The complex [ P t ( N H 3 ) 3 C l 3 ] + gives two geometric isomers. The number of geometric isomers expected for this complex ion if it has regular planar hexagonal geometry has to be determined and the isomers have to be drawn. The possibility of planar hexagonal geometry of the complex has to be verified. Concept Introduction: A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism. A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Chapter 22, Problem 22.70QP

Interpretation Introduction

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The complex [Pt(NH3)3Cl3]+ gives two geometric isomers. The number of geometric isomers expected for this complex ion if it has regular planar hexagonal geometry has to be determined and the isomers have to be drawn. The possibility of planar hexagonal geometry of the complex has to be verified.

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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