(a) Interpretation: The conversion of benzoyl chloride into benzaldehyde is to be stated. Concept introduction: The chemical reaction in which hydrogenation method is used to reduce an acyl or acid chloride into an aldehyde is known as Rosenmund reduction. This reaction is catalyzed by palladium over barium sulfate known as Rosenmund catalyst.

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Answer 1

Question

Chapter 21, Problem 21.20P

Interpretation Introduction

(a)

Interpretation:

The conversion of benzoyl chloride into benzaldehyde is to be stated.

Concept introduction:

The chemical reaction in which hydrogenation method is used to reduce an acyl or acid chloride into an aldehyde is known as Rosenmund reduction. This reaction is catalyzed by palladium over barium sulfate known as Rosenmund catalyst.

Interpretation Introduction

(b)

Interpretation:

The conversion of benzoyl chloride into N-benzylpyrrolidine is to be stated.

Concept introduction:

The compound that possesses the molecular formula, R-CO-Cl is known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many in organic reactions. These are also known as acyl chlorides.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

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Answer 2

Question

Chapter 21, Problem 21.20P

Interpretation Introduction

(a)

Interpretation:

The conversion of benzoyl chloride into benzaldehyde is to be stated.

Concept introduction:

The chemical reaction in which hydrogenation method is used to reduce an acyl or acid chloride into an aldehyde is known as Rosenmund reduction. This reaction is catalyzed by palladium over barium sulfate known as Rosenmund catalyst.

Interpretation Introduction

(b)

Interpretation:

The conversion of benzoyl chloride into N-benzylpyrrolidine is to be stated.

Concept introduction:

The compound that possesses the molecular formula, R-CO-Cl is known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many in organic reactions. These are also known as acyl chlorides.

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Answer 3

Question

Chapter 21, Problem 21.20P

Interpretation Introduction

(a)

Interpretation:

The conversion of benzoyl chloride into benzaldehyde is to be stated.

Concept introduction:

The chemical reaction in which hydrogenation method is used to reduce an acyl or acid chloride into an aldehyde is known as Rosenmund reduction. This reaction is catalyzed by palladium over barium sulfate known as Rosenmund catalyst.

Interpretation Introduction

(b)

Interpretation:

The conversion of benzoyl chloride into N-benzylpyrrolidine is to be stated.

Concept introduction:

The compound that possesses the molecular formula, R-CO-Cl is known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many in organic reactions. These are also known as acyl chlorides.

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Answer 4

Question

Chapter 21, Problem 21.20P

Interpretation Introduction

(a)

Interpretation:

The conversion of benzoyl chloride into benzaldehyde is to be stated.

Concept introduction:

The chemical reaction in which hydrogenation method is used to reduce an acyl or acid chloride into an aldehyde is known as Rosenmund reduction. This reaction is catalyzed by palladium over barium sulfate known as Rosenmund catalyst.

Interpretation Introduction

(b)

Interpretation:

The conversion of benzoyl chloride into N-benzylpyrrolidine is to be stated.

Concept introduction:

The compound that possesses the molecular formula, R-CO-Cl is known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many in organic reactions. These are also known as acyl chlorides.

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Answer 5

Chapter 21, Problem 21.20P

Interpretation Introduction

(a)

Interpretation:

The conversion of benzoyl chloride into benzaldehyde is to be stated.

Concept introduction:

The chemical reaction in which hydrogenation method is used to reduce an acyl or acid chloride into an aldehyde is known as Rosenmund reduction. This reaction is catalyzed by palladium over barium sulfate known as Rosenmund catalyst.

Interpretation Introduction

(b)

Interpretation:

The conversion of benzoyl chloride into N-benzylpyrrolidine is to be stated.

Concept introduction:

The compound that possesses the molecular formula, R-CO-Cl is known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many in organic reactions. These are also known as acyl chlorides.

Answer 6

Chapter 21, Problem 21.20P

Interpretation Introduction

(a)

Interpretation:

The conversion of benzoyl chloride into benzaldehyde is to be stated.

Concept introduction:

The chemical reaction in which hydrogenation method is used to reduce an acyl or acid chloride into an aldehyde is known as Rosenmund reduction. This reaction is catalyzed by palladium over barium sulfate known as Rosenmund catalyst.

Answer 7

Chapter 21, Problem 21.20P

Interpretation Introduction

(a)

Interpretation:

The conversion of benzoyl chloride into benzaldehyde is to be stated.

Concept introduction:

The chemical reaction in which hydrogenation method is used to reduce an acyl or acid chloride into an aldehyde is known as Rosenmund reduction. This reaction is catalyzed by palladium over barium sulfate known as Rosenmund catalyst.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The conversion of benzoyl chloride into N-benzylpyrrolidine is to be stated.

Concept introduction:

The compound that possesses the molecular formula, R-CO-Cl is known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many in organic reactions. These are also known as acyl chlorides.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The conversion of benzoyl chloride into N-benzylpyrrolidine is to be stated.

Concept introduction:

The compound that possesses the molecular formula, R-CO-Cl is known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many in organic reactions. These are also known as acyl chlorides.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

Solution Summary: The author explains that the conversion of benzoyl chloride into benzaldehyde takes place through Rosenmund reduction.

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