All the three isomers (i.e. ortho, meta and para) of dichlorobenzene needs to be determined. Concept Introduction : Molecules having same molecular formula but different arrangement of atoms in space are termed as structural isomers.

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Answer 1

Question

Chapter 21, Problem 33E

(a)

Interpretation Introduction

Interpretation: All the three isomers (i.e. ortho, meta and para) of dichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but different arrangement of atoms in space are termed as structural isomers.

(b)

Interpretation Introduction

Interpretation: The number of isomers of trichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

(c)

Interpretation Introduction

Interpretation: The synthesis of meta-isomer of dichlorobenzene needs to be explained using the given information.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

(d)

Interpretation Introduction

Interpretation: The isomer of trichlorobenzene which is hardest to prepare needs to be determined.

Concept Introduction: Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

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13. Ethylethanoate and butanoic acid can be classified as A. positional isomers B. chain isomers C. functional isomers D. stereoisomers 14. Which of the following pairs are positional isomers A. trans-1,4-dichlorocyclohexane, cis-1,3-dichlorocyclopentane B. trans 1,4-dichlorocyclohexane, cis-1,4-dichlorocyclohexane C. 2-pentanol, Cyclopentanol D. 1,2-cycohexanediol, 1,3-cycohexanediol 15. Which of the following compounds will have zero dipole moment? A. cis-1,2-dibromoethylene B. 1,1-dibromoethylene C. trans-1,2-dibromoethylene D. all of these 16. Which of the following is not aromatic: A. cyclopentadienyl cation B. cyclopentadienyl anion C. Cyclopropenyl cation D. Cycloheptatrienyl cation 17. Which of the following compounds containing lone pair has the least tendency to donate its electrons? A. the lone pair in pyridine B. the lone pair in furan C. the lone pair in pyrole D. the lone pair in thiophene

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A. A,C, and B D B. A and D only C. A, B, and C, D D. A, D and B, C E. C and D only

Answer 2

Question

Chapter 21, Problem 33E

(a)

Interpretation Introduction

Interpretation: All the three isomers (i.e. ortho, meta and para) of dichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but different arrangement of atoms in space are termed as structural isomers.

(b)

Interpretation Introduction

Interpretation: The number of isomers of trichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

(c)

Interpretation Introduction

Interpretation: The synthesis of meta-isomer of dichlorobenzene needs to be explained using the given information.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

(d)

Interpretation Introduction

Interpretation: The isomer of trichlorobenzene which is hardest to prepare needs to be determined.

Concept Introduction: Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

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Answer 3

Question

Chapter 21, Problem 33E

(a)

Interpretation Introduction

Interpretation: All the three isomers (i.e. ortho, meta and para) of dichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but different arrangement of atoms in space are termed as structural isomers.

(b)

Interpretation Introduction

Interpretation: The number of isomers of trichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

(c)

Interpretation Introduction

Interpretation: The synthesis of meta-isomer of dichlorobenzene needs to be explained using the given information.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

(d)

Interpretation Introduction

Interpretation: The isomer of trichlorobenzene which is hardest to prepare needs to be determined.

Concept Introduction: Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

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Answer 4

Question

Chapter 21, Problem 33E

(a)

Interpretation Introduction

Interpretation: All the three isomers (i.e. ortho, meta and para) of dichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but different arrangement of atoms in space are termed as structural isomers.

(b)

Interpretation Introduction

Interpretation: The number of isomers of trichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

(c)

Interpretation Introduction

Interpretation: The synthesis of meta-isomer of dichlorobenzene needs to be explained using the given information.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

(d)

Interpretation Introduction

Interpretation: The isomer of trichlorobenzene which is hardest to prepare needs to be determined.

Concept Introduction: Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

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Answer 5

Chapter 21, Problem 33E

(a)

Interpretation Introduction

Interpretation: All the three isomers (i.e. ortho, meta and para) of dichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but different arrangement of atoms in space are termed as structural isomers.

(b)

Interpretation Introduction

Interpretation: The number of isomers of trichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

(c)

Interpretation Introduction

Interpretation: The synthesis of meta-isomer of dichlorobenzene needs to be explained using the given information.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

(d)

Interpretation Introduction

Interpretation: The isomer of trichlorobenzene which is hardest to prepare needs to be determined.

Concept Introduction: Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

Answer 6

Chapter 21, Problem 33E

(a)

Interpretation Introduction

Interpretation: All the three isomers (i.e. ortho, meta and para) of dichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but different arrangement of atoms in space are termed as structural isomers.

Answer 7

Chapter 21, Problem 33E

(a)

Interpretation Introduction

Interpretation: All the three isomers (i.e. ortho, meta and para) of dichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but different arrangement of atoms in space are termed as structural isomers.

Answer 8

(b)

Interpretation Introduction

Interpretation: The number of isomers of trichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

Answer 9

(b)

Interpretation Introduction

Interpretation: The number of isomers of trichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

Answer 10

(c)

Interpretation Introduction

Interpretation: The synthesis of meta-isomer of dichlorobenzene needs to be explained using the given information.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

Answer 11

(c)

Interpretation Introduction

Interpretation: The synthesis of meta-isomer of dichlorobenzene needs to be explained using the given information.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

Answer 12

(d)

Interpretation Introduction

Interpretation: The isomer of trichlorobenzene which is hardest to prepare needs to be determined.

Concept Introduction: Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

Answer 13

(d)

Interpretation Introduction

Interpretation: The isomer of trichlorobenzene which is hardest to prepare needs to be determined.

Concept Introduction: Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 21 - Prob. 1E Ch. 21 - Prob. 2E Ch. 21 - Why are cyclopropane and cyclobutane so reactive?Ch. 21 - Prob. 4E Ch. 21 - Prob. 5E Ch. 21 - Prob. 6E Ch. 21 - Prob. 7E Ch. 21 - Name the five structural isomers of C6H14 .Ch. 21 - Draw the structural formula for each of the...Ch. 21 - Prob. 10E

All the three isomers (i.e. ortho, meta and para) of dichlorobenzene needs to be determined. Concept Introduction : Molecules having same molecular formula but different arrangement of atoms in space are termed as structural isomers.

Solution Summary: The author explains that all three isomers of dichlorobenzene need to be determined. Halogen stabilizes carbocation by resonance effect.

Interpretation: All the three isomers (i.e. ortho, meta and para) of dichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but different arrangement of atoms in space are termed as structural isomers.

Interpretation: The number of isomers of trichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

Interpretation: The synthesis of meta-isomer of dichlorobenzene needs to be explained using the given information.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

Interpretation: The isomer of trichlorobenzene which is hardest to prepare needs to be determined.

Concept Introduction: Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

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Chapter 21 Solutions

All the three isomers (i.e. ortho, meta and para) of dichlorobenzene needs to be determined. Concept Introduction : Molecules having same molecular formula but different arrangement of atoms in space are termed as structural isomers.

Solution Summary: The author explains that all three isomers of dichlorobenzene need to be determined. Halogen stabilizes carbocation by resonance effect.

Interpretation: All the three isomers (i.e. ortho, meta and para) of dichlorobenzene needs to be determined. Concept Introduction : Molecules having same molecular formula but different arrangement of atoms in space are termed as structural isomers.

Interpretation: The number of isomers of trichlorobenzene needs to be determined. Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

Interpretation: The synthesis of meta-isomer of dichlorobenzene needs to be explained using the given information. Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

Interpretation: The isomer of trichlorobenzene which is hardest to prepare needs to be determined. Concept Introduction: Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

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Chapter 21 Solutions

Interpretation: All the three isomers (i.e. ortho, meta and para) of dichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but different arrangement of atoms in space are termed as structural isomers.

Interpretation: The number of isomers of trichlorobenzene needs to be determined.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

Interpretation: The synthesis of meta-isomer of dichlorobenzene needs to be explained using the given information.

Concept Introduction : Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.

Interpretation: The isomer of trichlorobenzene which is hardest to prepare needs to be determined.

Concept Introduction: Molecules having same molecular formula but arrangement of atoms in space is different are termed as structural isomers.