Organic Chemistry Study Guide and Solutions
Organic Chemistry Study Guide and Solutions
6th Edition
ISBN: 9781936221868
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 21, Problem 21.12P
Interpretation Introduction

Interpretation:

The reason as to why the acid-catalyzed hydrolysis of esters is faster than that of amides is to be explained using the analysis of resonance effects and leaving-group basicities.

Concept introduction:

The hydrolysis is the reaction in which a compound is broken down using the molecule of water. The hydrolysis reactions are generally catalyzed by acids and bases. The hydrolysis of the carboxylic derivatives produces carboxylic acids.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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