For the following complexes whether optical isomers are present have to be determined and the same have to be drawn. (a) cis - [ C o ( N H 3 ) 2 ( e n ) 2 ] 3 + (b) trans - [ I r C l 2 ( C 2 O 4 ) 2 ] 3 − Concept Introduction: Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism. A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other. In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Answer 1

Question

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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9. compore the Following two Venctions IN termy Of Ronction Rate and explan in detail the reasoning that led to your conclusion +He p₁₂ 11- ㅐ 15 .. +He H #H H / H b. Compare the Following too reactions 14 terms of reaction Rate and explain in detail the reasoning that led to your conclusion Н d-C- tłu Na +2446 е -ll +2n "H

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a. Write the product For each of the Following reactions H 6-836-6 레 +H₂ N A H A-C-C=C-C-CH + 2 Na +2 NH3 - H H b. Write the reaction Mechanism For. reaction each

Answer 2

Question

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Answer 3

Question

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Answer 4

Question

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Answer 5

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 6

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 7

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 8

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 9

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 22.3 - Another complex studied by Werner had a...Ch. 22.4 - Prob. 22.1E Ch. 22.4 - Prob. 22.2E Ch. 22.5 - Prob. 22.2CC Ch. 22.5 - Prob. 22.3E Ch. 22.5 - Prob. 22.4E Ch. 22.5 - Prob. 22.3CC Ch. 22.7 - Prob. 22.5E Ch. 22.7 - Prob. 22.6E Ch. 22.7 - Prob. 22.7E

Solution Summary: The author explains that optical isomers are non-superimposable mirror images of atoms or groups of molecules.

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Chapter 22 Solutions