General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN: 9781305580343
Author: Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher: Cengage Learning
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Question
Chapter 22.5, Problem 22.4E
(a)
Interpretation Introduction
Interpretation:
For the following complexes optical isomers have to be drawn if present.
(a) trans-
(b) cis-
Concept Introduction:
Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.
A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.
In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.
(b)
Interpretation Introduction
Interpretation:
For the following complexes optical isomers have to be drawn if present.
(a) trans-
(b) cis-
Concept Introduction:
Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.
A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.
In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.
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Chapter 22 Solutions
General Chemistry - Standalone book (MindTap Course List)
Ch. 22.3 - Another complex studied by Werner had a...Ch. 22.4 - Prob. 22.1ECh. 22.4 - Prob. 22.2ECh. 22.5 - Prob. 22.2CCCh. 22.5 - Prob. 22.3ECh. 22.5 - Prob. 22.4ECh. 22.5 - Prob. 22.3CCCh. 22.7 - Prob. 22.5ECh. 22.7 - Prob. 22.6ECh. 22.7 - Prob. 22.7E
Ch. 22 - What characteristics of the transition elements...Ch. 22 - Prob. 22.2QPCh. 22 - Prob. 22.3QPCh. 22 - Prob. 22.4QPCh. 22 - Prob. 22.5QPCh. 22 - Prob. 22.6QPCh. 22 - Prob. 22.7QPCh. 22 - Prob. 22.8QPCh. 22 - Silver(I) ion in basic solution is reduced by...Ch. 22 - What evidence did Werner obtain to show that the...Ch. 22 - Define the terms complex ion, ligand, and...Ch. 22 - Prob. 22.12QPCh. 22 - Prob. 22.13QPCh. 22 - Prob. 22.14QPCh. 22 - Prob. 22.15QPCh. 22 - Prob. 22.16QPCh. 22 - Explain the difference in behavior of d and l...Ch. 22 - Prob. 22.18QPCh. 22 - Prob. 22.19QPCh. 22 - a Describe the steps in the formation of a...Ch. 22 - Prob. 22.21QPCh. 22 - Prob. 22.22QPCh. 22 - Prob. 22.23QPCh. 22 - Prob. 22.24QPCh. 22 - Prob. 22.25QPCh. 22 - Prob. 22.26QPCh. 22 - Prob. 22.27QPCh. 22 - Prob. 22.28QPCh. 22 - What is the correct name for the coordination...Ch. 22 - Prob. 22.30QPCh. 22 - Prob. 22.31QPCh. 22 - Prob. 22.32QPCh. 22 - Prob. 22.33QPCh. 22 - Prob. 22.34QPCh. 22 - Prob. 22.35QPCh. 22 - Prob. 22.36QPCh. 22 - Prob. 22.37QPCh. 22 - Prob. 22.38QPCh. 22 - Prob. 22.39QPCh. 22 - Prob. 22.40QPCh. 22 - Prob. 22.41QPCh. 22 - Prob. 22.42QPCh. 22 - Prob. 22.43QPCh. 22 - Prob. 22.44QPCh. 22 - Consider the complex ion [CoCl(en)2(NO2)]+. a What...Ch. 22 - Prob. 22.46QPCh. 22 - Prob. 22.47QPCh. 22 - Name the following complexes, using IUPAC rules. a...Ch. 22 - Prob. 22.49QPCh. 22 - Prob. 22.50QPCh. 22 - Prob. 22.51QPCh. 22 - Give the structural formula for each of the...Ch. 22 - Prob. 22.53QPCh. 22 - Prob. 22.54QPCh. 22 - Prob. 22.55QPCh. 22 - Prob. 22.56QPCh. 22 - Prob. 22.57QPCh. 22 - Prob. 22.58QPCh. 22 - Prob. 22.59QPCh. 22 - Prob. 22.60QPCh. 22 - Prob. 22.61QPCh. 22 - Prob. 22.62QPCh. 22 - Prob. 22.63QPCh. 22 - Prob. 22.64QPCh. 22 - Prob. 22.65QPCh. 22 - Prob. 22.66QPCh. 22 - Prob. 22.67QPCh. 22 - Prob. 22.68QPCh. 22 - There are only two geometric isomers of the...Ch. 22 - Prob. 22.70QPCh. 22 - Prob. 22.71QPCh. 22 - Prob. 22.72QPCh. 22 - Prob. 22.73QPCh. 22 - Prob. 22.74QPCh. 22 - Prob. 22.75QPCh. 22 - Prob. 22.76QPCh. 22 - Consider the complex ion [CoCO3(NH3)4], where the...Ch. 22 - Prob. 22.78QPCh. 22 - Prob. 22.79QPCh. 22 - Prob. 22.80QPCh. 22 - Prob. 22.81QPCh. 22 - Prob. 22.82QPCh. 22 - What is the name of K2[MoOCl4]?Ch. 22 - Write the formula and draw the structure of...Ch. 22 - Prob. 22.85QPCh. 22 - Prob. 22.86QPCh. 22 - Is it possible to have a paramagnetic...Ch. 22 - Prob. 22.88QPCh. 22 - Prob. 22.89QPCh. 22 - Prob. 22.90QPCh. 22 - Prob. 22.91QPCh. 22 - Prob. 22.92QP
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