The other product yield when compounds γ − lactones of D − glucaric acid subjected to procedure is to be determined. Concept introduction: 舧 A carbohydrate is a biomolecule consisting of carbon (C), hydrogen (H) and oxygen (O) atoms, usually with a hydrogen-oxygen atom ratio of 2:1 舧 HNO 3 is an oxidizing agent. 舧 Carbohydrates are oxidized by HNO 3 to give aldaric acid as a product. 舧 Aldaric acids are carbohydrates having two carboxylic acids. They are formed due to oxidation reaction of aldoses with dilute HNO 3 and their general reaction can be represented as: 舧 The molecules that are nonsuperimposable or not identical with their mirror images are known as chiral molecules. 舧 A pair of two mirror images that are nonidentical is known as enantiomers, which are optically active. 舧 The stereoisomers that are nonsuperimposable on each other and not mirror images of each other are known as diastereomers. 舧 The achiral compounds in which plane of symmetry is present internally and consists of chiral centres are known as meso compounds, but they are optically inactive. 舧 Compounds that have a plane of symmetry tend to exist in meso forms. A meso form arises when the two stereoisomers produce superimposable images, and hence, compounds having meso forms are optically inactive. 舧 Biomolecules containing an ester group ( − OCO ) as part of their ring structures are called lactones . They are derived from their respective hydroxycarboxylic acids. Formation of lactones is called lactonization . They mainly exist as γ and δ forms. 舧 Aldaric acids (obtained from oxidation of aldohexoses) produce lactones of the order. 舧 Fischer formulated new aldohexose products from glucose by interchanging the end-groups of the (+) − glucose chain. These aldohexoses were the L − sugars that were the mirror images of D − Gulose

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Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 22, Problem 18PP

Interpretation Introduction

Interpretation:

The other product yield when compounds γ−lactones of D−glucaric acid subjected to procedure is to be determined.

Concept introduction:

舧 A carbohydrate is a biomolecule consisting of carbon (C), hydrogen (H) and oxygen (O) atoms, usually with a hydrogen-oxygen atom ratio of 2:1

舧 HNO3 is an oxidizing agent.

舧 Carbohydrates are oxidized by HNO3 to give aldaric acid as a product.

舧 Aldaric acids are carbohydrates having two carboxylic acids. They are formed due to oxidation reaction of aldoses with dilute HNO3 and their general reaction can be represented as:

舧 The molecules that are nonsuperimposable or not identical with their mirror images are known as chiral molecules.

舧 A pair of two mirror images that are nonidentical is known as enantiomers, which are optically active.

舧 The stereoisomers that are nonsuperimposable on each other and not mirror images of each other are known as diastereomers.

舧 The achiral compounds in which plane of symmetry is present internally and consists of chiral centres are known as meso compounds, but they are optically inactive.

舧 Compounds that have a plane of symmetry tend to exist in meso forms. A meso form arises when the two stereoisomers produce superimposable images, and hence, compounds having meso forms are optically inactive.

舧 Biomolecules containing an ester group (−OCO) as part of their ring structures are called lactones. They are derived from their respective hydroxycarboxylic acids. Formation of lactones is called lactonization. They mainly exist as γ and δ forms.

舧 Aldaric acids (obtained from oxidation of aldohexoses) produce lactones of the order.

舧 Fischer formulated new aldohexose products from glucose by interchanging the end-groups of the (+)−glucose chain. These aldohexoses were the L−sugars that were the mirror images of D−Gulose

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Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 22, Problem 18PP

Interpretation Introduction

Interpretation:

The other product yield when compounds γ−lactones of D−glucaric acid subjected to procedure is to be determined.

Concept introduction:

舧 A carbohydrate is a biomolecule consisting of carbon (C), hydrogen (H) and oxygen (O) atoms, usually with a hydrogen-oxygen atom ratio of 2:1

舧 HNO3 is an oxidizing agent.

舧 Carbohydrates are oxidized by HNO3 to give aldaric acid as a product.

舧 Aldaric acids are carbohydrates having two carboxylic acids. They are formed due to oxidation reaction of aldoses with dilute HNO3 and their general reaction can be represented as:

舧 The molecules that are nonsuperimposable or not identical with their mirror images are known as chiral molecules.

舧 A pair of two mirror images that are nonidentical is known as enantiomers, which are optically active.

舧 The stereoisomers that are nonsuperimposable on each other and not mirror images of each other are known as diastereomers.

舧 The achiral compounds in which plane of symmetry is present internally and consists of chiral centres are known as meso compounds, but they are optically inactive.

舧 Compounds that have a plane of symmetry tend to exist in meso forms. A meso form arises when the two stereoisomers produce superimposable images, and hence, compounds having meso forms are optically inactive.

舧 Biomolecules containing an ester group (−OCO) as part of their ring structures are called lactones. They are derived from their respective hydroxycarboxylic acids. Formation of lactones is called lactonization. They mainly exist as γ and δ forms.

舧 Aldaric acids (obtained from oxidation of aldohexoses) produce lactones of the order.

舧 Fischer formulated new aldohexose products from glucose by interchanging the end-groups of the (+)−glucose chain. These aldohexoses were the L−sugars that were the mirror images of D−Gulose

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Check out a sample textbook solution

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 22, Problem 18PP

Interpretation Introduction

Interpretation:

The other product yield when compounds γ−lactones of D−glucaric acid subjected to procedure is to be determined.

Concept introduction:

舧 A carbohydrate is a biomolecule consisting of carbon (C), hydrogen (H) and oxygen (O) atoms, usually with a hydrogen-oxygen atom ratio of 2:1

舧 HNO3 is an oxidizing agent.

舧 Carbohydrates are oxidized by HNO3 to give aldaric acid as a product.

舧 Aldaric acids are carbohydrates having two carboxylic acids. They are formed due to oxidation reaction of aldoses with dilute HNO3 and their general reaction can be represented as:

舧 The molecules that are nonsuperimposable or not identical with their mirror images are known as chiral molecules.

舧 A pair of two mirror images that are nonidentical is known as enantiomers, which are optically active.

舧 The stereoisomers that are nonsuperimposable on each other and not mirror images of each other are known as diastereomers.

舧 The achiral compounds in which plane of symmetry is present internally and consists of chiral centres are known as meso compounds, but they are optically inactive.

舧 Compounds that have a plane of symmetry tend to exist in meso forms. A meso form arises when the two stereoisomers produce superimposable images, and hence, compounds having meso forms are optically inactive.

舧 Biomolecules containing an ester group (−OCO) as part of their ring structures are called lactones. They are derived from their respective hydroxycarboxylic acids. Formation of lactones is called lactonization. They mainly exist as γ and δ forms.

舧 Aldaric acids (obtained from oxidation of aldohexoses) produce lactones of the order.

舧 Fischer formulated new aldohexose products from glucose by interchanging the end-groups of the (+)−glucose chain. These aldohexoses were the L−sugars that were the mirror images of D−Gulose

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 22, Problem 18PP

Interpretation Introduction