For the complex tetracarbonyldibromoiron(II) ion, chemical formula of the compound has to be written. Concept Introduction: Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism. A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other. In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Answer 1

Question

Chapter 22, Problem 22.88QP

(a)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion, chemical formula of the compound has to be written.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion, possible number of geometric isomers has to be determined.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(c)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion whether the complex has optical isomers has to be ascertained.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below. Find the following: (a) The no. of protons corresponding to each signal in the spectra (6) Give the structure of the compound and assign the signals to each proton in the compound. a 70.2 Integration Values C5H10O2 b 47.7 C 46.5 d 69.5 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 Chemical Shift (ppm) 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8

Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below. Answer the following: (a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure of the molecule below. (b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible. complex splitting patterns assuming J values are not similar. там Br 22 2 3 6 4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0 Chemical Shift (ppm) ra. Br 2 3 6 6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 Chemical Shift (ppm) 2 2 Br 7.3 7.2 7.1 7.0 6.9 6.7 6.6 6.5 6.4 6.3 6.2 6.1 6.0 Chemical Shift (ppm) 5.9 5.8 5.7 5.5 5.4 5.3 5.2 5.0 4.9

1600° 1538°C 1493°C In the diagram, the letter L indicates that it is a liquid. Indicate its components in the upper region where only L is indicated. The iron-iron carbide phase diagram. Temperature (°C) 1400 8 1394°C y+L 1200 2.14 y, Austenite 10000 912°C 800a 0.76 0.022 600 400 (Fe) a, Ferrite Composition (at% C) 15 1147°C a + Fe3C 2 3 Composition (wt% C) L 2500 4.30 2000 y + Fe3C 727°C 1500 Cementite (Fe3C) 1000 4 5 6 6.70 Temperature (°F)

Answer 2

Question

Chapter 22, Problem 22.88QP

(a)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion, chemical formula of the compound has to be written.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion, possible number of geometric isomers has to be determined.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(c)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion whether the complex has optical isomers has to be ascertained.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Answer 3

Question

Chapter 22, Problem 22.88QP

(a)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion, chemical formula of the compound has to be written.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion, possible number of geometric isomers has to be determined.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(c)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion whether the complex has optical isomers has to be ascertained.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Answer 4

Question

Chapter 22, Problem 22.88QP

(a)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion, chemical formula of the compound has to be written.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion, possible number of geometric isomers has to be determined.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(c)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion whether the complex has optical isomers has to be ascertained.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Answer 5

Chapter 22, Problem 22.88QP

(a)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion, chemical formula of the compound has to be written.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion, possible number of geometric isomers has to be determined.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(c)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion whether the complex has optical isomers has to be ascertained.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 6

Chapter 22, Problem 22.88QP

(a)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion, chemical formula of the compound has to be written.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 7

Chapter 22, Problem 22.88QP

(a)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion, chemical formula of the compound has to be written.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 8

(b)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion, possible number of geometric isomers has to be determined.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 9

(b)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion, possible number of geometric isomers has to be determined.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 10

(c)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion whether the complex has optical isomers has to be ascertained.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 11

(c)

Interpretation Introduction

Interpretation:

For the complex tetracarbonyldibromoiron(II) ion whether the complex has optical isomers has to be ascertained.

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 22.3 - Another complex studied by Werner had a...Ch. 22.4 - Prob. 22.1E Ch. 22.4 - Prob. 22.2E Ch. 22.5 - Prob. 22.2CC Ch. 22.5 - Prob. 22.3E Ch. 22.5 - Prob. 22.4E Ch. 22.5 - Prob. 22.3CC Ch. 22.7 - Prob. 22.5E Ch. 22.7 - Prob. 22.6E Ch. 22.7 - Prob. 22.7E

Solution Summary: The author explains the chemical formula of the complex tetracarbonyldibromoiron(II) ion.

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Chapter 22 Solutions