EP GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
EP GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
11th Edition
ISBN: 9780133897340
Author: Petrucci
Publisher: PEARSON CO
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Chapter 24, Problem 10E
Interpretation Introduction

(a)

Interpretation:

The structure of complex pentamminenitrito-N-cobalt(III)ion needs to be drawn.

Concept introduction:

The structure of chelate complex is formed in such a way that the ligands are linked through covalent bonds wherein the metal ion is at the centre with ligands on either side of the metal ion.

The structures gets arranged to give a square planar, octahedral or tetrahedral sturcutre. Structures gets arranged to form a stable or symmetrical geometry.

Interpretation Introduction

(b)

Interpretation:

The structure of chelate complex ethylenediaminedithiocyanato-S-copper(II) needs to be drawn.

Concept introduction:

Structure of chelates are formed in such a way that multidentate ligands uses more that one atom to bind to a metal ion wherein the ligands are attached to the central atom. It is mostly in the form of rings or have square planar and tetrahedral structures. The geometry needs to be stable and hence, the molecules undergo rearrangement.

Interpretation Introduction

(c)

Interpretation:

The structure of hexaaquanickel(II) ion needs to be drawn.

Concept introduction:

Chelate indicates those structure which are cyclic in nature and metal ions unite with organic or inorganic molecules. The presence of mulitdentate ligands uses more atoms to bind to metal ion where ligands get attached to the central atom. The structure is mostly in the form of rings. The structure is

either square planar or tetrahedral. The geometry needs to be stable for which the molecules undergo rearrangement.

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Students have asked these similar questions
what is the formula of:  i. tetraamminebromochloroplatinum(IV) chloride  ii. hexaamminecobalt(III)tetrachloroferrate(III)   2. What is the structure of each of the ligands below, showing the donor atoms with their lone pair(s) of electrons  a. hydroxide ion b. thiocyanate ion c. Ethylene diammine [en] d. Oxalate ion e. dipyridyl [bipy]   3. what are ambidentate and bridging ligands? Give two examples of each.    4. Identify the cental metal ion, complex ion, ligands and counter ions in the complexes; [Pt(NH2)4]Br2  and [Co(NH3)4Cl2]Cl
6. Write formulas for the following compounds: a) pentaaquofluororuthenium(II) chloride b) aquabis(ethylenediamine) hydroxocobalt(III) nitrate c) sodium d) dibromodioxalatocobaltate(III) pentaamminechromium(III)-u-chloropentaaquochromium(III) chloride
give an example of tetradentate ligand.

Chapter 24 Solutions

EP GENERAL CHEMISTRY-MOD.MASTERINGCHEM.

Ch. 24 - Prob. 11ECh. 24 - Prob. 12ECh. 24 - If A, B, C, and D are four different ligands, a....Ch. 24 - Prob. 14ECh. 24 - Prob. 15ECh. 24 - The structures of four complex ions are given....Ch. 24 - Prob. 17ECh. 24 - Prob. 18ECh. 24 - Prob. 19ECh. 24 - In contrast to the case of Co2+ considered in...Ch. 24 - Prob. 21ECh. 24 - Prob. 22ECh. 24 - Prob. 23ECh. 24 - Prob. 24ECh. 24 - Prob. 25ECh. 24 - Prob. 26ECh. 24 - Prob. 27ECh. 24 - Prob. 28ECh. 24 - Prob. 29ECh. 24 - Prob. 30ECh. 24 - Prob. 31ECh. 24 - Prob. 32ECh. 24 - Prob. 33ECh. 24 - Prob. 34ECh. 24 - Prob. 35ECh. 24 - Prob. 36ECh. 24 - Prob. 37ECh. 24 - Draw dashed and solid wedge diagrams of...Ch. 24 - Prob. 39IAECh. 24 - Prob. 40IAECh. 24 - Prob. 41IAECh. 24 - Prob. 42IAECh. 24 - Prob. 43IAECh. 24 - Prob. 44IAECh. 24 - Prob. 45IAECh. 24 - Prob. 46IAECh. 24 - Prob. 47IAECh. 24 - Prob. 48IAECh. 24 - Prob. 49IAECh. 24 - Prob. 50IAECh. 24 - Prob. 51IAECh. 24 - Prob. 52IAECh. 24 - Prob. 53IAECh. 24 - Prob. 54IAECh. 24 - The compound CoCl22H2O4NH2 may be one of the...Ch. 24 - Prob. 56IAECh. 24 - Provide a valence bond description of the bonding...Ch. 24 - Prob. 58IAECh. 24 - Prob. 59IAECh. 24 - Prob. 60IAECh. 24 - Prob. 61IAECh. 24 - Prob. 62IAECh. 24 - The graph that follows represents the molar...Ch. 24 - Prob. 64FPCh. 24 - Prob. 65FPCh. 24 - The crystal field stabilization energy (CFSE) can...Ch. 24 - In your own words, describe the following terms or...Ch. 24 - Briefly describe each of the following ideas,...Ch. 24 - Prob. 69SAECh. 24 - The oxidation state of Ni in the complex ion...Ch. 24 - Prob. 71SAECh. 24 - Prob. 72SAECh. 24 - Prob. 73SAECh. 24 - Prob. 74SAECh. 24 - Prob. 75SAECh. 24 - The most soluble of the following solids in...Ch. 24 - Prob. 77SAECh. 24 - Write appropriate formulas for the following...Ch. 24 - Prob. 79SAECh. 24 - Prob. 80SAECh. 24 - Prob. 81SAECh. 24 - Prob. 82SAECh. 24 - Prob. 83SAECh. 24 - Prob. 84SAE
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