complexes forming a strong bond with the metal ion. b) Based on Lewis structure of CO, which end of the CO molecule do you think is the electron source to form the metal-ligand bond? Why?arrow_forwardK2[Cu(CN)2Cl2] a.Systematic name b.The coordination number c.The correct hybridization for the metal ion, based on the valence bond theory e.Draw the energy level diagram based on the crystal field theory f.The magnetic behaviour of the central metal ion.arrow_forwardINORGANIC CHEMISTRYarrow_forward
- Explain the process of how coordination compounds are formed.arrow_forwardCrystal Field Theory: Answer the question and provide complete solution a. Draw the electronic configuration of [NiCl.]. Determine whether its paramagnetic or diamagnetic. What is expected to happen to the color if the ligand is replaced by carbonyl?arrow_forwardConsider an octahedral complex where strong field ligands are bound to a central metal having a d electronic configuration of 3d5. Which of the following is most likely to be TRUE about the 3d orbitals in this complex following the concept of valence bond theory? The five 3d orbitals are split into two levels, with three orbitals in the lower level. All the 3d orbitals are occupied so hybridization of orbitals involves the vacant 4s, 4p, and 4d orbitals, forming six sp3d2 hybrid orbitals. The five 3d orbitals are split into two levels, with three orbitals in the upper level. There are two vacant 3d orbitals, and these may combine with the unoccupied 4s and 4p orbitals to form six d2sp3 hybrid orbitals.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning