Structure of cis-trans isomer of the following complexes has to be drawn. (a) [ C o ( N O 2 ) 4 ( N H 3 ) 2 ] − (b) [ C o ( N H 3 ) 5 ( N O ) 2 ] 2 + (c) [ C o ( N H 3 ) 6 ] 3 + (d) [ C r ( N H 3 ) 5 C l ] 2 + Concept Introduction: A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism. A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 1

Question

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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-Page: 8 nsition metal ions have high-spin aqua complexes except one: [Co(HO)₁]". What is the d-configuration, oxidation state of the metal in [Co(H:O))"? Name and draw the geometry of [Co(H2O)]? b) Draw energy diagrams showing the splitting of the five d orbitals of Co for the two possible electron configurations of [Co(H2O)]: Knowing that A = 16 750 cm and Пl. = 21 000 cm, calculate the configuration energy (.e., balance or ligand-field stabilization energy and pairing energy) for both low spin and high spin configurations of [Co(H2O)]. Which configuration seems more stable at this point of the analysis? (Note that 349.76 cm = 1 kJ/mol) Exchange energy (IT) was not taken into account in part (d), but it plays a role. Assuming exchange an occur within t29 and within eg (but not between tz, and ea), how many exchanges are possible in the low in configuration vs in the high spin configuration? What can you say about the importance of exchange energy 07

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Answer 2

Question

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 3

Question

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 4

Question

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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See solution

Answer 5

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 6

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 7

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 22.3 - Another complex studied by Werner had a...Ch. 22.4 - Prob. 22.1E Ch. 22.4 - Prob. 22.2E Ch. 22.5 - Prob. 22.2CC Ch. 22.5 - Prob. 22.3E Ch. 22.5 - Prob. 22.4E Ch. 22.5 - Prob. 22.3CC Ch. 22.7 - Prob. 22.5E Ch. 22.7 - Prob. 22.6E Ch. 22.7 - Prob. 22.7E

Solution Summary: The author explains the structure of cis-trans isomer of the following complexes.

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Chapter 22 Solutions