For the following complexes whether optical isomers are present have to be determined and the same have to be drawn. (a) cis - [ C o ( N H 3 ) 2 ( e n ) 2 ] 3 + (b) trans - [ I r C l 2 ( C 2 O 4 ) 2 ] 3 − Concept Introduction: Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism. A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other. In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Answer 1

Question

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Consider a solution of 0.00304 moles of 4-nitrobenzoic acid (pKa = 3.442) dissolved in 25 mL water and titrated with 0.0991 M NaOH. Calculate the pH at the equivalence point

Answer 2

Question

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Answer 3

Question

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Answer 4

Question

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Answer 5

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 6

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 7

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 8

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 9

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 22.3 - Another complex studied by Werner had a...Ch. 22.4 - Prob. 22.1E Ch. 22.4 - Prob. 22.2E Ch. 22.5 - Prob. 22.2CC Ch. 22.5 - Prob. 22.3E Ch. 22.5 - Prob. 22.4E Ch. 22.5 - Prob. 22.3CC Ch. 22.7 - Prob. 22.5E Ch. 22.7 - Prob. 22.6E Ch. 22.7 - Prob. 22.7E

Solution Summary: The author explains that optical isomers are non-superimposable mirror images of atoms or groups of molecules.

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Chapter 22 Solutions