Referring to the figure 22.27 given in textbook maximum absorption of the complex ion [ T i ( H 2 O ) 6 ] 3 + has to be determined. Concept Introduction: Almost all the Co-ordination compounds are colored compounds. Presence of unpaired electrons in a complex compound makes it colored as the unpaired electrons undergo transition from lower energy level to higher energy level. The color of the complex observed is complementary to the color absorbed in the wavelength region.

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Answer 1

Question

Chapter 22, Problem 22.92QP

(a)

Interpretation Introduction

Interpretation:

Referring to the figure 22.27 given in textbook maximum absorption of the complex ion [Ti(H2O)6]3+ has to be determined.

Concept Introduction:

Almost all the Co-ordination compounds are colored compounds. Presence of unpaired electrons in a complex compound makes it colored as the unpaired electrons undergo transition from lower energy level to higher energy level. The color of the complex observed is complementary to the color absorbed in the wavelength region.

(b)

Interpretation Introduction

Interpretation:

The absorption curve of [Ti(H2O)6]3+ and that of [Ti(CN)6]3− has to be compared.

Concept Introduction:

Almost all the Co-ordination compounds are colored compounds. Presence of unpaired electrons in a complex compound makes it colored as the unpaired electrons undergo transition from lower energy level to higher energy level. The color of the complex observed is complementary to the color absorbed in the wavelength region.

Stronger the ligand greater will be the crystal field splitting energy and lower will be the wavelength of absorption.

(c)

Interpretation Introduction

Interpretation:

The crystal field splitting energy of [Ti(H2O)6]3+ and that of [Ti(CN)6]3− has to be compared.

Concept Introduction:

Stronger the ligand greater will be the crystal field splitting energy and lower will be the wavelength of absorption.

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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression: AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T A. Calculate the value of AS for the process. B. Next, use the Gibbs-Helmholtz equation: (a(AG/T)) ΔΗ - T2 to calculate the value of AH for the process.

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Answer 2

Question

Chapter 22, Problem 22.92QP

(a)

Interpretation Introduction

Interpretation:

Referring to the figure 22.27 given in textbook maximum absorption of the complex ion [Ti(H2O)6]3+ has to be determined.

Concept Introduction:

Almost all the Co-ordination compounds are colored compounds. Presence of unpaired electrons in a complex compound makes it colored as the unpaired electrons undergo transition from lower energy level to higher energy level. The color of the complex observed is complementary to the color absorbed in the wavelength region.

(b)

Interpretation Introduction

Interpretation:

The absorption curve of [Ti(H2O)6]3+ and that of [Ti(CN)6]3− has to be compared.

Concept Introduction:

Almost all the Co-ordination compounds are colored compounds. Presence of unpaired electrons in a complex compound makes it colored as the unpaired electrons undergo transition from lower energy level to higher energy level. The color of the complex observed is complementary to the color absorbed in the wavelength region.

Stronger the ligand greater will be the crystal field splitting energy and lower will be the wavelength of absorption.

(c)

Interpretation Introduction

Interpretation:

The crystal field splitting energy of [Ti(H2O)6]3+ and that of [Ti(CN)6]3− has to be compared.

Concept Introduction:

Stronger the ligand greater will be the crystal field splitting energy and lower will be the wavelength of absorption.

Expert Solution & Answer

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Answer 3

Question

Chapter 22, Problem 22.92QP

(a)

Interpretation Introduction

Interpretation:

Referring to the figure 22.27 given in textbook maximum absorption of the complex ion [Ti(H2O)6]3+ has to be determined.

Concept Introduction:

Almost all the Co-ordination compounds are colored compounds. Presence of unpaired electrons in a complex compound makes it colored as the unpaired electrons undergo transition from lower energy level to higher energy level. The color of the complex observed is complementary to the color absorbed in the wavelength region.

(b)

Interpretation Introduction

Interpretation:

The absorption curve of [Ti(H2O)6]3+ and that of [Ti(CN)6]3− has to be compared.

Concept Introduction:

Almost all the Co-ordination compounds are colored compounds. Presence of unpaired electrons in a complex compound makes it colored as the unpaired electrons undergo transition from lower energy level to higher energy level. The color of the complex observed is complementary to the color absorbed in the wavelength region.

Stronger the ligand greater will be the crystal field splitting energy and lower will be the wavelength of absorption.

(c)

Interpretation Introduction

Interpretation:

The crystal field splitting energy of [Ti(H2O)6]3+ and that of [Ti(CN)6]3− has to be compared.

Concept Introduction:

Stronger the ligand greater will be the crystal field splitting energy and lower will be the wavelength of absorption.

Expert Solution & Answer

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Answer 4

Question

Chapter 22, Problem 22.92QP

(a)

Interpretation Introduction

Interpretation:

Referring to the figure 22.27 given in textbook maximum absorption of the complex ion [Ti(H2O)6]3+ has to be determined.

Concept Introduction:

Almost all the Co-ordination compounds are colored compounds. Presence of unpaired electrons in a complex compound makes it colored as the unpaired electrons undergo transition from lower energy level to higher energy level. The color of the complex observed is complementary to the color absorbed in the wavelength region.

(b)

Interpretation Introduction

Interpretation:

The absorption curve of [Ti(H2O)6]3+ and that of [Ti(CN)6]3− has to be compared.

Concept Introduction:

Almost all the Co-ordination compounds are colored compounds. Presence of unpaired electrons in a complex compound makes it colored as the unpaired electrons undergo transition from lower energy level to higher energy level. The color of the complex observed is complementary to the color absorbed in the wavelength region.

Stronger the ligand greater will be the crystal field splitting energy and lower will be the wavelength of absorption.

(c)

Interpretation Introduction

Interpretation:

The crystal field splitting energy of [Ti(H2O)6]3+ and that of [Ti(CN)6]3− has to be compared.

Concept Introduction:

Stronger the ligand greater will be the crystal field splitting energy and lower will be the wavelength of absorption.

Expert Solution & Answer

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Answer 5

Chapter 22, Problem 22.92QP

(a)

Interpretation Introduction

Interpretation:

Referring to the figure 22.27 given in textbook maximum absorption of the complex ion [Ti(H2O)6]3+ has to be determined.

Concept Introduction:

Almost all the Co-ordination compounds are colored compounds. Presence of unpaired electrons in a complex compound makes it colored as the unpaired electrons undergo transition from lower energy level to higher energy level. The color of the complex observed is complementary to the color absorbed in the wavelength region.

(b)

Interpretation Introduction

Interpretation:

The absorption curve of [Ti(H2O)6]3+ and that of [Ti(CN)6]3− has to be compared.

Concept Introduction:

Almost all the Co-ordination compounds are colored compounds. Presence of unpaired electrons in a complex compound makes it colored as the unpaired electrons undergo transition from lower energy level to higher energy level. The color of the complex observed is complementary to the color absorbed in the wavelength region.

Stronger the ligand greater will be the crystal field splitting energy and lower will be the wavelength of absorption.

(c)

Interpretation Introduction

Interpretation:

The crystal field splitting energy of [Ti(H2O)6]3+ and that of [Ti(CN)6]3− has to be compared.

Concept Introduction:

Stronger the ligand greater will be the crystal field splitting energy and lower will be the wavelength of absorption.

Answer 6

Chapter 22, Problem 22.92QP

(a)

Interpretation Introduction

Interpretation:

Referring to the figure 22.27 given in textbook maximum absorption of the complex ion [Ti(H2O)6]3+ has to be determined.

Concept Introduction:

Almost all the Co-ordination compounds are colored compounds. Presence of unpaired electrons in a complex compound makes it colored as the unpaired electrons undergo transition from lower energy level to higher energy level. The color of the complex observed is complementary to the color absorbed in the wavelength region.

Answer 7

Chapter 22, Problem 22.92QP

(a)

Interpretation Introduction

Interpretation:

Referring to the figure 22.27 given in textbook maximum absorption of the complex ion [Ti(H2O)6]3+ has to be determined.

Concept Introduction:

Almost all the Co-ordination compounds are colored compounds. Presence of unpaired electrons in a complex compound makes it colored as the unpaired electrons undergo transition from lower energy level to higher energy level. The color of the complex observed is complementary to the color absorbed in the wavelength region.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The absorption curve of [Ti(H2O)6]3+ and that of [Ti(CN)6]3− has to be compared.

Concept Introduction:

Almost all the Co-ordination compounds are colored compounds. Presence of unpaired electrons in a complex compound makes it colored as the unpaired electrons undergo transition from lower energy level to higher energy level. The color of the complex observed is complementary to the color absorbed in the wavelength region.

Stronger the ligand greater will be the crystal field splitting energy and lower will be the wavelength of absorption.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The absorption curve of [Ti(H2O)6]3+ and that of [Ti(CN)6]3− has to be compared.

Concept Introduction:

Almost all the Co-ordination compounds are colored compounds. Presence of unpaired electrons in a complex compound makes it colored as the unpaired electrons undergo transition from lower energy level to higher energy level. The color of the complex observed is complementary to the color absorbed in the wavelength region.

Stronger the ligand greater will be the crystal field splitting energy and lower will be the wavelength of absorption.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The crystal field splitting energy of [Ti(H2O)6]3+ and that of [Ti(CN)6]3− has to be compared.

Concept Introduction:

Stronger the ligand greater will be the crystal field splitting energy and lower will be the wavelength of absorption.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The crystal field splitting energy of [Ti(H2O)6]3+ and that of [Ti(CN)6]3− has to be compared.

Concept Introduction:

Stronger the ligand greater will be the crystal field splitting energy and lower will be the wavelength of absorption.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 22.3 - Another complex studied by Werner had a...Ch. 22.4 - Prob. 22.1E Ch. 22.4 - Prob. 22.2E Ch. 22.5 - Prob. 22.2CC Ch. 22.5 - Prob. 22.3E Ch. 22.5 - Prob. 22.4E Ch. 22.5 - Prob. 22.3CC Ch. 22.7 - Prob. 22.5E Ch. 22.7 - Prob. 22.6E Ch. 22.7 - Prob. 22.7E

Solution Summary: The author compares the absorption curve of the complex ion left[Ti (H_2O)

Concept explainers

Interpretation:

The crystal field splitting energy of [Ti(H2O)6]3+ and that of [Ti(CN)6]3− has to be compared.

Concept Introduction:

Stronger the ligand greater will be the crystal field splitting energy and lower will be the wavelength of absorption.

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Chapter 22 Solutions

Solution Summary: The author compares the absorption curve of the complex ion left[Ti (H_2O)

Concept explainers

Interpretation: The crystal field splitting energy of [Ti(H2O)6]3+ and that of [Ti(CN)6]3− has to be compared. Concept Introduction: Stronger the ligand greater will be the crystal field splitting energy and lower will be the wavelength of absorption.

Want to see the full answer?

Chapter 22 Solutions

Interpretation:

The crystal field splitting energy of [Ti(H2O)6]3+ and that of [Ti(CN)6]3− has to be compared.

Concept Introduction:

Stronger the ligand greater will be the crystal field splitting energy and lower will be the wavelength of absorption.