EP GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
EP GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
11th Edition
ISBN: 9780133897340
Author: Petrucci
Publisher: PEARSON CO
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Chapter 24, Problem 47IAE
Interpretation Introduction

(a)

Interpretation:

The pH of the solution should be determined.

Concept introduction:

A complex ion is formed when a metal ion reacts with a Lewis base in solution. This reaction is defined in terms of chemical equilibrium. A complexion comprises of a ligand and a metal ion as a result of an interaction of Lewis acid-base.

The Metal ion which is positively charged functions as a Lewis acid and Lewis base or the ligand has one or more lone pairs of electrons. For example, Cu2+, which is a highly charged and small metal ion having a significant tendency to function as Lewis acids, consequently exhibiting the highest affinity to form complex ions.

The development of a complexion is a stepwise procedure, and every step has its equilibrium constant. When two of the equations are added together, the equilibrium constants multiply. The Equilibrium Constant reflects the concentration in a reaction, which is the molarity, written as moles per liter (M = mol/L).

K=[C]c[D]d[A]a[B]b

The products of a reaction are present in the numerator, and the denominator has the reactants. The alphabets in upper-case are the molar concentrations of the reactants and products, and the alphabets in lower-case are the stoichiometric coefficients which balance the equation.

This implies that the pH of any solution is the log of the hydrogen ion concentration of that solution. For the calculation of pH, the log of the hydrogen ion concentration is selected, and the sign is reversed to obtain the answer.

Interpretation Introduction

(b)

Interpretation:

The concentration of [Fe(H2O)5OH]2+(aq) should be determined when the given solution is also 0.100 M HClO4 (where ClO4-does not complex with Fe3+).

Concept introduction:

A complex ion is formed when a metal ion reacts with a Lewis base in solution. This reaction is defined in terms of chemical equilibrium. A complexion comprises of a ligand and a metal ion as a result of an interaction of Lewis acid-base. The Metal ion which is positively charged functions as a Lewis acid and Lewis base or the ligand has one or more lone pairs of electrons. For example, Cu2+, which is a highly charged and small metal ion having a significant tendency to function as Lewis acids, consequently exhibiting the highest affinity to form complex ions.

The development of a complexion is a stepwise procedure, and every step has its equilibrium constant. When two of the equations are added together, the equilibrium constants multiply. The Equilibrium Constant reflects the concentration in a reaction, which is the molarity, written as moles per liter (M = mol/L).

The products of a reaction are present in the numerator, and the denominator has the reactants. The alphabets in upper-case are the molar concentrations of the reactants and products, and the alphabets in lower-case are the stoichiometric coefficients which balance the equation.

K=[C]c[D]d[A]a[B]b

pH= log [H+]. This implies that the pH of any solution is the log of the hydrogen ion concentration of that solution. For the calculation of pH, the log of the hydrogen ion concentration is selected, and the sign is reversed to obtain the answer.

Interpretation Introduction

(c)

Interpretation:

Whether the pH of the solution can be maintained so that does not exceed 1×10-6 M.

Concept introduction:

A complex ion is formed when a metal ion reacts with a Lewis base in solution. This reaction is defined in terms of chemical equilibrium. A complexion comprises of a ligand and a metal ion as a result of an interaction of Lewis acid-base.

The Metal ion which is positively charged functions as a Lewis acid and Lewis base or the ligand has one or more lone pairs of electrons. For example, Cu2+, which is a highly charged and small metal ion having a significant tendency to function as Lewis acids, consequently exhibiting the highest affinity to form complex ions.

The development of a complexion is a stepwise procedure, and every step has its equilibrium constant. When two of the equations are added together, the equilibrium constants multiply. The Equilibrium Constant reflects the concentration in a reaction, which is the molarity, written as moles per liter (M = mol/L).

K=[C]c[D]d[A]a[B]b

The products of a reaction are present in the numerator, and the denominator has the reactants. The alphabets in upper-case are the molar concentrations of the reactants and products, and the alphabets in lower-case are the stoichiometric coefficients which balance the equation.

pH= log [H+] This implies that the pH of any solution is the log of the hydrogen ion concentration of that solution. For the calculation of pH, the log of the hydrogen ion concentration is selected, and the sign is reversed to obtain the answer.

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Chapter 24 Solutions

EP GENERAL CHEMISTRY-MOD.MASTERINGCHEM.

Ch. 24 - Prob. 11ECh. 24 - Prob. 12ECh. 24 - If A, B, C, and D are four different ligands, a....Ch. 24 - Prob. 14ECh. 24 - Prob. 15ECh. 24 - The structures of four complex ions are given....Ch. 24 - Prob. 17ECh. 24 - Prob. 18ECh. 24 - Prob. 19ECh. 24 - In contrast to the case of Co2+ considered in...Ch. 24 - Prob. 21ECh. 24 - Prob. 22ECh. 24 - Prob. 23ECh. 24 - Prob. 24ECh. 24 - Prob. 25ECh. 24 - Prob. 26ECh. 24 - Prob. 27ECh. 24 - Prob. 28ECh. 24 - Prob. 29ECh. 24 - Prob. 30ECh. 24 - Prob. 31ECh. 24 - Prob. 32ECh. 24 - Prob. 33ECh. 24 - Prob. 34ECh. 24 - Prob. 35ECh. 24 - Prob. 36ECh. 24 - Prob. 37ECh. 24 - Draw dashed and solid wedge diagrams of...Ch. 24 - Prob. 39IAECh. 24 - Prob. 40IAECh. 24 - Prob. 41IAECh. 24 - Prob. 42IAECh. 24 - Prob. 43IAECh. 24 - Prob. 44IAECh. 24 - Prob. 45IAECh. 24 - Prob. 46IAECh. 24 - Prob. 47IAECh. 24 - Prob. 48IAECh. 24 - Prob. 49IAECh. 24 - Prob. 50IAECh. 24 - Prob. 51IAECh. 24 - Prob. 52IAECh. 24 - Prob. 53IAECh. 24 - Prob. 54IAECh. 24 - The compound CoCl22H2O4NH2 may be one of the...Ch. 24 - Prob. 56IAECh. 24 - Provide a valence bond description of the bonding...Ch. 24 - Prob. 58IAECh. 24 - Prob. 59IAECh. 24 - Prob. 60IAECh. 24 - Prob. 61IAECh. 24 - Prob. 62IAECh. 24 - The graph that follows represents the molar...Ch. 24 - Prob. 64FPCh. 24 - Prob. 65FPCh. 24 - The crystal field stabilization energy (CFSE) can...Ch. 24 - In your own words, describe the following terms or...Ch. 24 - Briefly describe each of the following ideas,...Ch. 24 - Prob. 69SAECh. 24 - The oxidation state of Ni in the complex ion...Ch. 24 - Prob. 71SAECh. 24 - Prob. 72SAECh. 24 - Prob. 73SAECh. 24 - Prob. 74SAECh. 24 - Prob. 75SAECh. 24 - The most soluble of the following solids in...Ch. 24 - Prob. 77SAECh. 24 - Write appropriate formulas for the following...Ch. 24 - Prob. 79SAECh. 24 - Prob. 80SAECh. 24 - Prob. 81SAECh. 24 - Prob. 82SAECh. 24 - Prob. 83SAECh. 24 - Prob. 84SAE
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